摘要:
Process for the manufacturing of graft polymers of polysaccharides or polypeptides or its respective derivatives, obtainable by free radical induced co-polymerization of A) a monomer selected from or a monomer mixture of (a) from 20 to 100% by weight of acrylic acid or methacrylic acid or of a mixture thereof or of the alkali metal, alkaline earth metal or ammonium salts thereof, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least 2 ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of either B1) polysaccharides, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidized hydrolytically degraded or oxidized enzymatically degraded polysaccharides, or such chemically modified degraded products, chemically modified mono-, oligo- or polysaccharides or mixtures of the stated compounds or B2) polypeptides, hydrolytically or enzymatically degraded and optionally chemically modified polypeptides or mixtures of the stated compounds in a weight ratio A:(B1 or B2) of from 1:99 to 18:82, wherein the components of the monomers of A) are added to B1) or B2) in an inert solvent at a temperature of 40 to 150 °C in the presence of a free radical-forming initiator, characterized in that at least 50% of the radical-forming initiator are with the component B1) or B2) before the addition of the monomers A) and the rest is added together with the monomers of A).
摘要:
A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and the aqueous float is free of waxes and oils.
摘要:
A process for the p reparation of a synthetic tanning a gent is disclosed whereby multi functional polymer is polymerized with sulfonated aromatic compound, pretreated with organic ligand to form an organo-polymeric matrix, free from formaldehyde. The product has potential application in leather industry for not only ensuring an eco-friendly approach in chrome tanning by way of eliminating the conventional pickling process and the resulting problem of total dissolved solids (TDS) associated with the effluent, but also suggesting an exhaust aid for chrome because of its multiple carboxyl groups. The product can also be used as a retanning agent in leather processing.
摘要:
The invention relates to an epichlorohydrin amine polymer in which the ratio of amine units to epichlorohydrin units ranges between 0.8:1.2 and 1.0:1.0, dimethylaminopropylamine and benzylamine being preferably used as amine units and/or ammonium units. The inventive epichlorohydrin amine polymer is used for treating the surface of semifinished leather products and textile materials, for example.
摘要:
The use of water-soluble graft polymers of monosaccharides, oligosaccharides, polysaccharides and their derivatives obtainable by the radically initiated polymerisation: A) of a monomer or monomer mixture of: (a) 20 to 100 wt % acrylic acid or methacrylic acid or a mixture thereof, the alkaline metal, alkaline earth metal or ammonium salts thereof; (b) 0 to 80 wt % of other monoethylenically unsaturated monomers which can be copolymerised with the monomers (a); and (c) 0 to 5 wt % of at least 2 ethylenically unsaturated, unconjugated monomers with double bonds in the molecule; in the presence of (B) monosaccharides, oligosaccharides, polysaccharides, oxidatively, hydrolytically or enzymatically decomposed polysaccharides, oxidised hydrolytically or oxidised enzymatically decomposed polysaccharides, chemically modified mono, oligo or polysaccharides or mixtures of said compounds; in the ratio by weight A : B (95 to 20) : (5 to 80), as tanning agents for solely, pre and co-tanning smoothed skins and hides and for post-tanning leather and hide.
摘要:
A method of using a dispersion of a selected amphiphilic copolymer formed from a predominant amount of at least one hydrophobic monomer and a minor amount of at least one copolymerizable hydrophilic monomer in the pretanning and tanning step improves moisture release in the wringing step and improves thickness adjustment in the splitting and shaving steps of leather treatment is disclosed.