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    Electrophotographic sensitive body
    26.
    发明专利
    Electrophotographic sensitive body 失效
    电子感应敏感体

    公开(公告)号：JPS6123154A

    公开(公告)日：1986-01-31

    申请号：JP14384284

    申请日：1984-07-11

    Applicant: Takasago Corp

    Inventor： HAGIWARA TOSHIMITSU ,  TSURUTA HARUKI

    IPC: C07C67/00 ,  C07C241/00 ,  C07C251/86 ,  G03G5/04 ,  G03G5/06 ,  H01L51/42

    CPC classification number: G03G5/0616

    Abstract: PURPOSE:To obtain an electrophotgraphic sensitive body high in solubility in a polymer binder and high in sensitivity and small in fatigue by forming a layer contg. a specified hydrazone compd. as an electrostatic charge transfer material. CONSTITUTION:A photosensitive layer 5 composed of a charge generating layer 3 composed essentially of a charge generating material 2, and a charge transfer layer 4 uniformly contg. a hydrazone compd. is formed on a conductive substrate 1. The hydrazone compd. is represented by formula I and prepared by reaching 2-methyl-4-dibenzylaminobenzaldehyde represented by formula II with 1,1-diphenylhydrazine or its mineral acid salt in a solvent, such as methanol or ethanol, at the reflux temp. of solvent, or lower. When needed, the small amt. of a tertiary amine, such a pyridine or triethylamine, an inorg. acid, or an org. acid, such as acetic acid, is used as a condensing agent, and the hydrazone compd. is used in the amt. of 10-90wt%, preferably, 30-90wt%.

    Abstract translation: 目的：获得在聚合物粘合剂中溶解度高，电导率敏感性高，灵敏度高，疲劳小的形式， 指定的腙化合物 作为静电电荷转移材料。 构成：由基本上由电荷产生材料2组成的电荷产生层3和电荷转移层4均匀地包含的感光层5。 腙类化合物 形成在导电基板1上。 由式I表示，并通过在溶剂如甲醇或乙醇中在回流温度下与1,1-二苯基肼或其无机酸盐达到由式II表示的2-甲基-4-二苄基氨基苯甲醛制备。 的溶剂，或更低。 当需要的时候，小amt。 的叔胺，如吡啶或三乙胺，Inorg。 酸或组织。 酸如乙酸用作缩合剂，腙化合物。 用于amt。 10-90wt％，优选30-90wt％。

    Electrophotographic sensitive body
    27.
    发明专利
    Electrophotographic sensitive body 失效
    电子感应敏感体

    公开(公告)号：JPS59185342A

    公开(公告)日：1984-10-20

    申请号：JP5933483

    申请日：1983-04-06

    Applicant: Canon Inc

    Inventor： SAKAI KIYOSHI ,  ISHIKAWA SHIYOUZOU

    IPC: G03G5/06

    CPC classification number: G03G5/065 ,  G03G5/0616

    Abstract: PURPOSE:To obtain a good toner image by incorporating a specified hydrazone type compd. CONSTITUTION:A photosensitive body contains a compd. represented by formula I in which R1, R2 are each optionally substd. alkyl, aralkyl, or aryl, but both are not alkyl at the same time, and R3 is H, halogen, alkyl, or alkoxy. Said compd. can be applied to all the types of photosensitive bodies using org. photoconductive compds., and above all, preferably used for the electrostatic charge transfer layer of the photosensitive layer functionally divided into the charge generating layer and the transfer layer, and the transfer layer is preferably formed on the generating layer. Said compd. itself has no film forming ability, so it is mixed with a binder resin to form the transfer layer. Such a hydrazone type compd. transfers positive holes to inject the holes produced from the generating layer to the transfer layer, then they reach the surface to neutralize negative charge and form an electrostatic charged image, and a good toner image is formed on the surface of the photosensitive body with a positively charged developer. Such a photosensitive body is good in sensitivity, low in residual potential, small in its change even after repeated uses, and it can be used for not only copying machines but widely for laser printers, etc.

    Abstract translation: 目的：通过加入指定的腙类化合物获得良好的调色剂图像。 构成：感光体包含一个compd。 由式I表示，其中R 1，R 2各自任意取代。 烷基，芳烷基或芳基，但两者不同时为烷基，R3为H，卤素，烷基或烷氧基。 说compd 可以应用于所有类型的感光体使用组织。 光电子性能，最重要的是优选用于功能上划分为电荷产生层和转移层的感光层的静电电荷转移层，转移层优选形成在生成层上。 说compd 本身没有成膜能力，因此与粘合剂树脂混合以形成转印层。 这种腙类化合物 转移正孔，将从发生层产生的孔注入转印层，然后它们到达表面以中和负电荷并形成静电荷图像，并且在感光体的表面上以积极的方式形成良好的调色剂图像 充电开发商。 这样的感光体的灵敏度好，残留电位低，即使重复使用也变化小，不仅可以复印机而且广泛用于激光打印机等。

    Electrophotographic sensitive body
    28.
    发明专利
    Electrophotographic sensitive body 失效
    电子感应敏感体

    公开(公告)号：JPS59182455A

    公开(公告)日：1984-10-17

    申请号：JP5510883

    申请日：1983-04-01

    Applicant: Canon Inc

    Inventor： SAKAI KIYOSHI ,  ISHIKAWA SHIYOUZOU

    IPC: C07D307/52 ,  C07D307/56 ,  G03G5/06

    CPC classification number: G03G5/0629 ,  G03G5/0616

    Abstract: PURPOSE:To obtain an electrophotographically useful sensitive body by incorporating a hydrazone type photoconductive substance into a photosensitive layer. CONSTITUTION:A hydrazone compound represented by general formula 1 is incorporated into an electrophotographic sensitive body. In the formula, each of R1 and R2 is optionally substituted alkyl, aralkyl or aryl, both of them are not alkyl, R3 is H or -CO2R5 (R5 is alkyl or aryl), and R4 is alkyl or optionally substituted aryl.

    Abstract translation: 目的：通过将腙型光电导物质并入感光层来获得电子照相用的敏感体。 构成：将由通式1表示的腙化合物并入电子照相感光体。 在该式中，R 1和R 2各自为任选取代的烷基，芳烷基或芳基，它们都不是烷基，R 3为H或-CO 2 R 5（R 5为烷基或芳基），且R 4为烷基或任选取代的芳基。

    Printing plate for electrophotographic photomechanical process
    29.
    发明专利
    Printing plate for electrophotographic photomechanical process 失效
    印刷电子光化学工艺印刷版

    公开(公告)号：JPS59168462A

    公开(公告)日：1984-09-22

    申请号：JP4378783

    申请日：1983-03-16

    Applicant: Ricoh Co Ltd

    Inventor： TSUTSUI KIYOUJI ,  SAKAI KIYOSHI

    IPC: G03G13/28 ,  B41N1/14 ,  G03G5/00 ,  G03G5/06

    CPC classification number: G03G5/0616

    Abstract: PURPOSE:To obtain a printing plate for an electrophotographic photomechanical process superior in printing resistance and suitable also for manufacturing a printed circuit by forming on a conductive substrate a layer contg. a specified hydrazone compd. as an org. photoconductive compd. and an alkali-soluble resin. CONSTITUTION:A printing plate having a photosensitive layer is prepared by coating a conductive substrate of an aluminum plate or the like with a coating liquid contg. an alkaline soln.-soluble resin, such as a styrene-maleic anhydride copolymer or novolak resin, and necessary additives, such as sensitizer and solubilizing agent, and a photoconductive compd. represented by the formula (R1 is alkyl or benzyl; R2 is H, 1-3C alkyl or alkoxy or dialkylamino; n is 1-5, and when n is >=2, R2 may be same or different), and drying it. This printing plate is imagewise exposed with a process camera, developed with a soln. of sodium silicate or the like to prepare a printing plate. The printing plate thus obtained does not cause peeling of the photosensitive layer or breakdown of a hydrophilic layer, etc. during printing operation, and it is superior in printing resistance.

    Abstract translation: 目的：为了获得印刷电阻优异的电子照相光电机械工艺的印版，也适用于在导电基板上形成印刷电路板。 指定的腙化合物 作为组织 光电导体 和碱溶性树脂。 构成：具有感光层的印版通过涂覆铝板等的导电性基材与涂布液接触来制备。 碱性溶胶可溶性树脂如苯乙烯 - 马来酸酐共聚物或酚醛清漆树脂，以及必需的添加剂，如敏化剂和增溶剂，以及光电导体。 由式（R1是烷基或苄基; R2是H，1-3C烷基或烷氧基或二烷基氨基; n是1-5，当n = 2时，R2可以相同或不同），并干燥。 该印版通过用soln显影的工艺相机成像曝光。 的硅酸钠等制备印刷版。 由此得到的印刷版在印刷操作期间不会引起感光层的剥离或亲水层的破坏，并且其耐印刷性优异。

    Electrophotographic sensitive body
    30.
    发明专利
    Electrophotographic sensitive body 失效
    电子感应敏感体

    公开(公告)号：JPS59113445A

    公开(公告)日：1984-06-30

    申请号：JP22296382

    申请日：1982-12-21

    Applicant: Dainippon Ink & Chem Inc

    Inventor： KAWAHARA TATSUROU ,  TAKENOUCHI OSAMU ,  TANAKA HISAMI ,  GUEN CHIYAN KEE

    IPC: G03G5/06

    CPC classification number: G03G5/0637 ,  G03G5/0616

    Abstract: PURPOSE:To improve sensitivity and durability by forming a photosensitive layer contg. a specified 1,2,3,4-tetrahydroquinoline compd. on a conductive substrate. CONSTITUTION:Photosensitive layers 2, 2', 2'' formed on a conductive substrate 1 contains a 1,2,3,4-tetrahydroquinoline (THQ) compd. represented by the formula shown here in which A is an aromatic hydrocarbon or heterocyclic group; R1- R3 are each H, halogen, alkyl, aryl, or the like. The photosensitive layer 2 may be formed by using said THQ together with a sensitizing dye or an electron acceptor, and a binder, or the photosensitive layer 2' may be formed by dispersing a charge transfer substance 3 into a charge transfer layer composed of said THQ and the binder. The photosensitive layer 2'' of multilayer structure uses the THQ incorporated in the charge transfer layer 4. The THQ acts as a photoconductor in the photosensitive layer 2, and as a charge transfer medium in the photosensitive layers 2', 2''. As a result, these photosensitive layers are good in sensitivity, small in fluctuation, resistant against repeated uses, and rich in durability.

    Abstract translation: 目的：通过形成感光层来提高灵敏度和耐久性。 指定的1,2,3,4-四氢喹啉化合物 在导电基板上。 构成：形成在导电基底1上的感光层2,2'，2“含有1,2,3,4-四氢喹啉（THQ）化合物。 由这里所示的式表示，其中A是芳族烃或杂环基; R 1 -R 3各自为H，卤素，烷基，芳基等。 感光层2可以通过使用所述THQ与敏化染料或电子受体以及粘合剂一起使用，或者感光层2'可以通过将电荷转移物质3分散到由所述THQ组成的电荷转移层中而形成 和粘合剂。 多层结构的感光层2“使用结合在电荷转移层4中的THQ。THQ在感光层2中用作感光体，并且作为感光层2'，2”中的电荷转移介质。 结果，这些感光层的灵敏度好，波动小，耐反复使用，耐久性高。

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