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    PRODUCTION OF NITROGEN-CONTAINING COMPOUND USING SULFENAMIDE
    63.
    发明专利
    PRODUCTION OF NITROGEN-CONTAINING COMPOUND USING SULFENAMIDE 失效

    公开(公告)号：JPS63218682A

    公开(公告)日：1988-09-12

    申请号：JP5370287

    申请日：1987-03-09

    申请人： AGENCY IND SCIENCE TECHN

    发明人： YONEMOTO KATSUMI ,  SHIBUYA ISAO

    IPC分类号： C07D327/04 ,  C07D285/00 ,  C07D291/06 ,  C07D339/06 ,  C07D521/00

    摘要： PURPOSE:To simply and inexpensively obtain a ring-expanded product by N atom useful as a synthetic intermediate for agricultural chemicals and medicine under mild conditions in high yield, by reacting a heterocyclic cationic compound with a sulfenamide derivative as a ring expanding reagent. CONSTITUTION:A heterocyclic cationic compound expressed by formula I (X and Y are hetero atoms; R is electron-donating group; Z is acid radical of inorganic strong acid; number of ring member of cation part is 5) such as 5- morpholine-3-phenyl-1,4,2-dithiazolium perchloric acid salt or mesoionic compound expressed by formula II (R is R ; R is inert substituent group; W is S or O) is reacted with a sulfenamide derivative expressed by formula III (R is N,N-disubstituted thiocarbamoylsulfenamide, heterocyclic group, aroyl or substituted imidoyl) such as dimethylthiocarbamoylsulphenamide in a solvent such as acetonitrile under mild conditions of room temperature and neutral for several ten minutes - several days to provide the aimed compound expressed by formula V (numbers of ring member are 6) having antiaromatic properties.

    Photoconductive film and electrophotographic sensitive body
    67.
    发明专利
    Photoconductive film and electrophotographic sensitive body 失效
    光电膜和电子感光敏感体

    公开(公告)号：JPS6139050A

    公开(公告)日：1986-02-25

    申请号：JP15936684

    申请日：1984-07-31

    申请人： Canon Inc

    发明人： ISHIKAWA SHOZO ,  MABUCHI MINORU ,  KOYAMA TAKASHI

    IPC分类号： C07D411/06 ,  C07D327/00 ,  C07D327/04 ,  C07D335/00 ,  C07D411/04 ,  C07D413/06 ,  C07D417/06 ,  C07D421/06 ,  G03G5/04 ,  G03G5/06 ,  H01L51/42

    CPC分类号： G03G5/0635 ,  G03G5/0627 ,  G03G5/0661 ,  G03G5/067

    摘要： PURPOSE:To obtain an org. semiconductor film having high sensitivity by contg. oxathiillium salt compd. CONSTITUTION:A titled body is constituted with an electrophotographic sensitive body provided with the photoconductive film contg. the oxathiillium salt compd. expressed by formulas I -III and the photosensitive layer contg. the oxathiillium salt compd. expressed by formulas I -III on a conductive substrate. The film contg. the oxathiillium salt compd. exhibits photoconductivity and can be used for the photosensitive layer of the following electrophotographic sensitive body: More specifically, the film of the oxathiillium salt compd. is formed by a vacuum deposition method on the conductive substrate or said compd. is dispersed and incorporated into a suitable binder, then the film is formed, by which the electrophotographic sensitive body can be prepd. The more preferable embodiment is the application of the photoconductive film as an electric charge generating layer in the electrophotographic sensitive body of which the photosensitive layer is separated in function to the charge generating layer and charge transfer layer.

    摘要翻译： 目的：获得机构。 具有高灵敏度的半导体膜。 氧ium ium盐 构成：标题物体由设置有光电导膜的电子照相感光体构成。 氧硫草盐 由式I-III和感光层对比表示。 氧硫草盐 由导电基底上的式I-III表示。 电影连续剧 氧硫草盐 表现出光电导率，可用于以下电子照相感光体的感光层：更具体地说，将氧硫杂ium盐的化合物 通过真空沉积方法形成在导电基板或所述压电体上。 分散并并入合适的粘合剂中，然后形成膜，通过该膜可以制备电子照相感光体。 更优选的实施方案是将感光层与电荷产生层和电荷转移层功能分离的电子照相感光体中作为电荷产生层的光电导膜的应用。