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公开(公告)号：JPWO2009119390A1
公开(公告)日：2011-07-21
申请号：JP2010505559
申请日：2009-03-17
Applicant: 一般財団法人石油エネルギー技術センター , 出光興産株式会社
CPC classification number: B01J29/166 , B01J29/076 , B01J29/106 , B01J29/146 , B01J35/10 , B01J2229/16 , B01J2229/20 , B01J2229/36 , C10G45/06 , C10G45/08 , C10G45/12 , C10G47/20
Abstract: 結晶性アルミノシリケートと該結晶性アルミノシリケートを除く多孔性無機酸化物とを含む担体に活性金属を担持した重質油水素化分解触媒であって、(a)前記担体が、結晶性アルミノシリケートと多孔性無機酸化物の合計量基準で、結晶性アルミノシリケート18質量%以上45質量%未満と多孔性無機酸化物55質量%超82質量%以下を含み、(b)前記活性金属が、モリブデン、タングステン、及びニッケルから選ばれる一種又は二種以上の金属であり、かつ、(c)前記重質油水素化分解触媒の細孔分布が、細孔径50〜10,000Åの細孔の総細孔容積に対し、細孔径500〜10,000Åの細孔の細孔容積が10%以下、細孔径100〜200Åの細孔の細孔容積が60%以上である重質油水素化分解触媒は、良好な脱硫機能を有し、かつ減圧残渣油のような沸点が525℃以上の高沸点留分に対し優れた分解活性を有する重質油水素化分解触媒である。
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公开(公告)号：JP5008666B2
公开(公告)日：2012-08-22
申请号：JP2008522559
申请日：2007-06-25
Applicant: 一般財団法人石油エネルギー技術センター , 出光興産株式会社
CPC classification number: B01J29/166 , B01J29/48 , B01J29/64 , B01J29/7815 , B01J35/0006 , B01J35/002 , B01J37/0045 , B01J2229/12 , B01J2229/20 , B01J2229/42 , C10G11/04 , C10G11/05 , C10G11/18 , C10G2300/1059 , C10G2300/202 , C10G2300/301 , C10G2400/02
Abstract: The present invention 1, 2 or 3 provides a desulfurization function-added FCC catalyst which can efficiently reduce the sulfur content of FCC gasoline while maintaining the yield of FCC gasoline in a process of producing FCC gasoline by cracking of heavy oil. The catalyst has vanadium supported on a carrier comprising (a) an alumina-coated zeolite and (b) a porous inorganic oxide except zeolite and/or a clay mineral, wherein the supported vanadium amount is from 500 to 20000 ppm by mass in terms of vanadium metal and the acid amount is from 20 to 450 µmol/g and the macropore surface area is from 30 to 150 m 2 /g; or the catalyst has vanadium supported on a carrier containing from 5 to 40 % by mass of (a) an alumina-coated zeolite and from 30 to 70 % by mass of (b) an alumina, wherein the vanadium concentration ratio before and after grinding the catalyst is at least 2; or the catalyst has at least vanadium and manganese and/or phosphorus supported on a porous inorganic oxide-containing carrier, wherein the supported vanadium amount is from 500 to 20000 ppm by mass in terms of vanadium metal, vanadium and manganese and/or phosphorus form a complex ion in the supporting solution for use in supporting vanadium and manganese and/or phosphorus, and the permeability of the complex ion through a reverse osmosis membrane is at most 25 % relative to the permeability of vanadium through the reverse osmosis membrane.
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5.发明专利
公开(公告)号：JP5547923B2
公开(公告)日：2014-07-16
申请号：JP2009180946
申请日：2009-08-03
Applicant: 出光興産株式会社 , 日揮触媒化成株式会社 , 一般財団法人石油エネルギー技術センター
CPC classification number: C10G47/18 , B01J29/064 , B01J29/076 , B01J29/106 , B01J29/166 , B01J29/42 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/0203 , B01J37/20 , B01J2229/42 , C10G47/20
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