PROCESS FOR PRODUCING PURE N,N'-ASYMMETRICALLY SUBSTITUTED PHENYLUREAS

    公开(公告)号:JPH05194360A

    公开(公告)日:1993-08-03

    申请号:JP21679392

    申请日:1992-08-14

    申请人: CHEMIE LINZ GMBH

    摘要: Process for the preparation of very pure ureas of the formula phenyl-(NH-CO-NR1R2)n in which phenyl represents an unsubstituted or substituted phenyl or phenylene group and R1 and R2 are either identical and each represent an alkyl group, or are different, in which case R1 represents a hydrogen atom and R2 represents an alkyl or phenyl group, or R1 and R2, together with the nitrogen atom, represent an aliphatic heterocyclic ring and n is the number 1 or 2, by reacting a phenylurea of the formula phenyl-(NH-CO-NH2)n with an amine of the formula NR1R2H at temperatures from 100 to 200 degrees C. in a diluent which is inert under the reaction conditions, the reaction being interrupted before by-products are formed, and the urea which is formed being removed from the starting compounds, and the unreacted starting compounds being returned to the process if appropriate.