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公开(公告)号：JP2013216594A
公开(公告)日：2013-10-24
申请号：JP2012086763
申请日：2012-04-05
IPC分类号： C07D301/30
摘要： PROBLEM TO BE SOLVED: To provide a method for industrially producing a cyclic ether group-containing (meth)acrylate in high yield, and to provide an active energy ray-curable resin composition compounded therewith.SOLUTION: A high-purity cyclic ether group-containing (meth)acrylate is provided, which is obtained by reaction between a halogenated alkylene cyclic ether and a norbornene derivative with such a structure that cyclopentadiene is added to (meth)acrylic acid or its alkali metal salt, and subjecting the resultant norbornene derivative to vapor phase thermal decomposition and distillation refining.
摘要翻译： 要解决的问题：提供一种以高产率工业生产含环醚基的（甲基）丙烯酸酯的方法，并提供与其混合的活性能量射线固化树脂组合物。溶液：高纯度环醚基 - 提供了通过将卤代亚烷基环醚和降冰片烯衍生物与环戊二烯加入到（甲基）丙烯酸或其碱金属盐中的结构反应得到的含（甲基）丙烯酸酯，并将所得降冰片烯衍生物 气相热分解和蒸馏精制。
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公开(公告)号：JP2013177547A
公开(公告)日：2013-09-09
申请号：JP2012244990
申请日：2012-11-07
发明人： HIRATA AKIMICHI , KUDO MAYU , MARUYAMA TAKASHI
IPC分类号： C09J4/02 , G02B5/30 , G02F1/1335 , G02F1/13363
摘要： PROBLEM TO BE SOLVED: To provide an active energy ray-curable adhesive for polarizing plates, having a high curing rate, a good wetting property and adhesiveness to a polyvinyl alcohol-based polarizing film and various protective films, retardation films and optical compensation films in producing a polarizing plate, having low viscosity and good workability, free from generation of uneven adhesion, and exhibiting high adhesive force, high durability, high water resistance and excellent transparency.SOLUTION: There is provided an active energy ray-curable adhesive including 45-95 wt.% of an N-hydroxyalkyl (meth)acrylamide, 4-54 wt.% of an N, N-dialkylacrylamide and 0.5-20 wt.% of a linear compound and/or branched compound having two or more vinyl groups on terminals or side chains. A polarizing film is bonded to a protective film, a retardation film or an optical compensation film with the adhesive, and the adhesive is cured by active energy ray irradiation.
摘要翻译： 要解决的问题：为了提供一种用于偏光板的活性能量射线固化性粘合剂，其具有高固化速度，对聚乙烯醇类偏振膜以及各种保护膜，相位差膜和光学补偿膜具有良好的润湿性和粘附性 制造偏光板，粘度低，加工性好，无粘结不均匀，粘合力高，耐久性高，耐水性高，透明性优异。本发明提供一种活性能量射线固化型粘合剂， 95重量％的N-羟烷基（甲基）丙烯酰胺，4-54重量％的N，N-二烷基丙烯酰胺和0.5-20重量％的具有两个或多个乙烯基的线性化合物和/或支链化合物在 端子或侧链。 偏光膜用粘合剂粘合到保护膜，延迟膜或光学补偿膜上，并且通过活性能量射线照射来固化粘合剂。
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3.发明专利Method for producing water-insoluble ionic vinyl monomer and antistatic agent and antistatic composition comprising the same 有权生产水不溶性离子型乙烯单体和抗静电剂的方法和包含其的抗静电组合物
公开(公告)号：JP2013087259A
公开(公告)日：2013-05-13
申请号：JP2011231721
申请日：2011-10-21
IPC分类号： C08F20/34 , C07C67/28 , C07C69/54 , C07C233/38 , C07C311/48 , C08F20/60 , C08K5/103 , C08K5/20 , C08L33/14 , C09K3/16
摘要： PROBLEM TO BE SOLVED: To provide a high-purity ionic vinyl monomer that has good compatibility with a resin and an organic solvent and does not contain a metal ion, an organic solvent and water; and an antistatic agent and an antistatic resin composition comprising the monomer.SOLUTION: The ionic vinyl monomer is synthesized with high purity and a high yield, which is represented by general formula (1), wherein Rrepresents a hydrogen atom or a methyl group; Rand Reach independently represents a 1-3C alkyl group, and may be the same or different from each other; Rrepresents a 1-3C alkyl group, a 1-3C alkenyl group, or a benzyl group; Y represents an oxygen atom or NH-; Z represents a 1-3C alkylene group; and Rfand Rfmay be the same or different from each other and each represents a 1-4C perfluoroalkyl group or a fluoro group with the carbon number of 0. A polymer and the like comprising the ionic vinyl monomer are used as antistatic active ingredients.
摘要翻译： 要解决的问题：提供与树脂和有机溶剂具有良好相容性且不含金属离子，有机溶剂和水的高纯度离子型乙烯基单体; 以及包含该单体的抗静电剂和抗静电性树脂组合物。 解决方案：以通式（1）表示的高纯度和高收率合成离子型乙烯基单体，其中R
1 表示氢原子或 甲基; R 2 和R 3 各自独立地表示1-3C烷基，并且可以相同或不同。 R 4 表示1-3C烷基，1-3C烯基或苄基; Y表示氧原子或NH-; Z表示1-3C亚烷基; 并且Rf 1 和Rf 2 可以相同或不同，并且各自表示1-4C全氟烷基或 碳数为0的氟基。使用包含离子性乙烯基单体的聚合物等作为抗静电活性成分。 版权所有（C）2013，JPO＆INPIT -
公开(公告)号：JP2013178466A
公开(公告)日：2013-09-09
申请号：JP2012237687
申请日：2012-10-29
发明人： HIRATA AKIMICHI , KUDO MAYU , MARUYAMA TAKASHI
IPC分类号： G02B5/30 , C08F220/54 , C09J4/02 , C09J5/00 , C09J11/06
摘要： PROBLEM TO BE SOLVED: To provide an active energy ray-curable adhesive for a polarizing plate, the adhesive showing good wettability and adhesiveness to a polyvinyl alcohol-based polarizing film and various protective films, retardation films and optical compensation films in manufacturing a polarizing plate, having a low viscosity and good workability, preventing uneven adhesion and having high adhesion strength, high heat resistance as well as excellent transparency, and a fast curing rate.SOLUTION: A polarizing plate excellent in polarizing property, transparency and heat resistance is obtained by laminating a polarizing film with a polarizing layer protective film, a retardation film or an optical compensation film by using an active energy ray-curable adhesive in which N-hydroxyalkyl (meth)acrylamide and an N-substituted amide monofunctional monomer are compounded as a main component, and then curing the adhesive by irradiation with active energy rays.
摘要翻译： 要解决的问题：为了提供一种用于偏光板的活性能量射线固化性粘合剂，在制备偏振片时，对聚乙烯醇类偏振膜和各种保护膜，相位差膜和光学补偿膜显示出良好的润湿性和粘附性的粘合剂 具有低粘度和良好的加工性，防止粘合性差，粘合强度高，耐热性高，透明性好，固化速度快。解决偏光性，透明性，耐热性优异的偏光板，可以通过 通过使用其中N-羟烷基（甲基）丙烯酰胺和N-取代的酰胺单官能单体配合作为主要的活性能量射线固化性粘合剂，层合具有偏振层保护膜，延迟膜或光学补偿膜的偏振膜 组分，然后通过用活性能量射线照射固化粘合剂。
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公开(公告)号：JP2013116927A
公开(公告)日：2013-06-13
申请号：JP2011241307
申请日：2011-11-02
发明人： HIRATA AKIMICHI , NAGAMOTO AKIMOTO
摘要： PROBLEM TO BE SOLVED: To provide an active energy ray-curable coating composition which has high dispersibility of a carbon-based filler, does not cause separation or flocculation in a long storage, has favorable adhesiveness and film formability to various substrates, is capable of forming a coating film having excellent smoothness, transparency, hardness, scratch resistance, durability and electrical conductivity in combination, and has a high curing speed; and also to provide an active energy ray-curable coating agent and a coating film formed therefrom.SOLUTION: The solvent-free active energy ray-curable coating composition is obtained by dispersing the carbon-based filler in an N-substituted (meth)acrylamide and further according to needs, blending a multifunctional polymerizable compound and a thermoplastic resin. Besides, the coating film is obtained by blending the active energy ray-curable coating agent using the above coating composition as a base and by applying and curing the coating agent on the surface of the substrate.
摘要翻译： 要解决的问题为了提供一种具有高分散性的碳基填料的活性能量射线固化涂料组合物，不会在长时间储存中引起分离或絮凝，对各种基材具有良好的粘合性和成膜性， 能够组合形成具有优异的平滑性，透明性，硬度，耐刮擦性，耐久性和导电性的涂膜，并且具有高固化速度; 并且还提供活性能量射线固化涂覆剂和由其形成的涂膜。 解决方案：通过将碳系填料分散在N-取代的（甲基）丙烯酰胺中，并根据需要配合多官能聚合性化合物和热塑性树脂，得到无溶剂的活性能量射线固化型涂料组合物。 此外，通过将使用上述涂料组合物的活性能量射线固化涂料作为基料并通过在基材的表面上涂布和固化涂布剂来获得涂膜。 版权所有（C）2013，JPO＆INPIT
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6.发明专利Antifog coating composition and antifog coating material obtained by using the same 审中-公开抗菌涂料组合物和使用它的抗菌涂料
公开(公告)号：JP2013249413A
公开(公告)日：2013-12-12
申请号：JP2012126327
申请日：2012-06-01
发明人： HIRATA AKIMICHI
摘要： PROBLEM TO BE SOLVED: To provide a transparent active energy-curable coating composition suppressed in a bleeding phenomenon, excellent in long term antifog and antifouling properties, having sufficient adhesiveness, and further water resistance not deteriorated even under high-temperature and high-humidity conditions.SOLUTION: An active energy ray-curable or heat-curable coating composition is used which includes: 50-99 wt.% of a liquid hydrophilic (meth)acrylic monomer; and 1-50 wt.% of a chlorine ion-free unsaturated quaternary ammonium salt expressed by general formula [1] soluble in the monomer.
摘要翻译： 要解决的问题：为了提供抑制渗血现象的透明活性能量固化涂料组合物，即使在高温高湿条件下，长期防雾和防污性也优异，具有足够的粘合性和进一步的耐水性也不会劣化 。溶液：使用活性能量射线固化或热固化涂料组合物，其包括：50-99重量％的液体亲水（甲基）丙烯酸单体; 和1-50重量％的由通式[1]表示的不含氯离子的不饱和季铵盐可溶于单体。
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7.发明专利Method of manufacturing water-insoluble ionic vinyl monomer, and antistatic agent and antistatic composition made thereof 审中-公开制造水不溶性离子型乙烯单体的方法及其抗静电剂及其抗微生物组合物
公开(公告)号：JP2013227247A
公开(公告)日：2013-11-07
申请号：JP2012099965
申请日：2012-04-25
IPC分类号： C07C211/63 , C07C209/68 , C07C303/40 , C07C311/48 , C08F26/04 , C09K3/16
摘要： PROBLEM TO BE SOLVED: To provide a water-insoluble ionic vinyl monomer that contains none of metal ions, an organic solvent, and water, is superior in compatibility, moisture resistance, and hydrolysis resistance, and has long-period antistatic effects.SOLUTION: A water-insoluble ionic vinyl monomer represented by general formula [1], where Rand Reach represent a hydrogen atom or methyl group, Rand Rrepresent an alkyl group, an alkenyl group, or a benzyl group, and Xrepresents straight-chain sulfonimide anion [(RfSO)(RfSO)N](where Rfand Rfeach represent a perfluoroalkyl group or fluoro group) or cyclic imide anion [CF(CFSO)N]can be obtained by separating an organic solvent phase after anion exchange reaction carried out in a biphasic system in the presence of both a water-insoluble organic solvent and water, bubbling an inert gas etc., after vacuum concentration, and removing the organic solvent and water, and further adding an ion adsorbent to a water phase during the anion exchange reaction.
摘要翻译： 要解决的问题：提供不含金属离子，有机溶剂和水的不溶于水的离子型乙烯基单体，其相溶性，耐湿性和耐水解性优异，具有长期的抗静电效果。解决方案： 由通式[1]表示的水不溶性离子型乙烯基单体，其中兰德拉克代表氢原子或甲基，兰德R代表烷基，烯基或苄基，X代表直链磺酰亚胺阴离子[（ RfSO）（RfSO）N]（其中Rf和Rfeach代表全氟烷基或氟基）或环状酰亚胺阴离子[CF（CFSO）N]）可以通过在双相系统中进行阴离子交换反应之后分离有机溶剂相 在真空浓缩后，存在水不溶性有机溶剂和水，鼓泡惰性气体等，除去有机溶剂和水，并且在阴离子交换期间进一步向水相中加入离子吸附剂 行动。
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公开(公告)号：JP2013133426A
公开(公告)日：2013-07-08
申请号：JP2011285157
申请日：2011-12-27
发明人： HIRATA AKIMICHI , KUDO MAYU , TAKENOUCHI MIKI , MARUYAMA TAKASHI
摘要： PROBLEM TO BE SOLVED: To provide an active energy ray-curable adhesive for polarizing plate, which never causes adhesion unevenness, in manufacturing of a polarizing plate, while having satisfactory wettability and adhesiveness to a polyvinyl alcohol-based polarizing film and various protective films or phase difference films and good workability, combines high adhesive force and excellent transparency, and has a high curing rate.SOLUTION: The active energy ray-curable adhesive contains 45 wt.% or more of N-hydroxyalkyl (meth)acrylamide, 5-35 wt.% of tetraethylene glycol monophenylether acrylate, and 1-50 wt.% of acryloyl morpholine. A polarizing plate including an adhesive layer formed by mutually sticking a polarizing film and a protective film or phase difference film by the adhesive and curing the adhesive by irradiation with active energy ray is also provided.
摘要翻译： 要解决的问题：为了提供一种偏振片的活性能量射线固化性粘合剂，其不会引起粘合不均匀，在偏振片的制造中，同时具有令人满意的润湿性和与聚乙烯醇系偏振膜和各种保护膜的粘附性， 相位差膜和良好的可加工性，结合了高粘合力和优异的透明度，并且具有高固化速度。解决方案：活性能量射线固化粘合剂含有45重量％以上的N-羟烷基（甲基）丙烯酰胺，5-35 四乙二醇单苯基醚丙烯酸酯的重量百分比，和1-50重量％的丙烯酰吗啉。 还提供了一种偏振片，其包括通过粘合剂相互粘贴偏光膜和保护膜或相位差膜形成的粘合剂层，并且通过用活性能量射线照射固化粘合剂。
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公开(公告)号：JP2013130618A
公开(公告)日：2013-07-04
申请号：JP2011278315
申请日：2011-12-20
发明人： HIRATA AKIMICHI , KUDO MAYU , TAKENOUCHI MIKI , MARUYAMA TAKASHI
IPC分类号： G02B5/30 , C09J4/02 , G02F1/1335
摘要： PROBLEM TO BE SOLVED: To provide an active energy ray curable adhesive for a polarizing plate which has excellent wettability and adhesiveness to a polyvinyl alcohol-based polarizing film, various protection films and a retardation film, has excellent workability, causes no adhesion unevenness, has both high adhesive force and excellent transparency, and has high curing speed, when a polarizing plate is manufactured.SOLUTION: A polarizing plate having excellent polarization properties, durability and moisture resistance can be manufactured by sticking a polarizing film to a polarizing layer protection film and/or a retardation film using an active energy ray curable adhesive which is formed by blending hydroxyalkyl(meth)acrylamide and ethylene oxide-modified acrylate as main components, and curing the adhesive by irradiation of active energy rays.
摘要翻译： 要解决的问题：为了提供对聚乙烯醇系偏振膜具有优异的润湿性和粘附性的偏光板用活性能量射线固化性粘合剂，各种保护膜和延迟膜，具有优异的可加工性，不会引起粘合不均匀，具有 粘合力高，透明度高，固化速度快。当制造偏振片时，可以制造出具有极好性，耐久性和耐湿性优异的偏光板，通过将偏光膜粘贴在偏振层保护膜上， /或使用通过将（甲基）丙烯酸羟烷基酯和环氧乙烷改性丙烯酸酯作为主要成分混合而形成的活性能量射线固化型粘合剂，并通过活性能量射线的照射使粘合剂固化的延迟膜。
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公开(公告)号：JP2013189411A
公开(公告)日：2013-09-26
申请号：JP2012058205
申请日：2012-03-15
发明人： HIRATA AKIMICHI , NAGAMOTO AKIMOTO
IPC分类号： C07C231/12 , C07B61/00 , C07C235/06 , C07D295/18
摘要： PROBLEM TO BE SOLVED: To provide a method for producing high-purity N-substituted-β-alkoxypropionic acid amide in a short time and efficiently even under a mild reaction condition.SOLUTION: A method for producing N-substituted-β-alkoxypropionic acid amide expressed by general formula [2] comprises: subjecting methyl (meth)acrylate and a primary or secondary amine to a Michael addition reaction and an amidation reaction in the presence of a basic compound to obtain N-substituted-β-substituted aminopropionic acid amide; with the obtained N-substituted-β-substituted aminopropionic acid amide as a raw material, quaternizing an amino group in the β-position with a quaternizing agent; and reacting the obtained quaternary ammonium salt with a primary alcohol in the presence of a basic compound. In formula, Rrepresents H or a methyl group; Rrepresents a 1-4C alkyl group or the like; Rrepresents H or a 1-4C alkyl group or the like; and Rrepresents a 1-6C linear or branched alkyl group or alkenyl group.
摘要翻译： 要解决的问题：即使在温和的反应条件下，也能够在短时间内有效地提供高纯度N-取代 - 烷氧基丙酸酰胺的制备方法。解决方案：制备N-取代 - 由通式[2]表示的烷氧基丙酸酰胺包括：在碱性化合物的存在下使（甲基）丙烯酸甲酯和伯胺或仲胺进行迈克尔加成反应和酰胺化反应，得到N-取代的 - 取代的 氨基丙酸酰胺; 用得到的N-取代的 - 取代的氨基丙酸酰胺作为原料，用季铵化剂季铵化位点中的氨基; 并在碱性化合物的存在下使所得季铵盐与伯醇反应。 在式中，R表示H或甲基; R表示1-4C烷基等; R表示H或1-4C烷基等; 并且R表示1-6C直链或支链烷基或烯基。
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