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1.发明专利Method for producing polycarbonate resin, and polycarbonate resin composition 有权生产聚碳酸酯树脂的方法和聚碳酸酯树脂组合物
公开(公告)号：JP2014101487A
公开(公告)日：2014-06-05
申请号：JP2013056265
申请日：2013-03-19
发明人： SHIBATA HIROKI , NISHIHARA RYOHEI , YAMAMOTO MASANORI , KUMAZAWA KATSUHISA , HYODO NARUTOSHI , TSURUHARA KENJI
CPC分类号： C08G64/307
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a polycarbonate resin having good color tone and excellent characteristics in transparency, heat resistance, mechanical strength, and impact resistance; and to provide a polycarbonate resin composition containing the polycarbonate resin.SOLUTION: The method for producing the polycarbonate resin comprises a step of performing a polycondensation reaction of a carbonate diester with a dihydroxy compound in the presence of a transesterification catalyst. The transesterification catalyst contains phosphorus compounds shown by the following general formulae (1) and/or (2) and at least one basic compound selected from the group consisting of compounds of group 1 elements (except hydrogen) of the long period type periodic table, compounds of group 2 elements thereof, basic boron compounds, basic phosphorus compounds and nitrogen-containing basic compounds.
摘要翻译： 要解决的问题：提供一种具有良好色调的聚碳酸酯树脂的生产方法和透明性，耐热性，机械强度和耐冲击性的优异特性; 并提供含有聚碳酸酯树脂的聚碳酸酯树脂组合物。溶液：聚碳酸酯树脂的制造方法包括在酯交换催化剂存在下，进行碳酸二酯与二羟基化合物的缩聚反应的工序。 酯交换催化剂含有下述通式（1）和/或（2）所示的磷化合物和选自长周期型周期表中的第1族元素（氢除外）的化合物的至少一种碱性化合物， 第2族元素的化合物，碱性硼化合物，碱性磷化合物和含氮碱性化合物。
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公开(公告)号：JP2014028881A
公开(公告)日：2014-02-13
申请号：JP2012169366
申请日：2012-07-31
IPC分类号： C08G64/30
摘要： PROBLEM TO BE SOLVED: To reduce a content of phenol contained in a polycarbonate resin composition obtained, and suppress an offensive odor.SOLUTION: A process for producing a polycarbonate resin includes feeding a melted polycarbonate resin obtained by polycondensation reaction between a dihydroxy compound and diphenyl carbonate into a kneading extruder equipped with a vent portion, a water injection portion, and a screw, followed by a water injection/devolatilization treatment. Here, an area of a vent port of the vent portion per flow rate of the melted polycarbonate resin satisfies a condition of following formula (1), a temperature of the melted polycarbonate resin is 350°C or lower, and a number of rotations (n) of the screw satisfies following formula (2): A≥1.5×10(m/(kg/h)) (1), and n×d>25,000 (2) (in the formula (2), n is a number of rotations (rpm) of the screw and d is a diameter (m) of the screw).
摘要翻译： 要解决的问题：降低所得聚碳酸酯树脂组合物中所含的苯酚含量，抑制异味。解决方案：一种制备聚碳酸酯树脂的方法包括将通过缩聚反应得到的熔融聚碳酸酯树脂进料到二羟基化合物和二苯基 碳酸盐装入配备有排气部，注水部和螺杆的捏合挤出机中，然后进行注水/脱挥发分处理。 这里，熔融的聚碳酸酯树脂的每个流量的排气口的排出口的面积满足下述（1）的条件，熔融的聚碳酸酯树脂的温度为350℃以下， n）满足下式（2）：A≥1.5×10（m /（kg / h））（1），n×d> 25,000（2）（式（2） 螺杆的转数（rpm），d是螺杆的直径（μm）。
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公开(公告)号：JP2013209477A
公开(公告)日：2013-10-10
申请号：JP2012079614
申请日：2012-03-30
IPC分类号： C08G64/30
摘要： PROBLEM TO BE SOLVED: To efficiently purify by-product phenol produced as a by-product in a polycondensation reaction and to re-use the by-product phenol.SOLUTION: In a method for producing a polycarbonate resin in which a dihydroxy compound and diphenyl carbonate are subjected to a polycondensation reaction by a plurality of reactors while distilling away byproduct phenol produced as a by-product in each reactor to the outside of the reaction system, the byproduct phenol is made contact with a phenol-containing liquid having phenol concentration higher than the byproduct phenol to recover as high-purity phenol and a liquid containing a component having a boiling point that is higher than that of phenol is refluxed to the reactors.
摘要翻译： 要解决的问题：有效地纯化在缩聚反应中作为副产物产生的副产物苯酚，并重新使用副产物苯酚。溶液：在一种聚碳酸酯树脂的制备方法中，其中二羟基化合物和二苯基 碳酸酯通过多个反应器进行缩聚反应，同时将在每个反应器中作为副产物生产的副产物酚蒸馏到反应体系外部，副产物苯酚与苯酚浓度较高的含酚液体接触 比作为高纯度苯酚回收的副产物苯酚和含有沸点高于苯酚的组分的液体回流到反应器。
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公开(公告)号：JP2009221482A
公开(公告)日：2009-10-01
申请号：JP2009117737
申请日：2009-05-14
发明人： AOSHIMA NORIYUKI , KATO SATOSHI , HOSHINO TOYOMASA , SHINTANI NOBORU , UEDA TADASHI , MIKI YASUAKI , KUMAZAWA KATSUHISA
IPC分类号： C08G63/78 , C08L67/02 , C08L101/00 , C08L101/16 , C12N15/09 , C12P7/18 , C12P7/46 , C12P7/62
摘要： PROBLEM TO BE SOLVED: To provide a polyester enabling control of the biodegradable rate and containing a diol and a dicarboxylic acid as constituent components. SOLUTION: A high-molecular weight and biodegradable polyester includes a diol and a dicarboxylic acid as constituent components, wherein at least one of component of the raw materials is derived from biomass resources and sulfur atom content in the polyester is ≥0.0001 ppm and ≤50 ppm, expressed in terms of atom, and the polyester is used as a resin can contribute greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and have physical properties suited for practical use. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译： 要解决的问题：提供能够控制生物降解速率并含有二醇和二羧酸作为构成成分的聚酯。 解决方案：高分子量和可生物降解的聚酯包括二醇和二羧酸作为构成成分，其中原料中的至少一种成分来自生物质资源，聚酯中的硫原子含量≥0.0001ppm 和≤50ppm，以原子表示，聚酯用作树脂可大大有助于解决与化石燃料资源耗尽有关的环境问题和问题，并具有适用于实际应用的物理性质。 版权所有（C）2010，JPO＆INPIT
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公开(公告)号：JP2005161673A
公开(公告)日：2005-06-23
申请号：JP2003403521
申请日：2003-12-02
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of an aliphatic polyester pellet constituted so as to easily cut a strand of an aliphatic polyester and permitting the adaptation of a simple means.
SOLUTION: The strand comprising an aliphatic polyester polymer or an aliphatic polyester polymer composition is put in a liquid cooling medium such as water in a molten state to be cooled and solidified for 3 s or above and the solidified strand is cut to manufacture pellets. At this time, the surface temperature Ts(°C) of the solidified strand desirably satisfies a relational expression of Ts≤(Tm-10) (wherein Tm is a melting point of the aliphatic polyester polymer or the aliphatic polyester polymer composition in the range of 50-260°C).
COPYRIGHT: (C)2005,JPO&NCIPI摘要翻译： 要解决的问题：提供一种脂肪族聚酯颗粒的制造方法，其构成为容易地切割脂肪族聚酯的链，并允许适应简单的方法。 解决方案：将包含脂族聚酯聚合物或脂族聚酯聚合物组合物的链条放入液体冷却介质如熔融状态的水中，冷却固化3秒或以上，并将固化的链条切割制造 颗粒。 此时，凝固线的表面温度Ts（℃）优选满足Ts≤（Tm-10）的关系式（Tm为脂肪族聚酯聚合物或脂肪族聚酯聚合物组合物的熔点， 50-260℃）。 版权所有（C）2005，JPO＆NCIPI
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公开(公告)号：JP2011126291A
公开(公告)日：2011-06-30
申请号：JP2011074822
申请日：2011-03-30
IPC分类号： B29B9/06
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a particulate polymer such as a pellet of uniform size.
SOLUTION: When the particulate polymer is produced by passing a melted polymer through a die head 11 having a plurality of holes for forming strands and cutting the strands, the difference between highest value and lowest value of the outlet temperature of the die head 11 is controlled within a temperature range of 5°C. The control is independently performed for each section by dividing the die head 11 into a plurality of sections. As the melted polymer, for example, a polycarbonate obtained by melt polycondensation of a dihydroxy compound and a diester carbonate by interesterification reaction or the like can be applied.
COPYRIGHT: (C)2011,JPO&INPIT摘要翻译： 待解决的问题：提供一种尺寸均匀的颗粒状聚合物的制造方法。 解决方案：当通过使熔融的聚合物通过具有多个用于形成股线的孔并且切割股线的模头11来生产颗粒聚合物时，模头的出口温度的最高值和最低值之间的差异 11控制在5℃的温度范围内。 通过将模头11分成多个部分，对于每个部分独立地执行控制。 作为熔融聚合物，可以使用例如通过二聚羟基化合物和碳酸二酯通过酯交换反应等进行熔融缩聚得到的聚碳酸酯。 版权所有（C）2011，JPO＆INPIT
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公开(公告)号：JP2009041036A
公开(公告)日：2009-02-26
申请号：JP2008263163
申请日：2008-10-09
发明人： AOSHIMA NORIYUKI , MIKI YASUAKI , KUMAZAWA KATSUHISA , KATO SATOSHI , UEDA TADASHI , HOSHINO TOYOMASA , SHINTANI NOBORU , YAMAGISHI KENJI , ISOTANI ATSUSHI
IPC分类号： C08G63/16
CPC分类号： C08G63/16 , C08G63/20 , C08G63/78 , C08L1/00 , C08L3/00 , C08L5/00 , C08L67/02 , C08L99/00 , C08L2201/06 , C08L2666/02
摘要： PROBLEM TO BE SOLVED: To provide a resin having a property suitable for practical use and greatly contributes such as to environmental problems and depletion of fossil fuel resources. SOLUTION: In the biomass resources derived polyesters and a processes for production of the biomass resources derived polyesters wherein the main repetitive units are dicarboxylic acid unit and a diol unit, at least one of the dicarboxylic acid and the diol of resources of the polyester is obtained from the biomass resources, wherein the amount of acid terminal of the polyester is 50 equivalents/ton or less. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译： 要解决的问题：提供具有适用于实际应用的性质的树脂，并且极大地有助于环境问题和化石燃料资源的消耗。 解决方案：在生物质资源衍生的聚酯中，生产生物质源的聚酯的生产方法，其中主要重复单元是二羧酸单元和二醇单元，二羧酸和二醇的至少一种是 从生物质资源获得聚酯，其中聚酯的酸性末端的量为50当量/吨以下。 版权所有（C）2009，JPO＆INPIT
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公开(公告)号：JP2008247953A
公开(公告)日：2008-10-16
申请号：JP2007087536
申请日：2007-03-29
IPC分类号： C08G64/30
CPC分类号： C08G64/205 , B01J19/1862 , B01J19/20 , B01J2219/00083 , B01J2219/00094 , C08G64/307
摘要： PROBLEM TO BE SOLVED: To reduce the exchange frequency of a filter to filtrate a raw material.
SOLUTION: A molten raw material prepared in a raw material preparation tank is filtered with a filter part 20 having a plurality of serially connected pleat-type filters, etc., and supplied to a reactor. At least one combination of the filters satisfies the formula A>B, wherein A (μm) is the mesh opening of the upstream side of the filter and B (μm) is the mesh opening of the downstream side of the filter.
COPYRIGHT: (C)2009,JPO&INPIT摘要翻译： 要解决的问题：减少过滤器的原料的过滤器的交换频率。 解决方案：在原料制备罐中制备的熔融原料用具有多个串联连接的褶状过滤器等的过滤器部分20过滤，并供给反应器。 过滤器的至少一个组合满足公式A> B，其中A（μm）是过滤器的上游侧的网孔，B（μm）是过滤器的下游侧的网孔。 版权所有（C）2009，JPO＆INPIT
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公开(公告)号：JP2008238791A
公开(公告)日：2008-10-09
申请号：JP2007086877
申请日：2007-03-29
CPC分类号： B29B9/06 , B29K2069/00
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of particulate polymer such as a pellet, etc. of uniform size. SOLUTION: When molten polymer is passed through a die head 11 having a plurality of holes to strands, and cut to manufacture the particulate polymer, a difference between the highest temperature and the lowest temperature of the outlet temperature of the die head 11 is controlled within a temperature range of 5°C. The control is done by dividing the die head 11 into a plurality of sections, and independently conducted at each section. The molten polymer can be, for example, applied by polycarbonate, etc. obtained by fusing and condensing by transesterifcation of aromatic dihydroxy compound and carbonate diester. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译： 要解决的问题：提供具有均匀尺寸的颗粒状聚合物如颗粒等的制造方法。 解决方案：当熔融聚合物通过具有多个孔的模头11到股线上并切割以制造颗粒聚合物时，模头11的出口温度的最高温度和最低温度之间的差异 控制在5°C的温度范围内。 通过将模头11分割成多个部分进行控制，并且在每个部分独立地进行控制。 熔融聚合物可以例如通过聚碳酸酯等施加，其通过芳族二羟基化合物和碳酸二酯的酯交换进行缩合和缩合而获得。 版权所有（C）2009，JPO＆INPIT
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公开(公告)号：JP2008229505A
公开(公告)日：2008-10-02
申请号：JP2007073135
申请日：2007-03-20
摘要： PROBLEM TO BE SOLVED: To provide a reaction apparatus which is used when an ester interchange reaction is performed by using an aromatic dihydroxy compound and a carbonate diester as raw materials and which has an agitation means and a plurality of internal coils, can ensure the fluidity of a reaction solution and has excellent heat transfer capacity.
SOLUTION: A relationship A/B (the internal coil pitch) of a center-to-center distance A between the adjacent ones of internal coils 24, 25, 26 to an outside diameter B of any of internal coils is within 1.6-4.0. The internal coils are arranged spirally and twofold to fivefold.
COPYRIGHT: (C)2009,JPO&INPIT摘要翻译： 待解决的问题：提供一种当通过使用芳族二羟基化合物和碳酸二酯作为原料进行酯交换反应并具有搅拌装置和多个内部线圈的反应装置时，可以 确保反应溶液的流动性，并具有优良的传热能力。 解决方案：内部线圈24,25,26中的相对于内部线圈24,25,26之间的中心到中心距离A与任何内部线圈的外径B之间的关系A / B（内部线圈间距）在1.6 -4.0。 内部线圈螺旋地设置两倍至五倍。 版权所有（C）2009，JPO＆INPIT
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