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公开(公告)号：US5013702A
公开(公告)日：1991-05-07
申请号：US434915
申请日：1989-11-09
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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公开(公告)号：US4983677A
公开(公告)日：1991-01-08
申请号：US381364
申请日：1989-07-18
申请人： Bryce V. Johnson , Joyce M. Kunde
发明人： Bryce V. Johnson , Joyce M. Kunde
摘要： An extrudable composition comprising hydrocarbon polymer, organophosphite or organophosphate compound and fluorocarbon polymer. The organophosphite or organophosphate and the fluorocarbon polymer are present in the composition in such relative proportions and concentrations as to reduce the occurrence of melt defects during the extrusion of said thermoplastic hydrocarbon polymer.
摘要翻译： 包含烃聚合物，有机亚磷酸酯或有机磷酸酯化合物和氟碳聚合物的可挤出组合物。 有机亚磷酸酯或有机磷酸酯和氟碳聚合物以相对比例和浓度存在于组合物中，以减少在挤出所述热塑性烃聚合物期间熔融缺陷的发生。
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公开(公告)号：US4526882A
公开(公告)日：1985-07-02
申请号：US544544
申请日：1983-10-24
CPC分类号： C08F10/00 , Y10S526/904
摘要： A comminuted, supported polymerization catalyst for alpha-olefins comprises (A) an organoaluminum compound and (B) a solid titanium-containing component formed by at least one halogen-containing compound of titanium(IV); (b) at least one electron donor; and (c) at least one hydrocarbon-insoluble magnesium-containing compound; and (2) retreating such comminuted product with (a) at least one halogen-containing compound of titanium(IV); and (b) a mixture containing ethylbenzoate and a substituted alkyl aromatic acid ester in which the substituent group has a negative Hammett constant; and optionally, at least one chlorocarbon and/or at least one haloalkylchlorosilane.
摘要翻译： 一种粉碎的负载型α-烯烃聚合催化剂包括（A）有机铝化合物和（B）由至少一种含钛的钛（IV）化合物形成的固体含钛组分; （b）至少一个电子给体; 和（c）至少一种不溶于烃的含镁化合物; 和（2）用（a）至少一种含卤素的钛（IV）化合物后处理该粉碎产品; 和（b）含有苯甲酸乙酯和取代烷基芳族酸酯的混合物，其中取代基具有负的哈米特常数; 和任选的至少一种氯化碳和/或至少一种卤代烷基氯硅烷。
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4.发明授权Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound, a chlorocarbon and an ester 失效用钛（IV）化合物，氯碳化合物和酯取代粉碎的烯烃聚合催化剂
公开(公告)号：US4431572A
公开(公告)日：1984-02-14
申请号：US378406
申请日：1982-05-14
CPC分类号： C08F10/00
摘要： A comminuted, supported polymerization catalyst for alpha-olefins comprises (A) an organoaluminum compound and (B) a solid titanium-containing component formed by (1) comminuting a solid reaction product comprising (a) at least one halogen-containing compound of titanium (IV); (b) at least one electron donor; and (c) at least one hydrocarbon-insoluble magnesium-containing compound; and (2) retreating such comminuted product with (a) at least one halogen-containing compound of titanium (IV); (b) at least one chlorocarbon; and (c) at least one organic acid ester.
摘要翻译： 粉碎的负载型α-烯烃聚合催化剂包括（A）有机铝化合物和（B）通过（1）粉碎固体反应产物形成的固体含钛组分，所述固体反应产物包含（a）至少一种含卤素的钛化合物 （四）; （b）至少一个电子给体; 和（c）至少一种不溶于烃的含镁化合物; 和（2）用（a）至少一种含卤素的钛（IV）化合物后处理该粉碎产品; （b）至少一种氯化碳; 和（c）至少一种有机酸酯。
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公开(公告)号：US4866022A
公开(公告)日：1989-09-12
申请号：US186359
申请日：1988-04-25
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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公开(公告)号：US4855360A
公开(公告)日：1989-08-08
申请号：US182028
申请日：1988-04-15
申请人： Denis Duchesne , Bryce V. Johnson
发明人： Denis Duchesne , Bryce V. Johnson
CPC分类号： C08L23/02 , C08L23/06 , C08L23/0815 , C08L2205/03 , C08L27/16 , C08L27/20 , C08L71/02
摘要： An extrudable composition comprising thermoplastic hydrocarbon polymer, poly(oxyalkylene) polymer and fluorocarbon polymer. The poly(oxyalkylene) polymer and the fluorocarbon polymer are present in the composition in such relative proportions and concentrations as to reduce the occurrence of melt defects during the extrusion of said hydrocarbon polymer composition.
摘要翻译： 包含热塑性烃聚合物，聚（氧化烯）聚合物和碳氟聚合物的可挤出组合物。 聚（氧化烯）聚合物和氟碳聚合物以相对比例和浓度存在于组合物中，以减少在所述烃聚合物组合物的挤出期间熔融缺陷的发生。
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7.发明授权Supported olefin polymerization catalyst produced from a magnesium alkyl/organophosphoryl complex 失效由烷基镁/有机磷酰基络合物制备的负载型烯烃聚合催化剂
公开(公告)号：US4657882A
公开(公告)日：1987-04-14
申请号：US813603
申请日：1985-12-26
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics, comprises the product formed by (a) complexing a magnesium alkyl composition with an organophosphoryl compound; (b) reacting the resulting stable complex with a compatible precipitation agent to form a solid component; and (c) reacting the resulting solid with a titanium (IV) compound and an electron donor compound in a suitable diluent.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括通过（a）使烷基镁组合物与有机磷酰基化合物络合形成的产物; （b）使得到的稳定配合物与相容的沉淀剂反应以形成固体组分; 和（c）使所得固体与合适的稀释剂中的钛（IV）化合物和电子给体化合物反应。
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公开(公告)号：US4581342A
公开(公告)日：1986-04-08
申请号：US674996
申请日：1984-11-26
CPC分类号： C08F10/00
摘要： A solid-hydrocarbon insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics, comprises the product formed by (a) complexing a magnesium alkyl composition with an ortho disubstituted hindered aromatic acid ester; (b) reacting the resulting complex with a compatible precipitation agent to form a solid component; and (c) reacting the resulting solid with a titanium(IV) compound and an electron donor compound in a suitable diluent.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括通过（a）使烷基镁组合物与邻二取代的受阻芳族酸酯络合而形成的产物; （b）使所得的络合物与相容的沉淀剂反应以形成固体组分; 和（c）使所得固体与合适的稀释剂中的钛（IV）化合物和电子给体化合物反应。
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9.发明授权Olefin polymerization catalyst system producing polymer with low active chloride 失效烯烃聚合催化剂体系生产低活性氯化物的聚合物
公开(公告)号：US4567155A
公开(公告)日：1986-01-28
申请号：US653211
申请日：1984-09-24
CPC分类号： C08F10/00
摘要： A catalyst system especially suited for polymerizing alpha-olefins in the gas-phase to polymers containing essentially no active chloride comprises (A) a titanium-containing component supported on a hydrocarbon-insoluble magnesium-containing compound in combination with an electron donor compound and (B) a co-catalyst comprising (a) at least one trialkylaluminum compound (b) an aromatic acid ester and (c) an unhindered secondary amine, optionally reacted with a dialkylaluminum hydride, in substantial absence of compounds containing an Al-Cl bond.
摘要翻译： 特别适用于将气相中的α-烯烃聚合成基本上不含活性氯化物的聚合物的催化剂体系包括（A）负载在不溶于烃的化合物上的含钛组分与电子给体化合物的组合和（ B）助催化剂，其包含（a）至少一种三烷基铝化合物（b）芳族酸酯和（c）基本上不含有Al-Cl键的化合物的任选与氢化二烷基铝反应的未受阻胺。
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10.发明授权Retreating comminuted olefin polymerization catalyst with a titanium (IV) compound and an ester 失效用钛（IV）化合物和酯取代粉碎的烯烃聚合催化剂
公开(公告)号：US4431570A
公开(公告)日：1984-02-14
申请号：US378121
申请日：1982-05-14
申请人： Bryce V. Johnson
发明人： Bryce V. Johnson
CPC分类号： C08F10/00
摘要： A comminuted, supported polymerization catalyst for alpha-olefins comprises (A) an organoaluminum compound and (B) a solid titanium-containing component formed by (1) comminuting a solid reaction product comprising (a) at least one halogen-containing compound of titanium(IV); (b) at least one electron donor; and (c) at least one hydrocarbon-insoluble magnesium-containing compound; and (2) retreating such comminuted product with (a) at least one halogen-containing compound of titanium(IV); and (b) at least one organic acid ester.
摘要翻译： 粉碎的负载型α-烯烃聚合催化剂包括（A）有机铝化合物和（B）通过（1）粉碎固体反应产物形成的固体含钛组分，所述固体反应产物包含（a）至少一种含卤素的钛化合物 （四）; （b）至少一个电子给体; 和（c）至少一种不溶于烃的含镁化合物; 和（2）用（a）至少一种含卤素的钛（IV）化合物后处理该粉碎产品; 和（b）至少一种有机酸酯。
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