Method for inhibiting hydrate formation
    3.
    依法登记的发明
    Method for inhibiting hydrate formation 失效
    抑制水合物形成的方法

    公开(公告)号:USH1749H

    公开(公告)日:1998-09-01

    申请号:US306568

    申请日:1994-09-15

    IPC分类号: C09K8/52 C10L3/10 C07C9/00

    CPC分类号: C09K8/52 C09K2208/22 C10L3/10

    摘要: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The method uses a mixture comprising a first additive and a second additive. The mixture produces a synergistic hydrate inhibition effect. The first additive is selected from the class of substantially water soluble polymers. The second additive is selected from the class of ionic or non-ionic organic compounds which have a polar part and nonpolar part with the nonpolar part having an alkyl, alkenyl, or alkynyl group with 12 or fewer carbon atoms.

    摘要翻译: 公开了一种抑制在具有水合物形成成分的流体中形成笼形水合物的方法。 更具体地说,该方法可用于处理在管道中输送的天然气等石油流体流,以抑制管道中的水合物限制。 该方法使用包含第一添加剂和第二添加剂的混合物。 该混合物产生协同的水合物抑制作用。 第一种添加剂选自基本上水溶性聚合物的类别。 第二种添加剂选自具有极性部分和非极性部分的离子或非离子有机化合物,其中非极性部分具有12个或更少碳原子的烷基,烯基或炔基。

    Maleimide copolymers and method for inhibiting hydrate formation
    4.
    发明授权
    Maleimide copolymers and method for inhibiting hydrate formation 失效
    马来酰亚胺共聚物和抑制水合物形成的方法

    公开(公告)号:US5744665A

    公开(公告)日:1998-04-28

    申请号:US659550

    申请日:1996-06-06

    摘要: Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.

    摘要翻译: 新型马来酰亚胺共聚物具有至少两个单体单元,马来酰亚胺单元和具有侧基的乙烯基单元,侧基具有2至21个碳原子,至少一个氮原子和至少一个氧原子。 共聚物的平均分子量为约1,000至约6,000,000。 优选的马来酰亚胺共聚物包括丙烯酰胺/马来酰亚胺共聚物,N-乙烯基酰胺/马来酰亚胺共聚物,乙烯基内酰胺/马来酰亚胺共聚物,烯基环亚氨基醚/马来酰亚胺共聚物和丙烯酰胺/马来酰亚胺共聚物。 基本上水溶性的马来酰亚胺共聚物可用于通过降低石油流体物流中气体水合物晶体的成核,生长和/或附聚的速率来抑制在具有水合物形成成分的流体中形成笼形水合物,由此抑制形成 在输送石油流体的管道中存在水合物堵塞。 抑制剂可以以低浓度方便地使用,例如在油或气流中存在的水的约0.01重量%至约5重量%的范围内,以有效地处理具有水相的石油流体。

    Method for inhibiting hydrate formation
    5.
    发明授权
    Method for inhibiting hydrate formation 失效
    抑制水合物形成的方法

    公开(公告)号:US6028233A

    公开(公告)日:2000-02-22

    申请号:US624277

    申请日:1996-03-28

    摘要: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is claimed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble polymers having N-vinyl amide or N-allyl amide units. Specific examples of such copolymers include, N-vinyl-N-methylacetamide (VIMA) copolymerized with acryloylpyrrolidine (APYD) or acryloylpiperidine (APID), and more preferably, VIMA copolymerized with N-substituted methacrylamides, such as N-isopropylmethacrylamide (iPMAM) and methacryloylpyrrolidine (MAPYD) to produce inhibitors for practicing the claimed method.

    摘要翻译: 要求保护在具有水合物形成成分的流体中形成笼形水合物的方法。 更具体地说,该方法可用于处理在管道中输送的天然气等石油流体流,以抑制管道中的水合物限制。 用于实施该方法的水合物抑制剂包括基本上具有N-乙烯基酰胺或N-烯丙基酰胺单元的水溶性聚合物。 这种共聚物的具体实例包括与丙烯酰基吡咯烷(APYD)或丙烯酰基哌啶(APID)共聚的N-乙烯基-N-甲基乙酰胺(VIMA),更优选与N-取代的甲基丙烯酰胺如N-异丙基甲基丙烯酰胺(iPMAM)共聚的VIMA和 甲基丙烯酰基吡咯烷(MAPYD)以产生用于实施所要求保护的方法的抑制剂。

    Method for inhibiting hydrate formation using maleimide copolymers
    6.
    发明授权
    Method for inhibiting hydrate formation using maleimide copolymers 失效
    使用马来酰亚胺共聚物抑制水合物形成的方法

    公开(公告)号:US5936040A

    公开(公告)日:1999-08-10

    申请号:US976438

    申请日:1997-11-21

    CPC分类号: F17D1/05 C10L3/06 C09K2208/22

    摘要: Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.

    摘要翻译: 新型马来酰亚胺共聚物具有至少两个单体单元,马来酰亚胺单元和具有侧基的乙烯基单元,侧基具有2至21个碳原子,至少一个氮原子和至少一个氧原子。 共聚物的平均分子量为约1,000至约6,000,000。 优选的马来酰亚胺共聚物包括丙烯酰胺/马来酰亚胺共聚物,N-乙烯基酰胺/马来酰亚胺共聚物,乙烯基内酰胺/马来酰亚胺共聚物,烯基环亚氨基醚/马来酰亚胺共聚物和丙烯酰胺/马来酰亚胺共聚物。 基本上水溶性的马来酰亚胺共聚物可用于通过降低石油流体物流中气体水合物晶体的成核,生长和/或附聚的速率来抑制在具有水合物形成成分的流体中形成笼形水合物,由此抑制形成 在输送石油流体的管道中存在水合物堵塞。 抑制剂可以以低浓度方便地使用,例如在油或气流中存在的水的约0.01重量%至约5重量%的范围内,以有效地处理具有水相的石油流体。