公开(公告)号：US08426529B2

公开(公告)日：2013-04-23

申请号：US11801633

申请日：2007-05-10

Applicant: Lisa Saunders Baugh ,  Abhimanyu Onkar Patil ,  Christian Peter Mehnert ,  Kevin R. Squire ,  Kenneth A. Cook ,  Caiguo Gong ,  Enock Berluche ,  Karla Schall Colle ,  Alan J. Oshinski ,  Stephen Zushma ,  Beverly J. Poole

Inventor： Lisa Saunders Baugh ,  Abhimanyu Onkar Patil ,  Christian Peter Mehnert ,  Kevin R. Squire ,  Kenneth A. Cook ,  Caiguo Gong ,  Enock Berluche ,  Karla Schall Colle ,  Alan J. Oshinski ,  Stephen Zushma ,  Beverly J. Poole

IPC: C08F8/04 ,  C08F8/08 ,  C08F236/20 ,  C08F232/06

CPC classification number: C08F210/02 ,  C08F8/04 ,  C08F8/08 ,  C08F232/00

Abstract: Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics. Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described.

Abstract translation: 公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。 这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）重均分子量Mw大于约170,000; c）包含无定形材料并且具有约8℃至约129℃的玻璃化转变温度Tg，其也符合方程式Tg（℃）= [（摩尔％DCPD×3.142） - 4.67]; 和d）在乙烯 - 二环戊二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。 这样的共聚物可以通过氢化和/或环氧化来容易地衍生化，以提供适合用作工程热塑性塑料的聚合材料。 还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。

公开(公告)号：US08389625B2

公开(公告)日：2013-03-05

申请号：US12653742

申请日：2009-12-17

Applicant: Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  Jon Edmond Randolph Stanat

Inventor： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  Jon Edmond Randolph Stanat

IPC: C08K5/09

CPC classification number: C07D317/36 ,  C08L21/00 ,  C10G3/44 ,  C10G3/48 ,  C10G29/205 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1092 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/06 ,  C10G2400/10 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2270/00 ,  Y02P30/20

Abstract: This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.

Abstract translation: 本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。 更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。 在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。 还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。 或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。

公开(公告)号：US20120322948A1

公开(公告)日：2012-12-20

申请号：US13596567

申请日：2012-08-28

Applicant: Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

Inventor： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

IPC: C08F20/42 ,  C08F4/80

CPC classification number: C08C19/02 ,  C08F4/80 ,  C08F232/00 ,  C08G61/08

Abstract: In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.

Abstract translation: 在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个 来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

公开(公告)号：US20110257317A1

公开(公告)日：2011-10-20

申请号：US13085905

申请日：2011-04-13

Applicant: Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle ,  Manika Varma-Nair ,  Ramzi Yanni Saleh ,  Jon Edmond Randolph Stanat ,  Stephen Zushma ,  Victor DeFlorio

Inventor： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle ,  Manika Varma-Nair ,  Ramzi Yanni Saleh ,  Jon Edmond Randolph Stanat ,  Stephen Zushma ,  Victor DeFlorio

IPC: C08K5/11 ,  C07C69/604 ,  C07C69/74 ,  C08K5/12 ,  C08L27/06

CPC classification number: C07C69/34 ,  C07C69/74 ,  C07C2601/08 ,  C08K5/11 ,  C08K5/12

Abstract: Tetraesters of a C4-C5 aliphatic tetracarboxylic acid and OXO-alcohols and plasticized compositions containing said tetraesters are provided.

Abstract translation: 提供C4-C5脂族四羧酸和OXO-醇的四酯和含有所述四酯的增塑组合物。

公开(公告)号：US20090318597A1

公开(公告)日：2009-12-24

申请号：US11820559

申请日：2007-06-20

Applicant: Kevin R. Squire ,  Alan J. Oshinski ,  Kevin D. Robinson ,  Christian Peter Mehnert ,  Marsha M. Arvedson ,  Beverly J. Poole ,  Abhimanyu Onkar Patil ,  Lisa Saunders Baugh ,  Karla Schall Colle

Inventor： Kevin R. Squire ,  Alan J. Oshinski ,  Kevin D. Robinson ,  Christian Peter Mehnert ,  Marsha M. Arvedson ,  Beverly J. Poole ,  Abhimanyu Onkar Patil ,  Lisa Saunders Baugh ,  Karla Schall Colle

IPC: C08K5/04 ,  C08K3/34 ,  C08L45/00 ,  C08L67/02

CPC classification number: C08L23/0823 ,  C08K3/34 ,  C08L23/16 ,  C08L51/06 ,  C08L53/02 ,  C08L2666/06 ,  C08L2666/02 ,  C08L2666/24

Abstract: A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.

Abstract translation: 聚合物组合物包含（a）至少40重量％（基于组合物的重量）包含至少一个非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃聚合物（基于 环烯烃聚合物），其中至少一部分环烯烃聚合物的玻璃化转变温度大于100℃; （b）至多40重量％（基于组合物的重量）的非环烯烃聚合物改性剂; 和（c）至少10重量％（基于组合物的重量）为更多填料之一。 聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于100J / m，挠曲模量（1％割线法）大于1400MPa。

公开(公告)号：US07622534B2

公开(公告)日：2009-11-24

申请号：US11606673

申请日：2006-11-30

Applicant: Abhimanyu Onkar Patil ,  Karla Schall Colle

Inventor： Abhimanyu Onkar Patil ,  Karla Schall Colle

IPC: C08C19/06 ,  C08F8/08

CPC classification number: C08C19/06 ,  C08F8/08 ,  C08F2800/10 ,  C08F210/18 ,  C08F210/02

Abstract: A process for preparing an epoxidized α-olefin/diene copolymer including the steps of contacting in a reaction medium a) copolymers of an α-olefin and a diene, which copolymers contain at least one double bond in each diene-derived co-monomer, with b) a hydrogen peroxide epoxidizing agent, in the presence of a perfluorinated alcohol reaction solvent, and in the absence of any metal-containing epoxidation catalyst, under reaction conditions which promote formation of oxirane rings at the sites of the diene-derived co-monomer double bonds in the copolymeric precursor material.

Abstract translation: 一种制备环氧化的α-烯烃/二烯共聚物的方法，包括以下步骤：在反应介质中接触a）α-烯烃和二烯的共聚物，该共聚物在每个二烯衍生的共聚单体中含有至少一个双键， 其中b）过氧化氢环氧化剂，在全氟化醇反应溶剂存在下，在不存在任何含金属的环氧化催化剂的情况下，在促进二烯衍生的共聚物的位置处促进环氧乙烷环形成的反应条件下， 单体双键在共聚物前体材料中。

公开(公告)号：US20080132643A1

公开(公告)日：2008-06-05

申请号：US11606673

申请日：2006-11-30

Applicant: Abhimanyu Onkar Patil ,  Karla Schall Colle

Inventor： Abhimanyu Onkar Patil ,  Karla Schall Colle

IPC: C08F8/08 ,  C08L53/00 ,  C08L53/02

CPC classification number: C08C19/06 ,  C08F8/08 ,  C08F2800/10 ,  C08F210/18 ,  C08F210/02

Abstract: A process for preparing an epoxidized α-olefin/diene copolymer including the steps of contacting in a reaction medium a) copolymers of an α-olefin and a diene, which copolymers contain at least one double bond in each diene-derived co-monomer, with b) a hydrogen peroxide epoxidizing agent, in the presence of a perfluorinated alcohol reaction solvent, and in the absence of any metal-containing epoxidation catalyst, under reaction conditions which promote formation of oxirane rings at the sites of the diene-derived co-monomer double bonds in the copolymeric precursor material.

Abstract translation: 一种制备环氧化的α-烯烃/二烯共聚物的方法，包括以下步骤：在反应介质中接触a）α-烯烃和二烯的共聚物，该共聚物在每个二烯衍生的共聚单体中含有至少一个双键， 其中b）过氧化氢环氧化剂，在全氟化醇反应溶剂存在下，在不存在任何含金属的环氧化催化剂的条件下，在促进二烯衍生的共聚物的位置处促进环氧乙烷环形成的反应条件下， 单体双键在共聚物前体材料中。

公开(公告)号：US6015929A

公开(公告)日：2000-01-18

申请号：US23580

申请日：1998-02-13

Applicant: Manese Rabeony ,  Dennis George Peiffer ,  Christine Ann Costello ,  Karla Schall Colle ,  Pamela J Wright ,  Larry Dalton Talley

Inventor： Manese Rabeony ,  Dennis George Peiffer ,  Christine Ann Costello ,  Karla Schall Colle ,  Pamela J Wright ,  Larry Dalton Talley

IPC: C09K8/52 ,  C09K8/528 ,  C10L1/10 ,  C10L1/12 ,  C10L1/18 ,  C10L1/188 ,  C10L1/22 ,  C10L1/24 ,  C10L3/00 ,  C10L3/06 ,  C07C7/20 ,  F17D1/05

CPC classification number: C10L1/1881 ,  C09K8/52 ,  C09K8/528 ,  C10L1/2437 ,  C10L3/00 ,  C10L3/06 ,  C09K2208/22 ,  C10L1/10 ,  C10L1/125 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/232 ,  Y10S585/95

Abstract: This invention is directed toward a method for inhibiting the formation (nucleation, growth and agglomeration) of clathrate hydrates. The method comprises adding into a mixture of hydrate forming substituents and water, an effective amount of a hydrate anti-agglomerate selected from the group consisting of anionic, cationic, non-ionic and zwitterionic hydrate anti-agglomerate. The hydrate anti-agglomerant has a polar head group and a nonpolar tail group said nonpolar tail group not exceeding 11 carbon atoms in the longest carbon chain.

Abstract translation: 本发明涉及一种抑制包合物水合物的形成（成核，生长和附聚）的方法。 该方法包括向水合物形成取代基和水的混合物中加入有效量的选自阴离子，阳离子，非离子和两性离子水合物的防附聚物的水合物抗附聚物。 水合物抗附聚物具有极性头基和非极性尾基，所述非极性尾基在最长碳链中不超过11​​个碳原子。

公开(公告)号：US08263712B2

公开(公告)日：2012-09-11

申请号：US12231384

申请日：2008-09-02

Applicant: Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

Inventor： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

IPC: C08F8/04 ,  C08G61/08 ,  C08F4/80 ,  C07C255/31

CPC classification number: C08C19/02 ,  C08F4/80 ,  C08F232/00 ,  C08G61/08

Abstract: In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.

Abstract translation: 在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个 来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

公开(公告)号：US20100160506A1

公开(公告)日：2010-06-24

申请号：US12653742

申请日：2009-12-17

Applicant: Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  John Edmond Randolph Stanat

Inventor： Margaret May-Som Wu ,  Karla Schall Colle ,  Ramzi Yanni Saleh ,  Allen D. Godwin ,  John Edmond Randolph Stanat

IPC: C08K5/1515 ,  C08K5/109 ,  C07D301/03 ,  C07D317/24 ,  C07C1/207

CPC classification number: C07D317/36 ,  C08L21/00 ,  C10G3/44 ,  C10G3/48 ,  C10G29/205 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1092 ,  C10G2300/30 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/06 ,  C10G2400/10 ,  C10M107/10 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2270/00 ,  Y02P30/20

Abstract: This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.

Abstract translation: 本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。 更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。 在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。 还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。 或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。