公开(公告)号：US08546293B2

公开(公告)日：2013-10-01

申请号：US13607962

申请日：2012-09-10

Applicant: Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

Inventor： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC: B01J27/24

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

Abstract translation: 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。

公开(公告)号：US09149799B2

公开(公告)日：2015-10-06

申请号：US13093333

申请日：2011-04-25

Applicant: Andrey Karpov ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel

Inventor： Andrey Karpov ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel

IPC: B01J37/02 ,  C07C51/235 ,  B01J23/00 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/08

CPC classification number: B01J37/0219 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On  (I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.

Abstract translation: 一种蛋壳催化剂，其由长度为2-10mm，外径为4-10mm，壁厚为1-4mm的中空圆柱形支撑体和应用于支撑体外表面的蛋壳组成，催化活性氧化物材料 通式I，Mo12V2至4W0至3Cu0.8至1.5X10至4X20至400N（I），其中变量各自定义如下：X1 =碱金属和碱土金属的一种或多种元素; X2 = Si，Al，Ti和Zr组中的一种或多种元素; 并且n =元素氧的化学计量系数，其由除氧以外的元素的化学计量系数及其在I中的电荷确定。

公开(公告)号：US08618336B2

公开(公告)日：2013-12-31

申请号：US13271448

申请日：2011-10-12

Applicant: Josef Macht ,  Klaus Joachim Mueller-Engel ,  Frank Rosowski

Inventor： Josef Macht ,  Klaus Joachim Mueller-Engel ,  Frank Rosowski

IPC: C07C45/28

CPC classification number: C07C45/35 ,  C07C47/22

Abstract: A process for long-term operation of a heterogeneously catalyzed partial gas phase oxidation of propene to acrolein, in which the propene present in the reaction gas input mixture is partially oxidized as this gas mixture passes through the fixed catalyst bed which is accommodated in two spatially successive temperature zones A, B, and, in long-term operation, as a measure to counteract the reduction in the quality of the fixed catalyst bed, the temperature of at least one of the two temperature zones is increased such that the difference TB−TA becomes increasingly greater, where TB is the temperature of temperature zone B, and TA the temperature of temperature zone A.

Abstract translation: 长期运行丙烯到丙烯醛的非均相催化的部分气相氧化丙烯醛的方法，其中存在于反应气体输入混合物中的丙烯被部分氧化，因为该气体混合物通过固定的催化剂床，该催化剂床容纳在空间上 连续的温度区域A，B，并且在长期运行中，作为抵消固定催化剂床的质量降低的措施，两个温度区域中的至少一个的温度增加，使得TB- TA变得越来越大，其中TB是温度区B的温度，TA是温度区A的温度。

公开(公告)号：US20110275856A1

公开(公告)日：2011-11-10

申请号：US13093333

申请日：2011-04-25

Applicant: Andrey KARPOV ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Müller-Engel

Inventor： Andrey KARPOV ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Müller-Engel

IPC: C07C51/16 ,  B01J35/02 ,  B01J23/888

CPC classification number: B01J37/0219 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On  (I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.

Abstract translation: 一种蛋壳催化剂，其由长度为2-10mm，外径为4-10mm，壁厚为1-4mm的中空圆柱形支撑体和应用于支撑体外表面的蛋壳组成，催化活性氧化物材料 通式I，Mo12V2至4W0至3Cu0.8至1.5X10至4X20至400N（I），其中变量各自定义如下：X1 =碱金属和碱土金属的一种或多种元素; X2 = Si，Al，Ti和Zr组中的一种或多种元素; 并且n =元素氧的化学计量系数，其由除氧以外的元素的化学计量系数及其在I中的电荷确定。

公开(公告)号：US08686194B2

公开(公告)日：2014-04-01

申请号：US13546546

申请日：2012-07-11

Applicant: Josef Macht ,  Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Ulrich Hammon ,  Klaus Joachim Müller-Engel

Inventor： Josef Macht ,  Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Ulrich Hammon ,  Klaus Joachim Müller-Engel

IPC: C07C45/28 ,  B01J23/887

CPC classification number: B01J23/8872 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0215 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C01G39/00 ,  C01G39/006 ,  C01G51/006 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C07C5/00 ,  C07C45/35 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  C07C47/22

Abstract: Mo-, Bi- and Fe-comprising multimetal oxide compositions of the general stoichiometry I, Mo12BiaCobFecKdSieOx  (I), where a=0.5 to 1, b=7 to 8.5, c=1.5 to 3.0, d=0 to 0.15, e=0 to 2.5 and x=the stoichiometric coefficient of O2− which guarantees the electric neutrality of the multimetal oxide, and 12−b−1.5·c=A and 0.5≦A≦1.5, 0.2≦a/A≦1.3, and 2.5≦b/c≦9, and the use thereof.

Abstract translation: 含有Mo，Bi和Fe的多金属氧化物组合物，其中a = 0.5至1，b = 7至8.5，c = 1.5至3.0，d = 0至0.15，e = 0〜2.5，x =保证多金属氧化物电中性的O2-的化学计量系数，12-b-1.5·c = A和0.5＆nlE; A＆nlE; 1.5,0.2＆nlE; a / A＆nlE; 1.3和 2.5＆nlE; b / c＆nlE; 9及其使用。

公开(公告)号：US20130023699A1

公开(公告)日：2013-01-24

申请号：US13546546

申请日：2012-07-11

Applicant: Josef Macht ,  Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Ulrich Hammon ,  Klaus Joachim Mueller-Engel

Inventor： Josef Macht ,  Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Ulrich Hammon ,  Klaus Joachim Mueller-Engel

IPC: B01J23/887 ,  C07C45/28

CPC classification number: B01J23/8872 ,  B01J35/002 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0215 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C01G39/00 ,  C01G39/006 ,  C01G51/006 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C07C5/00 ,  C07C45/35 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  C07C47/22

Abstract: Mo-, Bi- and Fe-comprising multimetal oxide compositions of the general stoichiometry I, Mo12BiaCobFecKdSieOx  (I), where a=0.5 to 1, b=7 to 8.5, c=1.5 to 3.0, d=0 to 0.15, e=0 to 2.5 and x=the stoichiometric coefficient of O2− which guarantees the electric neutrality of the multimetal oxide, and 12−b−1.5·c=A and 0.5≦A≦1.5, 0.2≦a/A≦1.3, and 2.5≦b/c≦9, and the use thereof.

Abstract translation: 含有Mo，Bi和Fe的多金属氧化物组合物，其中a = 0.5至1，b = 7至8.5，c = 1.5至3.0，d = 0至0.15，e = 0〜2.5，x =保证多金属氧化物电中性的O2-的化学计量系数，12-b-1.5·c = A和0.5＆nlE; A＆nlE; 1.5,0.2＆nlE; a / A＆nlE; 1.3和 2.5＆nlE; b / c＆nlE; 9及其使用。

公开(公告)号：US08298980B2

公开(公告)日：2012-10-30

申请号：US12634149

申请日：2009-12-09

Applicant: Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

Inventor： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC: B01J27/25

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

Abstract translation: 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。

公开(公告)号：US20120095267A1

公开(公告)日：2012-04-19

申请号：US13271448

申请日：2011-10-12

Applicant: Josef MACHT ,  Klaus Joachim Müller-Engel ,  Frank Rosowski

Inventor： Josef MACHT ,  Klaus Joachim Müller-Engel ,  Frank Rosowski

IPC: C07C45/28

CPC classification number: C07C45/35 ,  C07C47/22

Abstract: A process for long-term operation of a heterogeneously catalyzed partial gas phase oxidation of propene to acrolein, in which the propene present in the reaction gas input mixture is partially oxidized as this gas mixture passes through the fixed catalyst bed which is accommodated in two spatially successive temperature zones A, B, and, in long-term operation, as a measure to counteract the reduction in the quality of the fixed catalyst bed, the temperature of at least one of the two temperature zones is increased such that the difference TB−TA becomes increasingly greater, where TB is the temperature of temperature zone B, and TA the temperature of temperature zone A.

Abstract translation: 长期运行丙烯到丙烯醛的非均相催化的部分气相氧化丙烯醛的方法，其中存在于反应气体输入混合物中的丙烯被部分氧化，因为该气体混合物通过固定的催化剂床，该催化剂床容纳在空间上 连续的温度区域A，B，并且在长期运行中，作为抵消固定催化剂床的质量降低的措施，两个温度区域中的至少一个的温度增加，使得TB- TA变得越来越大，其中TB是温度区B的温度，TA是温度区A的温度。

公开(公告)号：US08399711B2

公开(公告)日：2013-03-19

申请号：US12954770

申请日：2010-11-26

Applicant: Josef Macht ,  Andreas Raichle ,  Klaus Joachim Mueller-Engel ,  Ulrich Hammon

Inventor： Josef Macht ,  Andreas Raichle ,  Klaus Joachim Mueller-Engel ,  Ulrich Hammon

IPC: C07C45/35

CPC classification number: B01J23/002 ,  B01J23/8885 ,  B01J35/023 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C07C45/35 ,  C07C47/22 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845

Abstract: A process for preparing (meth)acrolein by heterogeneously catalyzed gas phase partial oxidation of a precursor compound, in which the reaction gas mixture which comprises at least 3% by volume of precursor compound is passed through a fresh fixed catalyst bed whose active material is a multielement oxide which comprises the elements Mo, Fe and Bi and at least one of the elements Ni and Co, and the fixed catalyst bed is loaded with at least 40 l (STP)/l·h of precursor compound, and the precursor compound is converted to an extent of at least 90 mol %, wherein, over the first 8000 operating hours, during X=10 to 500 operating hours, the highest temperature of the reaction gas mixture in the fixed catalyst bed is 400 to 450° C. and, during the remaining 8000−X operating hours, is 300 to

Abstract translation: 通过前体化合物的非均相催化气相部分氧化制备（甲基）丙烯醛的方法，其中将包含至少3体积％的前体化合物的反应气体混合物通过新鲜的固定催化剂床，活性材料为 包含元素Mo，Fe和Bi以及元素Ni和Co中的至少一种和固定催化剂床的多元素氧化物装载至少40μl（STP）/ l·h的前体化合物，前体化合物是 转化为至少90摩尔％的程度，其中，在第一个8000个工作小时内，在X = 10至500个操作小时期间，固定催化剂床中的反应气体混合物的最高温度为400至450℃， 在剩余的8000-X工作时间内，为300至<400℃，并且在X = 10至500个工作小时的时间内，平均有机前体化合物的固定催化剂床的负载大于 8000-X营业时间。

公开(公告)号：US20130006009A1

公开(公告)日：2013-01-03

申请号：US13607962

申请日：2012-09-10

Applicant: Andreas RAICHLE ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Catharina Horstmann ,  Josef Macht

Inventor： Andreas RAICHLE ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC: C07C45/28 ,  C07C51/16 ,  C07C253/00

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

Abstract translation: 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。