公开(公告)号：US20110275856A1

公开(公告)日：2011-11-10

申请号：US13093333

申请日：2011-04-25

申请人： Andrey KARPOV ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Müller-Engel

发明人： Andrey KARPOV ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Müller-Engel

IPC分类号： C07C51/16 ,  B01J35/02 ,  B01J23/888

CPC分类号： B01J37/0219 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On  (I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.

摘要翻译： 一种蛋壳催化剂，其由长度为2-10mm，外径为4-10mm，壁厚为1-4mm的中空圆柱形支撑体和应用于支撑体外表面的蛋壳组成，催化活性氧化物材料 通式I，Mo12V2至4W0至3Cu0.8至1.5X10至4X20至400N（I），其中变量各自定义如下：X1 =碱金属和碱土金属的一种或多种元素; X2 = Si，Al，Ti和Zr组中的一种或多种元素; 并且n =元素氧的化学计量系数，其由除氧以外的元素的化学计量系数及其在I中的电荷确定。

公开(公告)号：US09149799B2

公开(公告)日：2015-10-06

申请号：US13093333

申请日：2011-04-25

申请人： Andrey Karpov ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel

发明人： Andrey Karpov ,  Catharina Horstmann ,  Cornelia Katharina Dobner ,  Josef Macht ,  Frank Rosowski ,  Klaus Joachim Mueller-Engel

IPC分类号： B01J37/02 ,  C07C51/235 ,  B01J23/00 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/08

CPC分类号： B01J37/0219 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J37/0045 ,  B01J37/0221 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/235 ,  C07C57/04 ,  B01J2523/17 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On  (I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.

摘要翻译： 一种蛋壳催化剂，其由长度为2-10mm，外径为4-10mm，壁厚为1-4mm的中空圆柱形支撑体和应用于支撑体外表面的蛋壳组成，催化活性氧化物材料 通式I，Mo12V2至4W0至3Cu0.8至1.5X10至4X20至400N（I），其中变量各自定义如下：X1 =碱金属和碱土金属的一种或多种元素; X2 = Si，Al，Ti和Zr组中的一种或多种元素; 并且n =元素氧的化学计量系数，其由除氧以外的元素的化学计量系数及其在I中的电荷确定。

公开(公告)号：US20130006009A1

公开(公告)日：2013-01-03

申请号：US13607962

申请日：2012-09-10

申请人： Andreas RAICHLE ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Catharina Horstmann ,  Josef Macht

发明人： Andreas RAICHLE ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC分类号： C07C45/28 ,  C07C51/16 ,  C07C253/00

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

摘要翻译： 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。

公开(公告)号：US20100152475A1

公开(公告)日：2010-06-17

申请号：US12634149

申请日：2009-12-09

申请人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Catharina Horstmann ,  Josef Macht

发明人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Müller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC分类号： C07C255/08 ,  B01J27/20 ,  B01J27/24 ,  B01J27/25 ,  B01J23/18 ,  B01J23/28 ,  C07C51/25 ,  C07C45/28 ,  B01J23/22

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

摘要翻译： 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。

公开(公告)号：US08822371B2

公开(公告)日：2014-09-02

申请号：US12546883

申请日：2009-08-25

申请人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Müller-Engel ,  Holger Borchert ,  Gerhard Cox ,  Ulrich Cremer

发明人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Müller-Engel ,  Holger Borchert ,  Gerhard Cox ,  Ulrich Cremer

IPC分类号： B01J23/00

CPC分类号： C07C45/28 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/04 ,  B01J2523/00 ,  C07C45/35 ,  C07C45/37 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [Bi1WbOx]a[Mo12Z1cZ2dFeeZ3fZ4gZ5nOy]1, in which a finely divided oxide Bi1WbOx with the particle size d50A1 and, formed from element sources, a finely divided intimate mixture of stoichiometry Mo12Z1cZ2dFeeZ3fZ4gZ5h with the particle size d50A2 are mixed in a ratio of a:1, this mixture is used to form shaped bodies and these are treated thermally, where (d50A1)0.7·(d90A1)1.5·(a)−1≧820.

摘要翻译： 一种用于生产几何形状的催化剂体K的方法，其活性材料是化学计量[Bi1WbOx] a [Mo12Z1cZ2dFeeZ3fZ4gZ5nOy] 1的多元素氧化物，其中具有粒度d50A1的细分离氧化物Bi1WbOx，并且由元素源形成， 化学计量比Mo2Z1cZ2dFeeZ3fZ4gZ5h与粒径d50A2的混合物以a:1的比例混合，该混合物用于形成成型体，热处理，其中（d50A1）0.7·（d90A1）1.5·（a）-1≧ 820。

公开(公告)号：US20100069660A1

公开(公告)日：2010-03-18

申请号：US12557021

申请日：2009-09-10

申请人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Müller-Engel ,  Jochen Petzoldt ,  Ulrich Cremer

发明人： Andreas Raichle ,  Catharina Horstmann ,  Frank Rosowski ,  Klaus Joachim Müller-Engel ,  Jochen Petzoldt ,  Ulrich Cremer

IPC分类号： B01J21/06 ,  C07C45/27 ,  C07C255/00

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8885 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/34 ,  B01J2523/00 ,  C07C45/35 ,  C07C45/37 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [BiaZ1bOx]p[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy]1, in which a finely divided oxide BiaZ1bOx and, formed from element sources, a finely divided mixture of stoichiometry BicMo12FedZ2eZ3fZ4gZ5hZ6i are mixed in a ratio of p:1, this mixture is used to form shaped bodies and these are treated thermally, where 0

摘要翻译： 用于生产几何形状的催化剂体K的方法，其活性材料是化学计量的多元素氧化物[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy] 1，其中细分的氧化物BiaZ1bOx和由元素源形成的细分的化学计量比BicMo 12 FedZ 2eZ 3 fZ 4 gZ 5hZ 6i的混合物混合 以p：1的比例，将该混合物用于形成成形体，并将它们热处理，其中0

公开(公告)号：US08202814B2

公开(公告)日：2012-06-19

申请号：US12025448

申请日：2008-02-04

申请人： Martin Dieterle ,  Götz-Peter Schindler ,  Catharina Horstmann ,  Klaus Joachim Müller-Engel

发明人： Martin Dieterle ,  Götz-Peter Schindler ,  Catharina Horstmann ,  Klaus Joachim Müller-Engel

IPC分类号： B01J38/04

CPC分类号： B01J23/96 ,  B01J38/20 ,  C07C5/48 ,  C07C51/252 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/63 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C57/04

摘要： A process for regenerating a catalyst bed deactivated in the course of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon, in which a gas comprising molecular oxygen is conducted at elevated temperature through the deactivated catalyst bed and, in the course of the regeneration, the content of molecular oxygen in the regeneration gas is increased repeatedly and the increase in the carbon oxide content of the regeneration gas as it flows through the deactivated catalyst bed is restricted to values of ≦5% by volume.

摘要翻译： 在烃的非均相催化部分脱氢过程中使催化剂床再生失活的方法，其中包含分子氧的气体在高温下通过失活的催化剂床进行，并且在再生过程中， 再生气体中的分子氧反复增加，并且再生气体在流过失活催化剂床时的碳氧化物含量的增加被限制为±10体积％的量。

公开(公告)号：US08298980B2

公开(公告)日：2012-10-30

申请号：US12634149

申请日：2009-12-09

申请人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

发明人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC分类号： B01J27/25

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

摘要翻译： 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。

公开(公告)号：US08546293B2

公开(公告)日：2013-10-01

申请号：US13607962

申请日：2012-09-10

申请人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

发明人： Andreas Raichle ,  Holger Borchert ,  Klaus Joachim Mueller-Engel ,  Catharina Horstmann ,  Josef Macht

IPC分类号： B01J27/24

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/8876 ,  B01J23/8877 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/009 ,  B01J2523/00 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  Y02P20/582 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845 ,  C07C255/08 ,  B01J2523/15 ,  B01J2523/17 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/62

摘要： A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.

摘要翻译： 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，​​其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。

公开(公告)号：US08609906B2

公开(公告)日：2013-12-17

申请号：US12967337

申请日：2010-12-14

申请人： Annebart Engbert Wentink ,  Stefan Altwasser ,  Yan Li ,  Michael Krämer ,  Frank Rosowski ,  Catharina Horstmann

发明人： Annebart Engbert Wentink ,  Stefan Altwasser ,  Yan Li ,  Michael Krämer ,  Frank Rosowski ,  Catharina Horstmann

IPC分类号： C07C27/00

CPC分类号： C07C29/50 ,  C07C45/33 ,  C07C51/215 ,  C07C31/04 ,  C07C47/22 ,  C07C57/04

摘要： A process for preparing C1-C4-oxygenates from a reactant stream A which comprises essentially a C1-C4-alkane or a mixture of C1-C4-alkanes, by a) branching off a substream B of the reactant stream A and allowing it to react in a reactor with oxygen or an oxygenous gas stream C, which converts a portion of the C1-C4-alkane or a portion of the mixture which comprises C1-C4-alkanes to C1-C4-oxygenates, b) removing at least 90 mol % of the C1-C4-oxygenates formed from the product stream D resulting from step a) to form a remaining low boiler stream E, which comprises combining the low boiler stream E with the reactant stream A without further workup and without combination with the substream B down-stream of the branching site of the substream B.

摘要翻译： a）从反应物流A制备C1-C4-含氧化合物的方法，该反应物流A基本上包含C 1 -C 4烷烃或C 1 -C 4烷烃的混合物，a）将反应物流A的分支B分支， 在反应器中与氧或有氧气流C反应，C将C1-C4烷烃的一部分或包含C1-C4烷烃的混合物的一部分转化为C1-C4-氧化物，b）除去至少90 由步骤a）产生的产物流D形成的C1-C4-含氧化合物的摩尔％，以形成剩余的低沸点物流E，其包括将低沸点物流E与反应物流A组合而不进一步处理，并且不与 子流B的分支位点下游的子流B