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1.发明授权Optimized introduction of the starting materials for a process for preparing aromatic amines by hydrogenation of nitroaromatics 有权通过硝基芳族化合物的氢化优化引入用于制备芳族胺的方法的原料公开(公告)号：US08835688B2
公开(公告)日：2014-09-16
申请号：US13421453
申请日：2012-03-15
Applicant: Gerrit Waters , Johannes Buettner , Andreas Raichle , Markus Hiller , Peter Renze , Michael Herrich , Helmut Rueger , Burkhard Hantel , Arndt Hofmann , Ruediger Fritz , Kathrin Richter , Holgar Braunsberg , Lothar Bruntsch
Inventor： Gerrit Waters , Johannes Buettner , Andreas Raichle , Markus Hiller , Peter Renze , Michael Herrich , Helmut Rueger , Burkhard Hantel , Arndt Hofmann , Ruediger Fritz , Kathrin Richter , Holgar Braunsberg , Lothar Bruntsch
IPC: C07C209/00 , B01J8/22 , C07C209/36
CPC classification number: B01J19/26 , B01J8/226 , B01J8/228 , B01J2208/00123 , B01J2208/00132 , B01J2208/00141 , B01J2208/0015 , B01J2208/00902 , B01J2208/00911 , B01J2219/00761 , C07C209/36 , C07C211/50
Abstract: The invention relates to a process for preparing aromatic amines by hydrogenation of corresponding nitroaromatics by means of hydrogen, and also an apparatus suitable for this purpose. In particular, the invention relates to a process for preparing toluenediamine (TDA) by hydrogenation of dinitrotoluene (DNT).
Abstract translation: 本发明涉及通过氢气对相应的硝基芳族化合物进行氢化制备芳族胺的方法，以及适用于该目的的装置。 特别地，本发明涉及通过氢化二硝基甲苯（DNT）制备甲苯二胺（TDA）的方法。
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公开(公告)号：US08298980B2
公开(公告)日：2012-10-30
申请号：US12634149
申请日：2009-12-09
Applicant: Andreas Raichle , Holger Borchert , Klaus Joachim Mueller-Engel , Catharina Horstmann , Josef Macht
Inventor： Andreas Raichle , Holger Borchert , Klaus Joachim Mueller-Engel , Catharina Horstmann , Josef Macht
IPC: B01J27/25
CPC classification number: C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8877 , B01J35/023 , B01J37/0009 , B01J37/009 , B01J2523/00 , C07C45/35 , C07C253/26 , Y02P20/52 , Y02P20/582 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , C07C255/08 , B01J2523/15 , B01J2523/17 , B01J2523/51 , B01J2523/53 , B01J2523/55 , B01J2523/62
Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V−, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V− are comminuted and recycled into the obtaining of the finely divided mixture.
Abstract translation: 一种用于生产几何形状的催化剂体K的方法，其活性材料是多元素氧化物，其包含元素Mo，元素Bi和/或V以及元素Co，Ni，Fe，Cu和碱金属中的一种或多种，其中源 的不同元素用于获得通过压力附聚而粗化为粉末的细碎混合物，粗大的粉末用于通过压制附聚形成被分离成未损坏的成形体V +的成形体V和损坏的成形体 V-，未损坏的成形体V +通过热处理转化成成形的催化剂体K，并且损坏的成形体V-被粉碎并再循环到获得细碎的混合物中。
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公开(公告)号：US20120215029A1
公开(公告)日：2012-08-23
申请号：US13311371
申请日：2011-12-05
Applicant: Stefanie Haase , Dusko Kadijevic , Anne-Kathrin Merten , Michael Zoellinger , Andreas Raichle , Alexander Schocker , Sandra Mühlbeyer , Olaf Wiedenhoff , Joana Coelho Tsou
Inventor： Stefanie Haase , Dusko Kadijevic , Anne-Kathrin Merten , Michael Zoellinger , Andreas Raichle , Alexander Schocker , Sandra Mühlbeyer , Olaf Wiedenhoff , Joana Coelho Tsou
IPC: C07C209/36 , B01J19/00
CPC classification number: C07C229/36 , B01J8/228 , B01J21/066 , B01J23/755 , B01J35/023 , B01J37/0036 , B01J2208/00132 , B01J2208/00752 , B01J2219/00202 , B01J2219/00231 , B01J2219/0024 , C07C209/34 , C07C209/36 , C07C211/58 , C07C211/51 , C07C211/46 , C07C211/47 , C07C211/27
Abstract: A process for preparing aromatic amines by hydrogenation of nitroaromatics in the presence of catalysts, forming a fluid, amine-comprising reaction mixture in a reactor, wherein chromatographic analysis of the reaction mixture is carried out to determine the concentration of nitro and nitroso compounds in the reaction mixture.
Abstract translation: 一种通过在催化剂存在下氢化硝基芳族化合物制备芳族胺的方法，在反应器中形成含流体的含胺反应混合物，其中进行反应混合物的色谱分析以测定硝基和亚硝基化合物的浓度 反应混合物。
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公开(公告)号：US20120197047A1
公开(公告)日：2012-08-02
申请号：US13362607
申请日：2012-01-31
Applicant: Holger ALLARDT , Andreas RAICHLE , Reiner REETZ , Johannes BÜTTNER , Michael ZÖLLINGER , Stefanie HAASE , Rüdiger FRITZ
Inventor： Holger ALLARDT , Andreas RAICHLE , Reiner REETZ , Johannes BÜTTNER , Michael ZÖLLINGER , Stefanie HAASE , Rüdiger FRITZ
IPC: C07C201/12 , B01J47/00
CPC classification number: B01J39/02 , B01J39/05 , B01J47/026 , B01J49/06 , B01J49/60 , B01J2220/56 , C07C201/16 , C07C205/06
Abstract: Precipitations of nitrohydroxyaromatic salts out of the nitrated crude products obtained in the nitration of aromatic compounds after alkaline scrubbing, for example mononitrotoluenes, are prevented by contacting the nitrated crude products with an acidic ion exchanger. The nitrated crude products are preferably selected from a feedstream to a distillation column, a bottoms circulation stream of a distillation column and a feedstream to a vaporizer.
Abstract translation: 通过使硝化粗产物与酸性离子交换剂接触，可以防止碱性洗涤后芳族化合物硝化的硝化羟基芳族化合物的沉淀，例如单硝基甲苯。 硝化粗产物优选选自蒸馏塔的进料流，蒸馏塔的塔底循环流和蒸发器的进料流。
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5.发明授权公开(公告)号：US08076510B2
公开(公告)日：2011-12-13
申请号：US12107420
申请日：2008-04-22
Applicant: Ulrich Hammon , Thorsten Friese , Jochen Petzoldt , Klaus Joachim Mueller-Engel , Ulrich Cremer , Andreas Raichle
Inventor： Ulrich Hammon , Thorsten Friese , Jochen Petzoldt , Klaus Joachim Mueller-Engel , Ulrich Cremer , Andreas Raichle
IPC: C07C51/16
CPC classification number: B01J8/067 , B01J23/002 , B01J23/8885 , B01J27/199 , B01J35/0006 , B01J2208/00212 , B01J2208/00221 , B01J2208/00513 , B01J2208/025 , B01J2219/30207 , B01J2219/30215 , B01J2523/00 , C07C51/235 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/17 , B01J2523/55 , B01J2523/15 , B01J2523/51 , B01J2523/53 , B01J2523/62
Abstract: A process for starting-up a heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid or of methacrolein to methacrylic acid over a fixed catalyst bed disposed in a tube bundle reactor cooled by a heat exchange medium, wherein the temperature of the heat exchange medium is ≧290° C. and the temperature of that reactor plate surface which faces the reaction gas entry mixture and the temperature of the reaction gas entry mixture itself are ≦285° C.
Abstract translation: 一种在由热交换介质冷却的管束反应器中的固定催化剂床上启动丙烯醛异丙烯醛至丙烯醛或甲基丙烯醛至甲基丙烯酸的非均相催化部分气相氧化方法，其中热交换介质的温度 ≧290℃，反应气体入口混合物的反应器板表面的温度和反应气体入口混合物本身的温度为285℃
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Patent Agency Ranking
6.发明申请PROCESS FOR CHARGING A REACTOR WITH A FIXED CATALYST BED WHICH COMPRISES AT LEAST ANNULAR SHAPED CATALYST BODIES K 有权用固定的催化剂床充入反应器的过程，其中包含最小的形状催化剂体系K公开(公告)号：US20080312477A1
公开(公告)日：2008-12-18
申请号：US12138823
申请日：2008-06-13
Applicant: Andreas Raichle , Holger Borchert , Klaus Joachim Muller-Engel , Hagen Wilmer , Cornelia Dobner , Ulrich Cremer
Inventor： Andreas Raichle , Holger Borchert , Klaus Joachim Muller-Engel , Hagen Wilmer , Cornelia Dobner , Ulrich Cremer
CPC classification number: B07B1/469 , B01J8/0015 , B01J8/06 , B01J23/002 , B01J35/026 , B01J37/009 , B01J2208/00672 , B01J2208/00769 , B01J2208/025 , B01J2219/30215 , B01J2219/30475 , B01J2523/00 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845
Abstract: A process for charging a reactor with a fixed catalyst bed which comprises at least one annular shaped support catalyst body K, in which, before the charging, fragments formed in the preparation of the shaped catalyst bodies K are removed by screening.
Abstract translation: 一种用固定催化剂床装载反应器的方法，该反应器包括至少一个环形的载体催化剂体K，其中在装料之前，通过筛选除去在成形催化剂体K的制备中形成的碎片。
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7.发明授权公开(公告)号：US08609899B2
公开(公告)日：2013-12-17
申请号：US13109399
申请日：2011-05-17
Applicant: Andreas Raichle , Joana Coelho Tsou , Samuel Neto , Ulrich Penzel , Steffen Oehlenschlaeger , Michael Zoellinger , Holgar Braunsberg , Stefanie Haase , Johannes Buettner
Inventor： Andreas Raichle , Joana Coelho Tsou , Samuel Neto , Ulrich Penzel , Steffen Oehlenschlaeger , Michael Zoellinger , Holgar Braunsberg , Stefanie Haase , Johannes Buettner
IPC: C07C209/00
CPC classification number: C07C209/36 , C07C211/49
Abstract: The invention relates to a process for the continuous preparation of toluenediamine by liquid-phase hydrogenation of dinitrotoluene by means of hydrogen in the presence of a suspended, nickel-comprising catalyst in a reactor with a product isolation unit downstream of the reactor to give a product output from the reactor comprising a liquid phase comprising toluenediamine and dinitrotoluene, in which the nickel-comprising catalyst is suspended, wherein the concentration of dinitrotoluene in the liquid phase of the product output from the reactor in the region between the reactor and the downstream product isolation unit is set to a value in the range from 1 to 200 ppm by weight, based on the total weight of the liquid phase of the product output from the reactor.
Abstract translation: 本发明涉及通过在反应器中的悬浮的含镍催化剂存在下，借助于氢气对二硝基甲苯进行液相氢化来连续制备甲苯二胺的方法，该反应器具有在反应器下游的产物隔离单元以产生产物 从包括甲苯二胺和二硝基甲苯的液相的反应器输出，其中悬浮有含镍催化剂，其中在反应器和下游产物隔离之间的区域中从反应器输出的产物的液相中二硝基甲苯的浓度 基于从反应器输出的产物的液相的总重量，单位设定在1至200重量ppm的范围内的值。
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8.发明授权Process for preparing a multielement oxide composition comprising the element iron in oxidic form 有权制备包含氧化形式的元素铁的多元素氧化物组合物的方法公开(公告)号：US08128904B2
公开(公告)日：2012-03-06
申请号：US12013693
申请日：2008-01-14
Applicant: Andreas Raichle , Holger Borchert , Klaus Joachim Müller-Engel , Ulrich Cremer
Inventor： Andreas Raichle , Holger Borchert , Klaus Joachim Müller-Engel , Ulrich Cremer
IPC: B01J23/00
CPC classification number: C01G49/009 , C01G49/00
Abstract: A process for preparing a multielement oxide composition comprising the element iron in oxidic form, in which the source of the elemental constituent of iron used is an aqueous iron nitrate solution whose preparation comprises the melting of a solid hydrate of iron nitrate.
Abstract translation: 一种制备多元氧化物组合物的方法，其包含氧化形式的元素铁，其中所用铁的元素成分源是硝酸铁水溶液，其制备方法包括硝酸铁的固体水合物的熔融。
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9.发明申请公开(公告)号：US20110295039A1
公开(公告)日：2011-12-01
申请号：US13109399
申请日：2011-05-17
Applicant: Andreas Raichle , Joana Coelho Tsou , Samuel Neto , Ulrich Penzel , Steffen Oehlenschläger , Michael Zöllinger , Holgar Braunsberg , Stefanie Haase , Johannes Büttner
Inventor： Andreas Raichle , Joana Coelho Tsou , Samuel Neto , Ulrich Penzel , Steffen Oehlenschläger , Michael Zöllinger , Holgar Braunsberg , Stefanie Haase , Johannes Büttner
IPC: C07C209/36
CPC classification number: C07C209/36 , C07C211/49
Abstract: The invention relates to a process for the continuous preparation of toluenediamine by liquid-phase hydrogenation of dinitrotoluene by means of hydrogen in the presence of a suspended, nickel-comprising catalyst in a reactor with a product isolation unit downstream of the reactor to give a product output from the reactor comprising a liquid phase comprising toluenediamine and dinitrotoluene, in which the nickel-comprising catalyst is suspended, wherein the concentration of dinitrotoluene in the liquid phase of the product output from the reactor in the region between the reactor and the downstream product isolation unit is set to a value in the range from 1 to 200 ppm by weight, based on the total weight of the liquid phase of the product output from the reactor.
Abstract translation: 本发明涉及通过在反应器中的悬浮的含镍催化剂存在下，借助于氢气对二硝基甲苯进行液相氢化来连续制备甲苯二胺的方法，该反应器具有在反应器下游的产物隔离单元以产生产物 从包括甲苯二胺和二硝基甲苯的液相的反应器输出，其中悬浮有含镍催化剂，其中在反应器和下游产物隔离区域之间从反应器输出的产物的液相中二硝基甲苯的浓度 基于从反应器输出的产物的液相的总重量，单位设定在1至200重量ppm的范围内的值。
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公开(公告)号：US20100069660A1
公开(公告)日：2010-03-18
申请号：US12557021
申请日：2009-09-10
Applicant: Andreas Raichle , Catharina Horstmann , Frank Rosowski , Klaus Joachim Müller-Engel , Jochen Petzoldt , Ulrich Cremer
Inventor： Andreas Raichle , Catharina Horstmann , Frank Rosowski , Klaus Joachim Müller-Engel , Jochen Petzoldt , Ulrich Cremer
IPC: B01J21/06 , C07C45/27 , C07C255/00
CPC classification number: C07C51/252 , B01J23/002 , B01J23/8885 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/0221 , B01J37/34 , B01J2523/00 , C07C45/35 , C07C45/37 , C07C253/26 , Y02P20/52 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , C07C255/08
Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide of stoichiometry [BiaZ1bOx]p[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy]1, in which a finely divided oxide BiaZ1bOx and, formed from element sources, a finely divided mixture of stoichiometry BicMo12FedZ2eZ3fZ4gZ5hZ6i are mixed in a ratio of p:1, this mixture is used to form shaped bodies and these are treated thermally, where 0
Abstract translation: 用于生产几何形状的催化剂体K的方法，其活性材料是化学计量的多元素氧化物[BicMo12FedZ2eZ3fZ4gZ5hZ6iOy] 1，其中细分的氧化物BiaZ1bOx和由元素源形成的细分的化学计量比BicMo 12 FedZ 2eZ 3 fZ 4 gZ 5hZ 6i的混合物混合 以p：1的比例，将该混合物用于形成成形体，并将它们热处理，其中0
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