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1.发明授权Process for producing a nanoporous layer of nanoparticles and layer thus obtained 有权制备由此获得的纳米多孔纳米颗粒层和层的方法公开(公告)号：US08137442B2
公开(公告)日：2012-03-20
申请号：US12298057
申请日：2007-04-25
申请人： Bruno Pintault , David Guenadou , Luc Bianchi , Philippe Belleville , Karine Valle , Christophe Boscher , Joël Toulc'Hoat
发明人： Bruno Pintault , David Guenadou , Luc Bianchi , Philippe Belleville , Karine Valle , Christophe Boscher , Joël Toulc'Hoat
CPC分类号： C04B41/85 , B01D61/027 , B01D61/145 , B01D67/0048 , B01D67/0069 , B01D69/02 , B01D69/12 , B01D71/024 , B01D2323/34 , B01D2323/42 , B01D2325/022 , B01D2325/023 , C04B41/009 , C04B41/5089 , C04B41/52 , C04B41/89 , C04B2111/00801 , C23C4/11 , C23C4/134 , Y10S55/05 , Y10T428/249969 , C04B41/4527 , C04B41/4582 , C04B41/5031 , C04B41/4933 , C04B35/10 , C04B35/00 , C04B35/46 , C04B35/478 , C04B38/00
摘要： Process for producing at least one nanoporous layer of nanoparticles chosen from nanoparticles of a metal oxide, nanoparticles of metal oxides, and mixtures of said nanoparticles, on a surface of a substrate, in which at least one colloidal sol, in which said nanoparticles are dispersed and stabilized, is injected into a thermal plasma jet which sprays said nanoparticles onto said surface.Nanoporous layer and device, especially a separation device, comprizing said layer.
摘要翻译： 用于生产选自金属氧化物的纳米颗粒，金属氧化物纳米颗粒和所述纳米颗粒的纳米颗粒的纳米多孔纳米多孔层在基材表面上的方法，其中至少一种其中所述纳米颗粒分散的胶体溶胶 并稳定化，注入到将所述纳米颗粒喷射到所述表面上的热等离子体射流中。 纳米多孔层和器件，特别是分离装置，包括所述层。
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公开(公告)号：US20080090071A1
公开(公告)日：2008-04-17
申请号：US11577257
申请日：2005-10-20
CPC分类号： C23C4/123 , Y10T428/26 , Y10T428/265
摘要： The present invention relates to a method of coating a surface with nanoparticles, to a nanostructured coating that can be obtained by this method, and also to a device for implementing the method of the invention. The method is characterized in that it comprises an injection of a colloidal sol of said nanoparticles into a plasma jet that sprays them onto said surface. The device (1) comprises: a plasma torch (3); at least one container (5) containing the colloidal sol (7) of nanoparticles; a device (9) for fixing and for moving the substrate(S); and a device (11) for injecting the colloidal sol into the plasma jet (13) of the plasma torch. The present invention has applications in optical, electronic and energy devices (cells, thermal barriers) comprising a nanostructured coating that can be obtained by the method of the invention.
摘要翻译： 本发明涉及一种用纳米颗粒涂覆表面的方法，可以通过该方法获得的纳米结构涂层以及用于实现本发明的方法的装置。 该方法的特征在于，其包括将所述纳米颗粒的胶态溶胶注入等离子体射流，将其喷射到所述表面上。 装置（1）包括：等离子体焰炬（3）; 含有纳米粒子的胶体溶胶（7）的至少一个容器（5） 用于固定和移动衬底（S）的装置（9）; 以及用于将胶体溶胶注入到等离子体焰炬的等离子体射流（13）中的装置（11）。 本发明在光学，电子和能量装置（电池，热障碍）中的应用，其包括可以通过本发明的方法获得的纳米结构涂层。
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3.发明申请公开(公告)号：US20090241496A1
公开(公告)日：2009-10-01
申请号：US12298057
申请日：2007-04-25
申请人： Bruno Pintault , David Guenadou , Luc Bianchi , Philippe Belleville , Karine Valle , Christophe Boscher , Jöel Toulc'Hoat
发明人： Bruno Pintault , David Guenadou , Luc Bianchi , Philippe Belleville , Karine Valle , Christophe Boscher , Jöel Toulc'Hoat
CPC分类号： C04B41/85 , B01D61/027 , B01D61/145 , B01D67/0048 , B01D67/0069 , B01D69/02 , B01D69/12 , B01D71/024 , B01D2323/34 , B01D2323/42 , B01D2325/022 , B01D2325/023 , C04B41/009 , C04B41/5089 , C04B41/52 , C04B41/89 , C04B2111/00801 , C23C4/11 , C23C4/134 , Y10S55/05 , Y10T428/249969 , C04B41/4527 , C04B41/4582 , C04B41/5031 , C04B41/4933 , C04B35/10 , C04B35/00 , C04B35/46 , C04B35/478 , C04B38/00
摘要： Process for producing at least one nanoporous layer of nanoparticles chosen from nanoparticles of a metal oxide, nanoparticles of metal oxides, and mixtures of said nanoparticles, on a surface of a substrate, in which at least one colloidal sol, in which said nanoparticles are dispersed and stabilized, is injected into a thermal plasma jet which sprays said nanoparticles onto said surface.Nanoporous layer and device, especially a separation device, comprizing said layer.
摘要翻译： 用于生产选自金属氧化物的纳米颗粒，金属氧化物纳米颗粒和所述纳米颗粒的纳米颗粒的纳米多孔纳米多孔层在基材表面上的方法，其中至少一种其中所述纳米颗粒分散的胶体溶胶 并稳定化，注入到将所述纳米颗粒喷射到所述表面上的热等离子体射流中。 纳米多孔层和器件，特别是分离装置，包括所述层。
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4.发明申请Organic-inorganic hybrid material containing a mineral mesoporous phase and an organic phase, a membrane and fuel cell 有权含有矿物介孔相和有机相的有机 - 无机杂化材料，膜和燃料电池公开(公告)号：US20060194096A1
公开(公告)日：2006-08-31
申请号：US10542768
申请日：2004-01-22
CPC分类号： C08J5/2275 , B01D67/0079 , B01D69/141 , B01D71/00 , C08J2383/02 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1039 , H01M8/1044 , H01M8/1062 , H01M8/1081 , Y02P70/56
摘要： An organic-inorganic hybrid material comprising two phases: a first, mineral phase comprising a structured mesoporous network with open porosity; and a second, organic phase comprising an organic polymer, said organic phase being essentially not present inside the pores of the structured mesoporous network. Membrane and electrode comprising this material. Fuel cell comprising at least one such membrane and/or at least one such electrode. Process for preparing said hybrid material.
摘要翻译： 包含两相的有机 - 无机混合材料：第一矿物相，其包含具有开孔度的结构化介孔网络; 和包含有机聚合物的第二有机相，所述有机相基本上不存在于结构化介孔网络的孔内。 包含该材料的膜和电极。 包含至少一个这样的膜和/或至少一个这样的电极的燃料电池。 制备所述混合材料的方法。
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5.发明申请ORGANIC-INORGANIC HYBRID NANOFIBRES HAVING A MESOPOROUS INORGANIC PHASE, PREPARATION THEREOF BY ELECTROSPINNING, MEMBRANE, ELECTRODE, AND FUEL CELL 审中-公开具有无机无机相的有机 - 无机混合纳米微粒，通过电解，膜，电极和燃料电池的制备公开(公告)号：US20130260283A1
公开(公告)日：2013-10-03
申请号：US13639476
申请日：2011-04-06
申请人： Karine Valle , Philippe Belleville , Frank Pereira , Chrystel Laberty , Clément Sanchez , John Bass
发明人： Karine Valle , Philippe Belleville , Frank Pereira , Chrystel Laberty , Clément Sanchez , John Bass
摘要： Organic-inorganic hybrid nanofibres comprising two phases: a first mineral phase comprising a structured mesoporous network with open porosity; and a second organic phase comprising an organic polymer, wherein said organic phase is basically not present inside the pores of the structured mesoporous network. A membrane and an electrode comprising said nanofibres.A fuel cell comprising said membrane and/or said electrode.A method of preparing said nanofibres by electrically assisted extrusion (electrospinning).
摘要翻译： 包含两相的有机 - 无机杂化纳米纤维：第一矿物相，其包含具有开放孔隙率的结构化介孔网络; 和包含有机聚合物的第二有机相，其中所述有机相基本上不存在于结构化介孔网络的孔内。 一种膜和包含所述纳米纤维的电极。 一种包括所述膜和/或所述电极的燃料电池。 通过电辅助挤出（静电纺丝）制备所述纳米纤维的方法。
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6.发明授权Organic-inorganic hybrid material comprising a mineral mesoporous phase and an organic phase, a membrane and fuel cell 有权包含矿物介孔相和有机相的有机 - 无机杂化材料，膜和燃料电池公开(公告)号：US07923066B2
公开(公告)日：2011-04-12
申请号：US10542768
申请日：2004-01-22
IPC分类号： B05D1/14
CPC分类号： C08J5/2275 , B01D67/0079 , B01D69/141 , B01D71/00 , C08J2383/02 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1039 , H01M8/1044 , H01M8/1062 , H01M8/1081 , Y02P70/56
摘要： An organic-inorganic hybrid material comprising two phases: a first, mineral phase comprising a structured mesoporous network with open porosity; and a second, organic phase comprising an organic polymer, said organic phase being essentially not present inside the pores of the structured mesoporous network. Membrane and electrode comprising this material.Fuel cell comprising at least one such membrane and/or at least one such electrode.Process for preparing said hybrid material.
摘要翻译： 包含两相的有机 - 无机混合材料：第一矿物相，其包含具有开孔度的结构化介孔网络; 和包含有机聚合物的第二有机相，所述有机相基本上不存在于结构化介孔网络的孔内。 包含该材料的膜和电极。 包含至少一个这样的膜和/或至少一个这样的电极的燃料电池。 制备所述混合材料的方法。
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7.发明申请Conductive organic-inorganic hybrid material comprising a mesoporous phase, membrane, electrode and fuel cell 审中-公开导电有机 - 无机混合材料，其包含介孔相，膜，电极和燃料电池公开(公告)号：US20060182942A1
公开(公告)日：2006-08-17
申请号：US10542813
申请日：2004-01-22
CPC分类号： C08J5/2275 , B01D67/0079 , B01D69/141 , B01D71/00 , B01J47/12 , C08J2383/00 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1067 , H01M8/1072 , H01M8/1081 , H01M2300/0068 , H01M2300/0082 , H01M2300/0091 , Y02P70/56 , Y10T428/249953 , Y10T428/249956 , Y10T428/249958
摘要： A conductive organic-inorganic hybrid material comprising a mineral phase in which walls define pores forming a structured mesoporous network with open porosity; said material further comprising an organic oligomer or polymer integrated in said walls and bonded covalently to the mineral phase, and optionally another phase inside the pores, composed of at least one surfactant; at least one of the mineral phase, the oligomer, and the organic polymer having conductive and/or hydrophilic functions. Membrane and electrode comprising this material. Fuel cell comprising at least one such membrane and/or at least one such electrode. Process for preparing said material.
摘要翻译： 导电有机 - 无机混合材料，其包含矿物相，其中壁限定形成具有开放孔隙率的结构化介孔网络的孔; 所述材料进一步包含一体化在所述壁中的有机低聚物或聚合物，共价键合至矿物相，以及任选地在孔内的至少一种表面活性剂组成的另一相; 矿物相，低聚物和有机聚合物中的至少一种具有导电和/或亲水功能。 包含该材料的膜和电极。 包含至少一个这样的膜和/或至少一个这样的电极的燃料电池。 制备所述材料的方法。
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