公开(公告)号：US5587370A

公开(公告)日：1996-12-24

申请号：US521253

申请日：1995-08-30

Applicant: Janis Hajimichael ,  Sandor Botar ,  Edit Bleicher ,  Laszlo Pap ,  Istvan Szekely ,  Katalin Marmarosi n ee Kellner ,  Janos Ori

Inventor： Janis Hajimichael ,  Sandor Botar ,  Edit Bleicher ,  Laszlo Pap ,  Istvan Szekely ,  Katalin Marmarosi n ee Kellner ,  Janos Ori

IPC: A01N43/713 ,  A01P7/02 ,  C07D257/08

CPC classification number: C07D257/08 ,  A01N43/713

Abstract: The invention relates to novel 1,2-dihydro-1,2,4,5-tetrazine derivatives of the formula (IV) ##STR1## wherein means fluorine, chlorine or bromine; andY stands for hydrogen or fluorine,as well as to a process for the preparation thereof. The compounds according to the invention have acaricidal, larvicidal and ovicidal effects.

Abstract translation: 本发明涉及新的式（Ⅳ）的1,2-二氢-1,2,4,5-四嗪衍生物，其中意指氟，氯或溴; 和Y代表氢或氟，以及其制备方法。 根据本发明的化合物具有杀螨，杀幼体和杀卵作用。

公开(公告)号：US5045311A

公开(公告)日：1991-09-03

申请号：US306025

申请日：1989-05-12

Applicant: Janos Pinter ,  Josefne Pal ,  Eva Kiss ,  Erzsebet Shuszler ,  Sandor Angyan ,  Laszlo Pap ,  Andras Szego ,  Tamas Detre ,  Tamasne Marmarosi

Inventor： Janos Pinter ,  Josefne Pal ,  Eva Kiss ,  Erzsebet Shuszler ,  Sandor Angyan ,  Laszlo Pap ,  Andras Szego ,  Tamas Detre ,  Tamasne Marmarosi

IPC: A01N25/04 ,  A01N25/22 ,  A01N25/30 ,  A01N57/02 ,  A01N57/04 ,  A01N57/08 ,  A01N57/10 ,  A01P13/00 ,  B01F17/42

CPC classification number: A01N25/04

Abstract: The invention relates to an emulsifiable microemulsion concentrate containing a phophoric acid ester and/or thiophosphoric acid ester as active ingredient. In addition to 20 to 80% by weight of active ingredient, the composition comprises: 7 to 70% by weight of a nonionic surface active agent, preferably a block copolymer with a molecular weight of 1000 to 10000 formed from polyethylene oxide and polypropylene oxide, an alkylphenol polyglycol ether, ethoxylated fatty alcohol or a mixture of nonionic surface active agents; 2 to 50% by weight of water; if desired, 1 to 50% by weight of a co-surfactant, preferably C.sub.1-8 straight or branched chain and/or cyclic alcohol, C.sub.3-8 straight or branched chain and/or cyclic ketone, esters of C.sub.1-6 fatty acids with C.sub.1-6 alcohols or the mixture thereof; and if desired, 15 to 30% by weight of a water-immiscible organic solvent.

Abstract translation: PCT No.PCT / HU88 / 00029 Sec。 371日期1989年5月12日 102（e）日期1989年5月12日PCT提交1988年4月27日PCT公布。 出版物WO88 / 09122 日期：1988年12月1日本发明涉及含有磷酸酯和/或硫代磷酸酯作为活性成分的可乳化微乳液浓缩物。 除活性成分的20〜80重量％以外，组合物含有7〜70重量％的非离子表面活性剂，优选由聚氧化乙烯和聚环氧丙烷形成的分子量为1000〜10000的嵌段共聚物， 烷基酚聚乙二醇醚，乙氧基化脂肪醇或非离子表面活性剂的混合物; 2至50重量％的水; 如果需要，可以使用1至50重量％的助表面活性剂，优选C 1-8直链或支链和/或环醇，C 3-8直链或支链和/或环酮，C 1-6脂肪酸与 C 1-6醇或其混合物; 并且如果需要，为15〜30重量％的与水不混溶的有机溶剂。

公开(公告)号：US5013754A

公开(公告)日：1991-05-07

申请号：US367546

申请日：1989-06-16

Applicant: Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Rudolf Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

Inventor： Gyorgy Hidasi ,  Istvan Szekely ,  Bela Bertok ,  Sandor Zoltan ,  Lajos Nagy ,  Antal Gajari ,  Eva Somfai ,  Agnes Hegedus ,  Laszlo Pap ,  Rudolf Soos ,  Erzsebet Radvany ,  Sandor Botar ,  Tamas Szabolcsi

IPC: C07C69/747 ,  A01N20060101 ,  A01N37/34 ,  A01N53/00 ,  A01N53/08 ,  A01P7/04 ,  C07B20060101 ,  C07B57/00 ,  C07B61/00 ,  C07B63/04 ,  C07C20060101 ,  C07C67/52 ,  C07C69/743 ,  C07C253/30 ,  C07C253/34 ,  C07C255/00 ,  C07C255/37 ,  C07C255/39

CPC classification number: A01N53/00

Abstract: According to the present invention there is provided a synergistic insecticidal composition containing more than one active ingredients and being harmless to environment characterized by comprising in an amount of from 0.001 to 99% by weight a synthetic pyrethroid of the Formula /I/ ##STR1## namely substantially only the 1RtransS and 1StransR entantiomer-pair /Ib/ out from the possible eight isomers--optionally in admixture with an amount of up to 100% by weight of one or more activator/s/ and auxiliary agent/s/, particularly antioxidants, stabilizing agents, wetting agents, emulsifying agents, dispersing agents, antifoam agents, diluents and/or fillers.The enantiomer-pair Ib consisting of the 1RtransS and 1StransR isomers is new and the invention also relates to the said new enantiomer-pair and a process for the preparation thereof.The advantage of the insecticidal composition of the present invention is that it is less toxical towards warm-blooded animals and useful parasites and is therefore much less harmful to the environment.

公开(公告)号：US06320085B1

公开(公告)日：2001-11-20

申请号：US09297824

申请日：1999-07-13

Applicant: Geza Arvai ,  Bela Bertok ,  Zsuzsanna Kuruczne Ribai ,  Laszlo Pap ,  Istvan Szekely

Inventor： Geza Arvai ,  Bela Bertok ,  Zsuzsanna Kuruczne Ribai ,  Laszlo Pap ,  Istvan Szekely

IPC: C07C4311

CPC classification number: C07D317/54 ,  C07C41/09 ,  C07C43/23 ,  C07C43/215 ,  C07C43/225 ,  C07C43/166

Abstract: The subject matter of the invention is the process for the preparation of mixed ethers of formula I, wherein Ar represents an aromatic or one or more heteroatom-containing moiety, optionally substituted by one or more C1-4 alkoxy, methylenedioxy, C1-4 alkyl, halogen, C1-4 haloalkyl or nitro-group, and/or condensed with a benzene ring; R1 and R2 independently mean hydrogen, C1-4 alkyl, C1-4 haloalkyl, C2-4 alkenyl, phenyl, substituted phenyl, C3-6 cycloalkyl group, R3 means C3-6 alkynyl, optionally substituted by one or more C1-6 alkyl, C3-6 alkenyl, C3-6 alkynyl, C1-6 haloalkyl group, or halogen atom, R3 also means a C1-4 alkyloxy-C1-4 alkyloxy-C1-4 alkyl group. The process comprises the step of reacting the compounds of general formula II with 1 to 3 molar equivalent of the alcohol of general formula IlI in the presence of acid, a Lewis acid, a metal oxide or a metal carbonate, X means hydroxy, halogen or sulphonester leaving group, the resulting ether of general formula I is isolated, if desired, stabilized by the addition of a base and/or an antioxidant; and if desired the excess of the alcohol is recovered.

Abstract translation: 本发明的主题是制备式I的混合醚的方法，其中Ar表示芳族或一个或多个含杂原子的部分，任选地被一个或多个C 1-4烷氧基，亚甲二氧基，C 1-4烷基 ，卤素，C 1-4卤代烷基或硝基，和/或与苯环缩合; R1和R2独立地表示氢，C1-4烷基，C1-4卤代烷基，C2-4烯基，苯基，取代的苯基，C3-6环烷基，R3表示任选被一个或多个C 1-6烷基取代的C 3-6炔基 C3-6烯基，C3-6炔基，C1-6卤代烷基或卤素原子，R3也表示C1-4烷氧基-C1-4烷氧基-C1-4烷基。 该方法包括在酸，路易斯酸，金属氧化物或金属碳酸盐存在下使通式II的化合物与1至3摩尔当量的通式III的醇反应的步骤，X表示羟基，卤素或 如果需要，通过添加碱和/或抗氧化剂来稳定所得到的通式I的醚; 并且如果需要，回收过量的醇。

公开(公告)号：US5455237A

公开(公告)日：1995-10-03

申请号：US277800

申请日：1994-07-20

Applicant: Janis Hajimichael ,  Sandor Botar ,  Edit Bleicher ,  Laszlo Pap ,  Istvan Szekely ,  Katalin Marmarosi ,  Janos ri

Inventor： Janis Hajimichael ,  Sandor Botar ,  Edit Bleicher ,  Laszlo Pap ,  Istvan Szekely ,  Katalin Marmarosi ,  Janos ri

IPC: A01N43/713 ,  A01P7/02 ,  C07D257/08

CPC classification number: C07D257/08 ,  A01N43/713

Abstract: The invention relates to novel tetrazine derivatives of the formula (I), ##STR1## wherein X is fluorine, chlorine or bromine; andY is hydrogen or fluorine, as well as to a process for the preparation thereof.Furthermore, the invention relates to compositions containing the above compounds as well as to a process for the preparation thereof. The compounds and compositions according to the invention have acaricidal; larvicidal an ovicidal effects.

Abstract translation: 本发明涉及式（I）的新的四嗪衍生物，其中X是氟，氯或溴; 和Y是氢或氟，以及其制备方法。 此外，本发明涉及含有上述化合物的组合物及其制备方法。 根据本发明的化合物和组合物具有杀螨剂; 杀幼体具有杀卵作用。

公开(公告)号：US5389662A

公开(公告)日：1995-02-14

申请号：US687938

申请日：1991-05-31

Applicant: Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

Inventor： Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

IPC: A01N43/30 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N47/38 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/06 ,  A01N53/08 ,  A01N53/14 ,  A01N43/28

CPC classification number: A01N53/00

Abstract: The invention relates to novel combined compositions for combatting plant, animal and sanitarian as well as forestry, horticultural and warehouse pests. These compositions contain a pyrethroid-type insecticide as an insecticidally active ingredient and at least one fungicide inhibiting the ergosterol biosynthesis as activity-strengthening agent as well as optionally piperonylbutoxide and other additives.The advantages of the compositions according to the invention consist therein that the activity-strengthening substances used are fungicidal agents widely used and have an advantageous toxicology. The activity-strengthening agent exerts a synergistic effect together with the pyrethroid-type insecticide.The combinations according to the invention bear an outstanding importance in the protection of stored crops.

Abstract translation: PCT No.PCT / HU90 / 00055 Sec。 371日期1991年5月31日 102（e）日1991年5月31日PCT提交1990年7月30日PCT公布。 出版物WO91 / 01640 日期1991年2月21日。本发明涉及用于对抗植物，动物和卫生以及林业，园艺和仓库害虫的新型组合物。 这些组合物含有拟除虫菊酯型杀虫剂作为杀虫活性成分和至少一种抑制麦角甾醇生物合成作为活性增强剂以及任选的胡椒基丁醚和其它添加剂的杀真菌剂。 根据本发明的组合物的优点在于其中使用的活性增强物质是广泛使用的杀真菌剂并且具有有利的毒理学。 活性增强剂与拟除虫菊酯类杀虫剂一起发挥协同作用。 根据本发明的组合在保存作物方面具有突出的重要性。

公开(公告)号：US5189062A

公开(公告)日：1993-02-23

申请号：US827514

申请日：1992-01-28

Applicant: Andras Szego ,  Laszlo Pap ,  Lajos Nagy ,  Eva Somfai ,  Gyorgy Szucsany ,  Istvan Szekely ,  Aniko D. nee Molnar ,  Agnes Hegedus

Inventor： Andras Szego ,  Laszlo Pap ,  Lajos Nagy ,  Eva Somfai ,  Gyorgy Szucsany ,  Istvan Szekely ,  Aniko D. nee Molnar ,  Agnes Hegedus

IPC: A01N25/02

CPC classification number: A01N25/02

Abstract: ULV plant protecting arthropodicidal formulation comprising alkyl aryl polyglycol ether as further additives in addition to the active ingredient(s) dissolved in the mixture of alphatic hydrocarbons and sunflower oil. The formulation according to the invention has an initial contact angle on the plant surface of >13.degree., after 20 minutes of >6.degree. and it is often 120 minutes still at least 2.degree..

Abstract translation: ULV植物保护节肢动物杀菌制剂包含烷基芳基聚乙二醇醚作为另外的添加剂，除了溶解在脂肪烃和向日葵油的混合物中的活性成分之外。 根据本发明的制剂在> 13°的植物表面上具有初始接触角，20分钟> 6°后，通常为120分钟至少为2℃。

公开(公告)号：US4107851A

公开(公告)日：1978-08-22

申请号：US746671

申请日：1976-12-02

Applicant: Istvan Takacs ,  Gyorgy Fabry ,  Laszlo Pap ,  Gyorgy Kiszely

Inventor： Istvan Takacs ,  Gyorgy Fabry ,  Laszlo Pap ,  Gyorgy Kiszely

IPC: B01J8/24 ,  B01F13/02 ,  B01J8/36 ,  F23G5/30 ,  F26B3/08 ,  F26B3/092 ,  F27B15/00

CPC classification number: B01J8/36 ,  F26B3/0926

Abstract: A fluid is introduced into a bed of a material to be fluidized along the bottom surface thereof at a pulsating velocity which is by an order of magnitude greater than the velocity of fluidization.Such method can be carried out in a fluidization apparatus having a per se known distributor the orifices of which are overlapped by reeds which vibrate when a pressure fluid is introduced into a bed above the distributor.

Abstract translation: 将流体沿着其底表面以比流化速度大一个数量级的脉动速度被引入待流化的材料的床中。

公开(公告)号：US5912267A

公开(公告)日：1999-06-15

申请号：US945353

申请日：1997-12-23

Applicant: Istvan Szekely ,  Sandor Botar ,  Bela Bertok ,  Janis Hajimichael ,  Jeno Kiraly ,  Janosne Hadobas ,  Laszlo Pap ,  B. Iidiko Menesine

Inventor： Istvan Szekely ,  Sandor Botar ,  Bela Bertok ,  Janis Hajimichael ,  Jeno Kiraly ,  Janosne Hadobas ,  Laszlo Pap ,  B. Iidiko Menesine

IPC: A01N25/04 ,  A01N25/08 ,  A01N25/22 ,  A01N25/30 ,  A01N53/00 ,  A01N53/02 ,  A01N53/08 ,  A01N53/14

CPC classification number: A01N53/00 ,  Y10S514/937 ,  Y10S514/941 ,  Y10S514/949 ,  Y10S514/97

Abstract: The subject of the invention is an aqueous suspension containing: 0.1-20% by mass beta-cypermethrin, 0-40% by mass other pesticide substance, 1-10% by mass surface active substances in total and within this, 1-5% by mass ethoxylated polyaryl-phenol-phosphate or sulfate, 0.1-25% by mass mineral and/or synthetic silicates, 0.1-1% by mass synthetic silicic acid and up to 100% by mass other auxiliary materials and water as dispersant.

Abstract translation: PCT No.PCT / HU96 / 00020 Sec。 371 1997年12月23日第 102（e）1997年12月23日PCT PCT 1996年4月19日PCT公布。 第WO96 / 33615号公报 日期1996年10月31日本发明的主题是含有0.1-20质量％的β-氯氰菊酯，0-40质量％的其他农药物质，总共1-10质量％的表面活性物质的含水悬浮液 ，1-5％（重量）的乙氧基化聚芳基 - 苯酚 - 磷酸盐或硫酸盐，0.1-25％质量的矿物和/或合成硅酸盐，0.1-1％（质量）的合成硅酸和至多100％的其他辅助材料和水 作为分散剂。

公开(公告)号：US5424327A

公开(公告)日：1995-06-13

申请号：US303712

申请日：1994-09-09

Applicant: Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

Inventor： Laszlo Pap ,  Istvan Szekely ,  Lajos Nagy ,  Andras Szego ,  Andrea Toth ,  Eva Somfai ,  Csaba Szantay ,  Lajos Novak ,  Laszlo Poppe

IPC: A01N43/30 ,  A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  A01N47/38 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/06 ,  A01N53/08 ,  A01N53/14

CPC classification number: A01N53/00

Abstract: The invention relates to novel combined compositions for combatting plant, animal and sanitarian as well as forestry, horticultural and warehouse pests. These compositions contain a pyrethroid-type insecticide as an insecticidally active ingredient and at least one fungicide inhibiting the ergosterol biosynthesis as activity-strengthening agent as well as optionally piperonylbutoxide and other additives.The advantages of the compositions according to the invention consist therein that the activity-strengthening substances used are fungicidal agents widely used and have an advantageous toxicology. The activity-strengthening agent exerts a synergistic effect together with the pyrethroid-type insecticide.The combinations according to the invention bear an outstanding importance in the protection of stored crops.

Abstract translation: 本发明涉及用于对抗植物，动物和卫生以及林业，园艺和仓库害虫的新型组合组合物。 这些组合物含有拟除虫菊酯型杀虫剂作为杀虫活性成分和至少一种抑制麦角甾醇生物合成作为活性增强剂以及任选的胡椒基丁醚和其它添加剂的杀真菌剂。 根据本发明的组合物的优点在于其中使用的活性增强物质是广泛使用的杀真菌剂并且具有有利的毒理学。 活性增强剂与拟除虫菊酯类杀虫剂一起发挥协同作用。 根据本发明的组合在保护作物方面具有突出的重要性。