公开(公告)号：US10017590B2

公开(公告)日：2018-07-10

申请号：US15557011

申请日：2016-03-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogna ,  Giampiero Morini ,  Reynald Chevalier

IPC: C08F4/649 ,  C08F4/651 ,  C08F4/654 ,  C08F4/655 ,  C08F110/06 ,  C08F4/645

CPC classification number: C08F110/06 ,  C08F4/6455 ,  C08F4/6457 ,  C08F4/649 ,  C08F4/6495 ,  C08F4/6498 ,  C08F2410/01 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6543

Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, halogen and an electron donor of formula (I) or (II) When activated with an aluminum alkyl and optionally an external electron donor, solid catalyst component can give high activity and stereospecificity in the polymerization of olefins.

公开(公告)号：US20170166667A1

公开(公告)日：2017-06-15

申请号：US15428940

申请日：2017-02-09

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Alessandro Mignogna ,  Reynald Chevalier ,  Igor Kashulin ,  Ilya Nifant'ev ,  Giampiero Morini ,  Martin Schneider

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C07C327/26 ,  C07C327/28 ,  C07C329/10 ,  C07C333/04 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) In which X and Y are selected from, R1, and —OR1 and —NR2, B is oxygen or sulphur S is sulphur, R1 is selected from C1-C15 hydrocarbon groups, optionally contain a heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, R is hydrogen or R1 and A is a bivalent bridging group with chain length between the two bridging bonds being 1-10 atoms.

公开(公告)号：US09481745B2

公开(公告)日：2016-11-01

申请号：US14917549

申请日：2014-09-08

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogna ,  Reynald Chevalier ,  Giampiero Morini ,  Martin Schneider

IPC: C08F4/00 ,  C08F4/52 ,  C08F210/00 ,  C07C205/00 ,  C08F110/06 ,  C07C271/12

CPC classification number: C08F110/06 ,  C07C271/12 ,  C08F4/651 ,  C08F2500/12

Abstract: The present technology relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the general formula (I): where R1 is selected from C1-C15 hydrocarbon groups, the R2 groups are equal to or different from each other, are hydrogen, or the R1 groups can be fused together to form one or more cycles and A is a bivalent bridging group. The catalyst components of the present disclosure exhibit high activity and stereospecificity in the polymerization of olefins.

公开(公告)号：US20160115261A1

公开(公告)日：2016-04-28

申请号：US14891632

申请日：2014-05-13

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro Mignogna ,  Reynald Chevalier ,  Simona Guidotti ,  Dario Liguori ,  Giampiero Morini ,  Martin Schneider

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C07C271/44 ,  C07C2601/14 ,  C07C2602/08 ,  C08F4/6545 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15

Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.

Abstract translation: 一种用于烯烃聚合的固体催化剂组分，包括Mg，Ti，Cl和至少一种电子给体化合物，它是通过与Mg化合物和至少具有Ti-卤素键的电子与电子接触而获得的反应产物 供体选自具体的二酚衍生物。

公开(公告)号：US10246532B2

公开(公告)日：2019-04-02

申请号：US15557704

申请日：2016-03-08

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Reynald Chevalier ,  Alessandro Mignogna ,  Giampiero Morini

IPC: C08F110/06 ,  C07F7/28

Abstract: A solid catalyst component which exhibits high activity and stereospecificity in the polymerization of olefins made from or containing Mg, Ti and an electron donor of formula (I) where R and R1 are selected from the group consisting of C1-C20 hydrocarbon groups, C6-C14 aryl or alkylaryl groups hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N, and O; R2 to R11 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups which can be optionally fused together to form one or more cycles with the proviso that R6 and R11 cannot join together to form a phenyl ring.

公开(公告)号：US10005860B2

公开(公告)日：2018-06-26

申请号：US15428940

申请日：2017-02-09

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Alessandro Mignogna ,  Reynald Chevalier ,  Igor Kashulin ,  Ilya Nifant'ev ,  Giampiero Morini ,  Martin Schneider

IPC: C08F110/06 ,  C07C327/26 ,  C07C327/28 ,  C07C329/10 ,  C07C333/04

CPC classification number: C08F110/06 ,  C07C327/26 ,  C07C327/28 ,  C07C329/10 ,  C07C333/04 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6545

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) In which X and Y are selected from, R1, and —OR1 and —NR2, B is oxygen or sulphur S is sulphur, R1 is selected from C1-C15 hydrocarbon groups, optionally contain a heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, R is hydrogen or R1 and A is a bivalent bridging group with chain length between the two bridging bonds being 1-10 atoms.