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    IMINOXYTRIAZINES AS RADICAL GENERATORS
    1.
    发明申请
    IMINOXYTRIAZINES AS RADICAL GENERATORS 有权
    作为辐射发生器的IMINOXYTRIAZINES

    公开(公告)号：US20150284604A1

    公开(公告)日：2015-10-08

    申请号：US14437246

    申请日：2013-10-22

    Applicant: BASF SE

    Inventor： Peter Nesvadba ,  Lucienne Bugnon Folger ,  Antoine Carroy ,  Marc Faller

    IPC: C09J133/14 ,  C09D11/107

    CPC classification number: C09J133/14 ,  C07D251/30 ,  C07D251/42 ,  C07D403/14 ,  C09D11/107

    Abstract: Iminoxytriazine compounds of the formula I wherein n is 1 or 2; R1 and R2 independently of each other are hydrogen, NH2, NHR5, NR5R6, COR5, COOR5, CONH2, CONHR5, CONR5R6, CN, SR5, OR5, C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl, wherein said C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy, or R1 and R2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy; R3 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 1, R4 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 2, R4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R5 and R6 independently of each other are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl; are suitable as radical generating agents.

    Abstract translation: 式I的亚氨基三嗪化合物，其中n为1或2; R 1和R 2彼此独立地是氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5 R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基， C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基的基团取代或R 1和R 2一起 与其连接的C原子形成4-12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自以下的基团取代：C 1 -C 12烷基，C 3 -C 12环烷基，苯基， 卤素和C 1 -C 12烷氧基; R3是F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为1，则R4为F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2，则R4为衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

    Iminoxytriazines as radical generators
    4.
    发明授权
    Iminoxytriazines as radical generators 有权
    亚氨基三嗪作为自由基发生剂

    公开(公告)号：US09255217B2

    公开(公告)日：2016-02-09

    申请号：US14437246

    申请日：2013-10-22

    Applicant: BASF SE

    Inventor： Peter Nesvadba ,  Lucienne Bugnon Folger ,  Antoine Carroy ,  Marc Faller

    IPC: C07D251/30 ,  C07D251/42 ,  C07D403/14 ,  C09J133/14 ,  C09D11/107

    CPC classification number: C09J133/14 ,  C07D251/30 ,  C07D251/42 ,  C07D403/14 ,  C09D11/107

    Abstract: Iminoxytriazine compounds of the formula I wherein n is 1 or 2; R1 and R2 independently of each other are hydrogen, NH2, NHR5, NR5R6, COR5, COOR5, CONH2, CONHR5, CONR5R6, CN, SR5, OR5, C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl, wherein said C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy, or R1 and R2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy; R3 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 1, R4 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 2, R4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R5 and R6 independently of each other are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl; are suitable as radical generating agents.

    Abstract translation: 式I的亚氨基三嗪化合物，其中n为1或2; R 1和R 2彼此独立地是氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5 R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基， C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基的基团取代或R 1和R 2一起 与其连接的C原子形成4-12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自以下的基团取代：C 1 -C 12烷基，C 3 -C 12环烷基，苯基， 卤素和C 1 -C 12烷氧基; R3是F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为1，则R4为F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2，则R4为衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

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