Abstract:
Monoazo dyestuffs which in the form of the free acid correspond to the formula
WHEREIN R1 is alkyl or aryl; R2 is hydrogen or alkyl; R3 is hydrogen, halogen or alkyl; R4 is hydrogen, halogen, alkyl, alkoxy, or nitrile; p or m are 0 or 1 with the sum of the two being 1 or 2; and n is 1 or 2; and A may contain further substituents free of sulfo or sulfato, and their use for the dyeing of natural and synthetic fibre materials, especially for dyeing polyamide fibres. They give level dyeings of good yield with very good fastness to light. They are even absorbed well on polyamide fibres from a neutral to weak acid dye bath. By polyamide fibres there are here especially understood those of synthetic polyamides such as Epsilon -polycaprolactam or condensation products of adipic acid and hexamethylenediamine.
WHEREIN: R1 IS HYDROGEN, AN OPTIONALLY SUBSTITUTED ALKYL, CYCLOALKYL, ARALKYL, OR ARYL GROUP; R2 IS A OPTIONALLY SUBSTITUTED ALKYL, CYLOALKYL, ARALKYL OR ARYL GROUP, OR AN ALKOXY CABONYL GROUP, OR A HEETEROCYCLIC RADICAL; OR A RADIACAL OF THE FORMULA: WHEREIN X IS
-X-R3, -CO- OR -SO-
AND R3 IS AN OPTIONALLY SUBSTITUTED ALKYL, CYUCLOALKYL, ARALKYL, ARYL OR HETEROCYCLIC RADICAL; OR A RADICAL OF THE FORMULA:
-Y-N(-R4)-R5
WHEREIN Y IS
-CO-, -C(=NH)- OR -C(=S)-
AND R4 AND R5 ARE HYDROGEN OR OPTIONALLY SUBSTITUTED ALKYL GROUPS, CYLOALKYL GROUPS, ARALKYL GROUPS OR ARYL GROUPS; WHEREIN THE PERYLENE RADICAL CAN HAVE FURTHER SUBSTITUENTS; WITH THE PROVISO THAT WHEN R2 IS
Abstract:
AZO DYESTUFFS FREE FROM SULFONIC ACID GROUPS ARE PREPARED WHICH ARE VALUABLE NEW PIGMENT DYESTUFFS CHARACTERIZED BY GOOD FASTNESS TO LIGHT, SOLVENTS AND MIGRATION, AND BY A GOOD THERMAL STABILITY ADAPTED FOR USE IN COLORING PAPERS, LACQUERS, AND SYNTHETIC MATERIALS AND FOR PRODUCING PIGMENT PASTE AND PRINTING INKS. THE DYESTUFFS CORRESPOND TO THE GENERAL FORMULA
WHERE B DENOTES A DIRECT BOND, AN OPTIONALLY SUBSTITUTED ALIPHATIC, ARALIPHATIC, CARBOCYCLIC OR HETEROCYCLIC RADICAL, X STANDS FOR NH, O OR S; K1 DENOTES THE RADICAL OF A MONOFUNCTIONAL COUPLING COMPONENT; R STANDS FOR IDENTICAL OR DIFFERENT SUBSTITUENTS; AND M IS AN INTEGER FROM 0 TO 3.
Abstract:
Disazo dyestuffs which in the form of the free acid correspond to the formula
IN WHICH R1 is aryl, a C1-C4-aliphatic radical or dialkylamino with 1-6 carbon atoms in the alkyl radical; R2 is chlorine, bromine, alkoxy, or alkyl; R3 and R4 are hydrogen, chlorine, bromine, alkoxy, or alkyl; R5 is alkyl or aryl; R6 is hydrogen, alkyl, or alkyl substituted by cyano, carbonamide or carboxyl; R7 is a substituent, such as alkyl, alkoxy, halogen, nitro, sulfo, or cyano; B is a 1,4-phenylene or 1,4-napthylene radical; M IS A NUMBER 0-2; AND N IS A NUMBER 0-2; AND THEIR USE FOR THE DYEING AND PRINTING OF NATURAL AND SYNTHETIC FIBER MATERIALS CONTAINING AMIDE GROUPS, FOR EXAMPLE THOSE OF WOOL, SILK AND POLYAMIDE, SUCH AS POLY- Epsilon CAPROLACTUM OR THE REACTION PRODUCT OF HEXAMETHYLENE-DIAMINE WITH ADIPIC ACID, ARE DISCLOSED. The dyeings obtained, especially those on polyamide materials, are distinguished by good fastness properties, especially by good fastness to wet porcessing and good fastness to light.
IN WHICH R AND R'' ARE HYDROGEN, CHLORINE, OR FLUORINE; R" IS HYDROGENOR LOWER ALKYL; A IS A STRAIGHT-CHAIN OR BRANCHED ALKYLENE GROUP WITH 2 TO 6 CARBON ATOMS WHICH MAY BE INTERRUPTED BY OXYGEN AND/OR SULFUR ATOMS; AND N IS AN INTEGER OF 1 TO 3; AND THEIR USE IN THE DYEING AND PRINTING OF SYNTHETIC FIBER MATERIALS, E.G. POLYESTER, POLYAMIDE, CELLULOSE, ESTERS, ARE DISCLOSED. THE DYES GIVE GOOD YEILDS AND THE DYEINGS EXHIBIT GOOD TEXTURE, FASTNESS TO LIGHT, THERMOFIXING, WASHING, RUBBING AND IRONING.
Abstract:
Dyeing and printing of textile materials of metal-containing polypropylene with compounds of the general formula
IN WHICH A stands for a optionally substituted benzene or naphthalene radical the -OH-group and the substituent -CH Nbeing attached to adjacent carbon atoms; B represents a optionally substituted benzene or naphthalene the substituent -OR and the substituent
BEING ATTACHED TO ADJACENT CARBON ATOMS AND R representing an alkyl radical A and B cannot simultaneously represent radicals of the benzene series.
Abstract:
Process for the production of hydroxylamine-O-sulphonic acid from hydroxylamine or its salts and chlorosulphonic acid or oleum, wherein the reaction is performed in an inert organic diluent preferably, a halogenated aliphatic and/or aromatic hydrocarbon at a temperature of from 0* C. to 80* C.