公开(公告)号：US3925350A

公开(公告)日：1975-12-09

申请号：US32710973

申请日：1973-01-26

Applicant: BAYER AG

Inventor： WOLFRUM GERHARD ,  SOMMER RICHARD ,  KLAUKE ERICH

IPC: C09B29/40 ,  C09B29/36

CPC classification number: C09B29/3613 ,  Y10S8/924

Abstract: Monoazo dyestuffs which in the form of the free acid correspond to the formula

WHEREIN R1 is alkyl or aryl; R2 is hydrogen or alkyl; R3 is hydrogen, halogen or alkyl; R4 is hydrogen, halogen, alkyl, alkoxy, or nitrile; p or m are 0 or 1 with the sum of the two being 1 or 2; and n is 1 or 2; and A may contain further substituents free of sulfo or sulfato, and their use for the dyeing of natural and synthetic fibre materials, especially for dyeing polyamide fibres. They give level dyeings of good yield with very good fastness to light. They are even absorbed well on polyamide fibres from a neutral to weak acid dye bath. By polyamide fibres there are here especially understood those of synthetic polyamides such as Epsilon -polycaprolactam or condensation products of adipic acid and hexamethylenediamine.

公开(公告)号：US3891619A

公开(公告)日：1975-06-24

申请号：US31141472

申请日：1972-12-01

Applicant: BAYER AG

Inventor： SOMMER RICHARD ,  WIESEL MANFRED ,  OTTEN HANS-GUNTER ,  SIEGEL EDGAR

IPC: C09B29/40 ,  C09B20060101 ,  C09B29/00 ,  C09B29/36 ,  D06P1/00 ,  D06P1/06 ,  D06P3/00 ,  D06P3/06 ,  D06P3/24

CPC classification number: C09B29/22

Abstract: Monoazo dyestuffs which in the form of the free acid correspond to the general formula

WHEREIN R1 is hydrogen or alkyl; R2 is hydrogen, halogen, alkyl, alkoxy, nitro, nitrile, carbonamide or carboxylic acid ester; R3 is hydrogen, halogen, alkyl or alkoxy; R4 is alkyl or aryl; R5 is hydrogen or alkyl, R6 is hydrogen, halogen or alkyl; R7 is hydrogen, halogen, alkyl, alkoxy or nitrile; X is C2-C4-alkylene, aralkylene or phenylene; Y is SO3H or, if X is phenylene, SO3H or a radical -SO2-NH-SO2-R8; and R8 is alkyl, aryl or dialkylamine. These dyestuffs are used for the dyeing of natural and synthetic fibre materials, especially for dyeing polyamide fibres. They yield level yellow to orange dyeings with very good fastness to light. Dyestuffs are absorbed well on polyamide fibres even in a neutral to weakly acid dyebath. The dyestuffs are employed in the form of the free acid or in the form of its salts, especially the alkali salts, such as the sodium or potassium salts or the ammonium salts.

Abstract translation: 游离酸形式的单偶氮染料对应于通式，其中R1是氢或烷基; R2是氢，卤素，烷基，烷氧基，硝基，腈，碳酰胺或羧酸酯; R3是氢，卤素，烷基或烷氧基; R4是烷基或芳基; R5是氢或烷基，R6是氢，卤素或烷基; R7是氢，卤素，烷基，烷氧基或腈; X是C 2 -C 4亚烷基，亚芳基或亚苯基; Y是SO 3 H，或者如果X是亚苯基，则SO 3 H或-SO 2 -NH-SO 2 -R 8基团; R8是烷基，芳基或二烷基胺。 这些染料用于天然和合成纤维材料的染色，特别是染色聚酰胺纤维。 它们产生黄色至橙色的染色，具有非常好的耐光牢度。 即使在中性至弱酸性染浴中，染料也能很好的吸收在聚酰胺纤维上。 染料以游离酸的形式或其盐形式使用，特别是碱金属盐，例如钠盐或钾盐或铵盐。

公开(公告)号：US3883502A

公开(公告)日：1975-05-13

申请号：US24278772

申请日：1972-04-10

Applicant: BAYER AG

Inventor： SOMMER RICHARD ,  SIEGEL EDGAR

IPC: C09B31/04 ,  C09B31/06 ,  C09B31/14 ,  D06P3/24

CPC classification number: C09B31/04 ,  C09B31/061 ,  C09B31/14 ,  Y10S8/924

Abstract: Disazo dyestuffs are disclosed which, in the free acid form, have the formula


D R A W I N G
IN WHICH R1 is H, Cl, Br, alkyl, alkoxy or nitro; R2 and R3 are H, Cl, Br, alkoxy or alkyl; R4 is alkyl or optionally substituted aryl; R5 is H or alkyl which may be substituted by CN, carboxamide or carboxyl; R6 is a substituent, such as alkyl, alkoxy, halogen, nitro, sulpho, or cyano; B is 1,4-phenylene or 1,4-naphthylene; M IS 1 OR 2; AND N IS 0, 1 OR 2. The dyestuffs are useful in the printing and dyeing of natural and synthetic fiber materials containing amide groups to give dyeings having good fastness properties especially wet processing and light fastness.

Abstract translation: 公开了以游离酸形式具有式I的化合物，其中R 1是H，Cl，Br，烷基，烷氧基或硝基; R2和R3是H，Cl，Br，烷氧基或烷基; R4是烷基或任选取代的芳基; R5是H或可被CN，羧酰胺或羧基取代的烷基; R6是取代基，例如烷基，烷氧基，卤素，硝基，磺基或氰基; B是1,4-亚苯基或1,4-亚萘基; M IS 1 OR 2; 和N是0，1或2。

公开(公告)号：US3867369A

公开(公告)日：1975-02-18

申请号：US24592372

申请日：1972-04-20

Applicant: BAYER AG

Inventor： SOMMER RICHARD ,  WOLFRUM GERHARD

IPC: C09B31/15 ,  C09B31/14

CPC classification number: C09B31/15 ,  Y10S8/924

Abstract: Disazo dyestuffs which in the form of the free acid correspond to the formula

IN WHICH R1 is aryl, a C1-C4-aliphatic radical or dialkylamino with 1-6 carbon atoms in the alkyl radical; R2 is chlorine, bromine, alkoxy, or alkyl; R3 and R4 are hydrogen, chlorine, bromine, alkoxy, or alkyl; R5 is alkyl or aryl; R6 is hydrogen, alkyl, or alkyl substituted by cyano, carbonamide or carboxyl; R7 is a substituent, such as alkyl, alkoxy, halogen, nitro, sulfo, or cyano; B is a 1,4-phenylene or 1,4-napthylene radical; M IS A NUMBER 0-2; AND N IS A NUMBER 0-2; AND THEIR USE FOR THE DYEING AND PRINTING OF NATURAL AND SYNTHETIC FIBER MATERIALS CONTAINING AMIDE GROUPS, FOR EXAMPLE THOSE OF WOOL, SILK AND POLYAMIDE, SUCH AS POLY- Epsilon CAPROLACTUM OR THE REACTION PRODUCT OF HEXAMETHYLENE-DIAMINE WITH ADIPIC ACID, ARE DISCLOSED. The dyeings obtained, especially those on polyamide materials, are distinguished by good fastness properties, especially by good fastness to wet porcessing and good fastness to light.

Abstract translation: 游离酸形式的双偶氮染料对应于式Ⅰ化合物，其中R 1是芳基，C 1 -C 4脂族基团或烷基中具有1-6个碳原子的二烷基氨基; R2是氯，溴，烷氧基或烷基; R3和R4是氢，氯，溴，烷氧基或烷基; R5是烷基或芳基; R6是氢，烷基或被氰基，碳酰胺或羧基取代的烷基; R7是取代基，例如烷基，烷氧基，卤素，硝基，磺基或氰基; B是1,4-亚苯基或1,4-萘乙烯基; M是0-2; 和N是0-2; 并且它们用于包含酰胺基团的自然和合成纤维材料的染色和印刷，例如WOOL，SILK和POLYAMIDE，例如聚ε-丙烯酸酯或十六烷基二胺与ADIPIC的反应产物。 获得的染色，特别是聚酰胺材料的染色，具有良好的牢度特性，特别是耐湿牢度好，耐光牢度好。