Synthesis of organometallic cyclometallated transition metal complexes
    3.
    发明授权
    Synthesis of organometallic cyclometallated transition metal complexes 有权
    有机金属环金属化过渡金属络合物的合成

    公开(公告)号:US07399857B2

    公开(公告)日:2008-07-15

    申请号:US11289040

    申请日:2005-11-29

    IPC分类号: C07F15/00

    CPC分类号: C07F15/0033

    摘要: A process for forming a tris-cyclometallated complex comprises the step of reacting; a) an M(I) complex, wherein M represents Rh or Ir, and said complex comprises at least two ligands and contains at least two alkenyl groups pi-bonded to M, with b) a heterocyclic compound capable of forming a organometallic cyclometallated complex.

    摘要翻译: 形成三环金属化络合物的方法包括以下步骤: a)M(I)配合物,其中M表示Rh或Ir,并且所述络合物包含至少两个配体并且含有至少两个与M键合键合的烯基,b)可以形成有机金属环金属络合物的杂环化合物 。

    HYBRID FLUORESCENT/PHOSPHORESCENT OLEDS
    10.
    发明申请
    HYBRID FLUORESCENT/PHOSPHORESCENT OLEDS 审中-公开
    混合荧光/磷光体OLED

    公开(公告)号:US20080284318A1

    公开(公告)日:2008-11-20

    申请号:US11749899

    申请日:2007-05-17

    IPC分类号: H01J1/62

    摘要: An electroluminescent device comprises a) a fluorescent light emitting layer comprising a fluorescent emitter and a fluorescent host material wherein the HOMO energy level of the fluorescent host material is not more than 0.1 eV more negative than that of the fluorescent emitter; b) a phosphorescent light emitting layer comprising a phosphorescent emitter and a phosphorescent host material; and c) a spacer layer interposed between the fluorescent light emitting layer and the phosphorescent light emitting layer; wherein the triplet energy of the fluorescent host material is not more than 0.2 eV less than the triplet energy of both the spacer layer material and of the phosphorescent host material. The materials within these layers are selected so that the HOMO and triplet energy levels satisfy certain interrelationships. The invention provides devices that emit light with high luminous efficiency.

    摘要翻译: 一种电致发光器件包括:a)包含荧光发射体和荧光主体材料的荧光发光层,其中荧光主体材料的HOMO能级不比荧光发射体的阴离子多0.1eV; b)包含磷光发射体和磷光主体材料的磷光发光层; 以及c)插入在荧光发光层和磷光发光层之间的间隔层; 其中所述荧光主体材料的三重态能量比所述间隔层材料和所述磷光主体材料的三线态能量小不超过0.2eV。 选择这些层内的材料,使得HOMO和三重态能级满足某些相互关系。 本发明提供发光效率高的装置。