公开(公告)号：US20170372842A1

公开(公告)日：2017-12-28

申请号：US15194224

申请日：2016-06-27

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp

IPC: H01G9/025 ,  C09D7/12 ,  C07F5/00 ,  H01G9/048 ,  H01G9/15

CPC classification number: H01G9/025 ,  C07F5/003 ,  C09D7/63 ,  H01G9/048 ,  H01G9/15 ,  H01G9/151

Abstract: The present disclosure provides an electro-polarizable complex compound having the following general formula: [M4+(L)m]xKn,  (I) where complexing agent M is a four-valence metal; ligand L comprises one or more heteroatomic fragments comprising one or more neutral or anionic metal-coordinating heteroatoms and one or more electrically resistive fragments, m represents the number of ligands; x represents the oxidative state of the metal-ligand complex; K is a counter-ion or zwitterionic polymers which provides an electro-neutrality of the complex compound, n represents the number of counter-ions. The metal-coordinating heteroatoms form a first coordination sphere, and the number of heteroatoms in this first coordination sphere does not exceed 12.

公开(公告)号：US20170287637A1

公开(公告)日：2017-10-05

申请号：US15090509

申请日：2016-04-04

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/14 ,  C07F7/08 ,  H01G4/005 ,  C09K19/22 ,  C09K19/32 ,  H01G4/32 ,  C07D471/22 ,  C09K19/34

CPC classification number: H01G4/14 ,  C07D471/22 ,  C09B5/008 ,  C09B5/62 ,  C09B47/00 ,  C09B47/04 ,  C09K19/606 ,  H01G4/18 ,  H01G4/32

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having two-dimensional teat form and self-assembling by pi-pi stacking in a column-like supramolecule, R1 is a dopant group connected to Core1; a number m of R1 groups is 1, 2, 3 or 4. R2 is a substituent comprising one or more ionic groups connected to Core1; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear polarization effect. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, a number n of such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US10319523B2

公开(公告)日：2019-06-11

申请号：US15710587

申请日：2017-09-20

Applicant: Capacitor Sciences Incorporated

Inventor： Yan Li ,  Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Samuel Hein

IPC: H01G4/18 ,  C08F20/34 ,  C08F20/18 ,  H01L49/02 ,  C08F20/36 ,  C08G73/02 ,  C08L33/02 ,  H01G9/04 ,  H01G9/07

Abstract: A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.

公开(公告)号：US20180158616A1

公开(公告)日：2018-06-07

申请号：US15368171

申请日：2016-12-02

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/32 ,  H01G4/33 ,  H01G4/12 ,  H01G4/14 ,  H01G4/008 ,  H01G4/01 ,  C09D5/24 ,  C09D179/02 ,  C09D165/00

CPC classification number: H01G4/32 ,  C08G73/0266 ,  C08G73/0672 ,  C08G2261/3142 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3422 ,  C08G2261/51 ,  C09D5/24 ,  C09D165/00 ,  H01B1/127 ,  H01B1/128 ,  H01G4/008 ,  H01G4/01 ,  H01G4/14 ,  H01G4/33

Abstract: The present disclosure provides a multilayered electrode comprising an electro-conductive layer and at least one protective layer located on one side of the electro-conductive layer and selected from the list comprising a field-planarization layer, a tunneling injection blocking layer and a coulomb blocking layer.

公开(公告)号：US09978517B2

公开(公告)日：2018-05-22

申请号：US15090509

申请日：2016-04-04

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/14 ,  C07D471/22 ,  C09K19/22 ,  C07F7/08 ,  C09K19/34 ,  C09K19/32 ,  H01G4/32 ,  H01G4/005

CPC classification number: H01G4/14 ,  C07D471/22 ,  C09B5/008 ,  C09B5/62 ,  C09B47/00 ,  C09B47/04 ,  C09K19/606 ,  H01G4/18 ,  H01G4/32

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, R1 is a dopant group connected to Core1; a number m of R1 groups is 1, 2, 3 or 4. R2 is a substituent comprising one or more ionic groups connected to Core1; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear polarization effect. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, a number n of such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US20180137984A1

公开(公告)日：2018-05-17

申请号：US15805016

申请日：2017-11-06

Applicant: Capacitor Sciences Incorporated

Inventor： Paul T. Furuta ,  Yan Li ,  Barry K. Sharp ,  Pavel Ivan Lazarev

IPC: H01G7/06

CPC classification number: H01G7/06 ,  H01G4/1218 ,  H01G4/1227 ,  H01G4/1236 ,  H01G4/18 ,  H01G4/206 ,  H01G4/30 ,  H01G4/32

Abstract: The present disclosure provides a solid state energy storage device, comprising: a first electrically conductive electrode, a second electrically conductive electrode; and at least one metadielectric layer located between the first and second conductive electrodes. The metadielectric layer comprises at least one type of mesogen. The mesogen consists of an organic compound with at least one electrically resistive substituent and at least one polarizable unit. The polarizable unit may be independently selected from intramolecular and intermolecular polarizable units.

公开(公告)号：US20170283618A1

公开(公告)日：2017-10-05

申请号：US15469126

申请日：2017-03-24

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: C09B57/00 ,  C09B7/02 ,  H01G4/14

CPC classification number: C07D471/22 ,  C07C11/28 ,  C07C69/157 ,  C07C245/08 ,  C07C307/02 ,  C09B7/02 ,  H01G4/14 ,  H01G4/18 ,  H01G4/32

Abstract: A composite organic compound characterized by polarizability and resistivity that has a general structural formula: where C is a chromophore fragment, P is an optionally connected rylene fragment, D and A are electron donating and accepting groups respectively, and R represents resistive substituents optionally connected directly or via dopant connecting groups.

公开(公告)号：US10707019B2

公开(公告)日：2020-07-07

申请号：US15982482

申请日：2018-05-17

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/14 ,  C07D471/22 ,  C07B47/00 ,  H01G4/18 ,  H01G4/32 ,  C09B5/62 ,  C09K19/60 ,  C09B5/00 ,  C09B69/00 ,  C09B57/08 ,  C09B47/00 ,  C09B47/04

Abstract: An electro-polarizable compound has the following general formula: where Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, which is tetrapirolic macro-cyclic fragment, R1 is an dopant group connected to Core1, m is number of R1 which is equal to 1, 2, 3 or 4, R2 is a substituent comprising one or more ionic groups, p is number of R2 which is equal to 0, 1, 2, 3 or 4. The fragment marked NLE containing the Core1 with at least one R1 has a nonlinear effect of polarization. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, n is number of Core2 which is equal to 2, or 4, R3 is a substituent comprising one or more ionic groups, s is number of R3 which is equal to 0, 1, 2, 3 or 4. R4 is a non-polar resistive substituent, k is a number of R4 which is equal to 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US10672560B2

公开(公告)日：2020-06-02

申请号：US16208953

申请日：2018-12-04

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li ,  Ian S.G. Kelly-Morgan

IPC: H01G4/14 ,  C09B5/62 ,  H01G4/18 ,  C09B57/08 ,  C07D471/22 ,  H01G4/005 ,  H01G4/32 ,  C09B5/00

Abstract: An electro-polarizable compound having the following formula (I): where Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule comprising one or more rylene fragments, R1 is an electron donor group connected to Core1 and R1′ is an electron acceptor group connected to the Core1, m is number of acceptor group R1, m′ is a number of donor group R′, m and m′ are equal to 0, 1, 2, 3, 4, 5 or 6, wherein m and m′ are not both equal to 0, R2 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to the Core1-directly or via a connecting group, p is a number of ionic groups R2 which is equal to 0, 1, 2, 3 or 4; wherein the fragment marked NLE containing the Core1 with at least one group R1 and/or R1′ has a nonlinear effect of polarization, wherein Core2 is an electro-conductive oligomer, n is a number equal to 0, 2, or 4, R3 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to the Core2 directly or via a connecting group, s is a number of the ionic groups R3 which is equal to 0, 1, 2, 3 or 4; wherein R4 is a non-conjugate cyclic or polycyclic resistive substituent electrically insulating the column-like supramolecules from each other and connected to the aromatic polycyclic conjugated molecule (Core1) and/or to the Core2 directly or via a connecting group, k is a number of substituents R4 which is equal to 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US10395841B2

公开(公告)日：2019-08-27

申请号：US15368171

申请日：2016-12-02

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: C09D5/24 ,  H01B1/12 ,  H01G4/01 ,  H01G4/14 ,  H01G4/32 ,  H01G4/33 ,  C08G73/02 ,  C08G73/06 ,  H01G4/008 ,  C09D165/00

Abstract: The present disclosure provides a multilayered electrode comprising an electro-conductive layer and at least one protective layer located on one side of the electro-conductive layer and selected from the list comprising a field-planarization layer, a tunneling injection blocking layer and a coulomb blocking layer.