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公开(公告)号:US20220411324A1
公开(公告)日:2022-12-29
申请号:US17894693
申请日:2022-08-24
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Xiaoju Guo , Pascale Oram , Rostislav Vatchev Roussev , Ljerka Ukrainczyk , Taylor Marie Wilkinson
Abstract: Methods of manufacturing a glass-based article includes exposing a glass-based substrate having a lithium aluminosilicate composition to an ion exchange treatment to form the glass-based article. The ion exchange treatment including a molten salt bath having a concentration of a sodium salt in a range from 8 mol % to 100 mol %. The glass-based article includes sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article The glass-based article has compressive stress layer extending from the surface to a spike depth of layer from 4 micrometers to 8 micrometers. The glass-based article includes a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8.
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公开(公告)号:US11472733B2
公开(公告)日:2022-10-18
申请号:US16826473
申请日:2020-03-23
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Xiaoju Guo , Pascale Oram , Rostislav Vatchev Roussev , Ljerka Ukrainczyk , Taylor Marie Wilkinson
Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. A glass-based article comprises a lithium aluminosilicate composition and a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8. The article comprises sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article and a spike depth of layer that is greater than or equal to 4 micrometers and less than or equal to 8 micrometers. The article may comprise an average compressive stress of greater than or equal to 150 MPa over a depth from 15 micrometers to 40 micrometers.
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公开(公告)号:US20200308046A1
公开(公告)日:2020-10-01
申请号:US16826473
申请日:2020-03-23
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Xiaoju Guo , Pascale Oram , Rostislav Vatchev Roussev , Ljerka Ukrainczyk , Taylor Marie Wilkinson
Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. A glass-based article comprises a lithium aluminosilicate composition and a molar ratio of potassium dioxide (K2O) to sodium dioxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8. The article comprises sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article and a spike depth of layer that is greater than or equal to 4 micrometers and less than or equal to 8 micrometers. The article may comprise an average compressive stress of greater than or equal to 150 MPa over a depth from 15 micrometers to 40 micrometers.
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公开(公告)号:US12275668B2
公开(公告)日:2025-04-15
申请号:US18537240
申请日:2023-12-12
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Xiaoju Guo , Pascale Oram , Rostislav Vatchev Roussev , Ljerka Ukrainczyk , Taylor Marie Wilkinson
Abstract: Methods of manufacturing a glass-based article includes exposing a glass-based substrate having a lithium aluminosilicate composition to an ion exchange treatment to form the glass-based article. The ion exchange treatment including a molten salt bath having a concentration of a sodium salt in a range from 8 mol % to 100 mol %. The glass-based article includes sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article The glass-based article has compressive stress layer extending from the surface to a spike depth of layer from 4 micrometers to 8 micrometers. The glass-based article includes a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8.
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公开(公告)号:US11884581B2
公开(公告)日:2024-01-30
申请号:US17894693
申请日:2022-08-24
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Xiaoju Guo , Pascale Oram , Rostislav Vatchev Roussev , Ljerka Ukrainczyk , Taylor Marie Wilkinson
CPC classification number: C03C21/002 , C03C3/093 , C03C3/125 , C03C4/18 , H05K5/0017 , H05K5/03 , C03C2204/00
Abstract: Methods of manufacturing a glass-based article includes exposing a glass-based substrate having a lithium aluminosilicate composition to an ion exchange treatment to form the glass-based article. The ion exchange treatment including a molten salt bath having a concentration of a sodium salt in a range from 8 mol % to 100 mol %. The glass-based article includes sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article The glass-based article has compressive stress layer extending from the surface to a spike depth of layer from 4 micrometers to 8 micrometers. The glass-based article includes a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8.
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公开(公告)号:US20210061705A1
公开(公告)日:2021-03-04
申请号:US17005769
申请日:2020-08-28
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Vitor Marino Schneider , Wei Sun , Taylor Marie Wilkinson
Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. The glass-based articles comprise: a thickness t; a lithium aluminosilicate composition; and a molar ratio of sodium oxide (Na2O) to lithium oxide (Li2O) that is less than or equal to 0.63 at the center of the glass-based article. The articles have a molar ratio of sodium dioxide (Na2O) to lithium dioxide (Li2O) in a post-spike near region that is greater than or equal to 0.9 and/or less than 1.5.
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7.
公开(公告)号:US20240140856A1
公开(公告)日:2024-05-02
申请号:US18380710
申请日:2023-10-17
Applicant: CORNING INCORPORATED
Inventor: Qiang Fu , Charlene Marie Smith , Alana Marie Whittier , Taylor Marie Wilkinson
CPC classification number: C03C10/0027 , C03B32/02 , C03C10/0009 , C03C21/002 , C03C2204/00
Abstract: A glass-ceramic article includes a crystalline phase, a residual glass phase, greater than or equal to 55 mol % and less than or equal to 80 mol % SiO2, greater than or equal to 1 mol % and less than or equal to 8 mol % Al2O3, greater than or equal to 13 mol % and less than or equal to 35 mol % Li2O, greater than or equal to 0.05 mol % and less than or equal to 5 mol % Na2O, greater than or equal to 0.05 mol % and less than or equal to 3 mol % K2O, greater than or equal to 0.2 mol % and less than or equal to 2 mol % P2O5, and greater than or equal to 1.5 mol % and less than or equal to 10 mol % ZrO2, wherein the crystalline phase comprises a lithium disilicate sub-phase.
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公开(公告)号:US11787728B2
公开(公告)日:2023-10-17
申请号:US17005769
申请日:2020-08-28
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Vitor Marino Schneider , Wei Sun , Taylor Marie Wilkinson
CPC classification number: C03C3/093 , C03C3/091 , C03C4/18 , C03C21/002 , C03C2204/00
Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. The glass-based articles comprise: a thickness t; a lithium aluminosilicate composition; and a molar ratio of sodium oxide (Na2O) to lithium oxide (Li2O) that is less than or equal to 0.63 at the center of the glass-based article. The articles have a molar ratio of sodium dioxide (Na2O) to lithium dioxide (Li2O) in a post-spike near region that is greater than or equal to 0.9 and/or less than 1.5.
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公开(公告)号:US20230150869A1
公开(公告)日:2023-05-18
申请号:US17983754
申请日:2022-11-09
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Qiang Fu , Jill Marie Hall , Mathieu Gerard Jacques Hubert , Charlene Marie Smith , Ljerka Ukrainczyk , Taylor Marie Wilkinson
CPC classification number: C03C21/002 , C03C10/0027 , H05K5/03 , C03C2204/00
Abstract: A glass-ceramic article having greater than or equal to 65.00 wt. % and less than or equal to 80.00 wt. % SiO2, greater than 4.00 wt. % and less than or equal to 12.00 wt. % Al2O3, greater than or equal to 0.10 wt. % and less than or equal to 3.5 wt. % P2O5, greater than or equal to 8.00 wt. % and less than or equal to 17.00 wt. % Li2O, greater than or equal to 4.00 wt. % and less than or equal to 15.00 wt. % ZrO2, and greater than or equal to 0.05 wt. % and less than or equal to 4.00 wt. % CaO.
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公开(公告)号:US20240109806A1
公开(公告)日:2024-04-04
申请号:US18537240
申请日:2023-12-12
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Xiaoju Guo , Pascale Oram , Rostislav Vatchev Roussev , Ljerka Ukrainczyk , Taylor Marie Wilkinson
CPC classification number: C03C21/002 , C03C3/093 , C03C3/125 , C03C4/18 , H05K5/0017 , H05K5/03 , C03C2204/00
Abstract: Methods of manufacturing a glass-based article includes exposing a glass-based substrate having a lithium aluminosilicate composition to an ion exchange treatment to form the glass-based article. The ion exchange treatment including a molten salt bath having a concentration of a sodium salt in a range from 8 mol % to 100 mol %. The glass-based article includes sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article The glass-based article has compressive stress layer extending from the surface to a spike depth of layer from 4 micrometers to 8 micrometers. The glass-based article includes a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8.
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