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公开(公告)号:US11807573B2
公开(公告)日:2023-11-07
申请号:US17893798
申请日:2022-08-23
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Jong Se Park , Vitor Marino Schneider , Wei Sun
CPC classification number: C03C21/002 , C03C3/083
Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about −30 MPa/μm.
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公开(公告)号:US11787728B2
公开(公告)日:2023-10-17
申请号:US17005769
申请日:2020-08-28
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Vitor Marino Schneider , Wei Sun , Taylor Marie Wilkinson
CPC classification number: C03C3/093 , C03C3/091 , C03C4/18 , C03C21/002 , C03C2204/00
Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. The glass-based articles comprise: a thickness t; a lithium aluminosilicate composition; and a molar ratio of sodium oxide (Na2O) to lithium oxide (Li2O) that is less than or equal to 0.63 at the center of the glass-based article. The articles have a molar ratio of sodium dioxide (Na2O) to lithium dioxide (Li2O) in a post-spike near region that is greater than or equal to 0.9 and/or less than 1.5.
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公开(公告)号:US11827559B2
公开(公告)日:2023-11-28
申请号:US17354149
申请日:2021-06-22
Applicant: CORNING INCORPORATED
Inventor: Jason Thomas Harris , Joshua James McCaslin , Naveen Prakash , Vitor Marino Schneider , Charandeep Singh , Ross Johnson Stewart
IPC: C03C21/00 , B32B17/06 , B32B5/14 , B32B7/12 , G02F1/1333
CPC classification number: C03C21/002 , B32B5/145 , B32B7/12 , B32B17/06 , G02F1/133331 , B32B2457/208 , C03C2203/52
Abstract: Frangible glass articles having a fracture behavior that resists ejection of glass particles upon fracture. In some embodiments, the frangible glass articles can have a first surface region with a first elastic compressive stress energy per unit area of glass (Welcomp1), a second surface region with a second elastic compressive stress energy per unit area of glass (Welcomp2), and a central region with an elastic tensile stress energy per unit area of glass (WT), where (Welcomp1+Welcomp2)−WT≤25 J/m2. In some embodiments, the frangible glass articles can have a total load ratio (Wi/GD) less than 6.5 and a total elastic compressive stress energy per unit area of glass (WC) less than 60% of a total load (Wi), where: WC=Welcomp1+Welcomp2, Wi=WC+WT, GD=4G1C, and
G
1
C
=
K
1
C
2
(
1
-
v
2
)
E
.
In some embodiments, the frangible glass articles can have a differential load ratio (Wd/GIC) less than
7
2
e
(
-
1
2
d
1
t
)
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公开(公告)号:US20220402815A1
公开(公告)日:2022-12-22
申请号:US17893798
申请日:2022-08-23
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Jong Se Park , Vitor Marino Schneider , Wei Sun
Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about −30 MPa/μm.
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公开(公告)号:US20210395141A1
公开(公告)日:2021-12-23
申请号:US17354149
申请日:2021-06-22
Applicant: CORNING INCORPORATED
Inventor: Jason Thomas Harris , Joshua James McCaslin , Naveen Prakash , Vitor Marino Schneider , Charandeep Singh , Ross Johnson Stewart
Abstract: Frangible glass articles having a fracture behavior that resists ejection of glass particles upon fracture. In some embodiments, the frangible glass articles can have a first surface region with a first elastic compressive stress energy per unit area of glass (Welcomp1), a second surface region with a second elastic compressive stress energy per unit area of glass (Welcomp2), and a central region with an elastic tensile stress energy per unit area of glass (WT), where (Welcomp1+Welcomp2)−WT≤25 J/m2. In some embodiments, the frangible glass articles can have a total load ratio (Wi/GD) less than 6.5 and a total elastic compressive stress energy per unit area of glass (WC) less than 60% of a total load (Wi), where: WC=Welcomp1+Welcomp2, Wi=WC+WT, GD=4G1C, and G 1 C = K 1 C 2 ( 1 - v 2 ) E . In some embodiments, the frangible glass articles can have a differential load ratio (Wd/GIC) less than 7 2 e ( - 1 2 d 1 t ) .
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公开(公告)号:US11434167B2
公开(公告)日:2022-09-06
申请号:US17318547
申请日:2021-05-12
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Jong Se Park , Vitor Marino Schneider , Wei Sun
Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about −30 MPa/μm.
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公开(公告)号:US20210355026A1
公开(公告)日:2021-11-18
申请号:US17318547
申请日:2021-05-12
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Jong Se Park , Vitor Marino Schneider , Wei Sun
IPC: C03C21/00
Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about −30 MPa/μm.
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公开(公告)号:US20210061705A1
公开(公告)日:2021-03-04
申请号:US17005769
申请日:2020-08-28
Applicant: CORNING INCORPORATED
Inventor: Yuhui Jin , Joshua James McCaslin , Vitor Marino Schneider , Wei Sun , Taylor Marie Wilkinson
Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. The glass-based articles comprise: a thickness t; a lithium aluminosilicate composition; and a molar ratio of sodium oxide (Na2O) to lithium oxide (Li2O) that is less than or equal to 0.63 at the center of the glass-based article. The articles have a molar ratio of sodium dioxide (Na2O) to lithium dioxide (Li2O) in a post-spike near region that is greater than or equal to 0.9 and/or less than 1.5.
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