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公开(公告)号:US10662276B2
公开(公告)日:2020-05-26
申请号:US15774827
申请日:2016-11-09
Applicant: Dow Global Technologies LLC
Inventor: Adam C. Colson , Dan Yu , Daniel A. Aguilar , Amber Marie Stephenson , William H. Heath , Shouren Ge
IPC: C08G18/48 , C08G18/10 , C09D175/08 , C09J175/08 , C08G18/76 , C08G18/32
Abstract: A cured composition including a reaction product of a mixture that includes an isocyanate component having one or more isocyanates and an isocyanate-reactive component having a butylene oxide based polyol, which has a number average molecular weight greater than 2,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from (2) to (4). At least (50) wt % of a total weight of alkylene oxides used to form the butylene oxide based polyol is butylene oxide. An isocyanate index of the mixture is from (90) to (150). The cured composition in a cured state exhibits a first tan delta peak between a first temperature range of 50° C. to 0° C. and a second tan delta peak between a second temperature range of 75° C. and 150° C., according to a tan delta plot over a range of temperatures, and a value of the first tan delta peak and a value of the second tan delta peak each represents a ratio of a loss modulus of the cured composition and a storage modulus of the cured composition at a specific temperature within the range of temperatures, as measured according to dynamic mechanical thermal analysis. The values of the first and the second tan delta peaks are from (0.10) to (0.90).
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公开(公告)号:US20150307651A1
公开(公告)日:2015-10-29
申请号:US14652295
申请日:2013-12-13
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: Kwanho Chang , Jia Xie , Shouren Ge , Nathan Wilmot , Rajat Duggal
IPC: C08G59/50
CPC classification number: C08G59/5006 , C08G59/066 , C08G59/64 , C08G59/682 , C08G59/685 , C08K5/098 , C08K5/56 , C08L63/00
Abstract: An epoxy composition that includes an epoxy-terminated prepolymer, an alkanolamine hardener having at least one hydroxyl group and an organometallic compound, where amine groups of the alkanolamine hardener react with epoxy groups of the epoxy-terminated prepolymer in a stoichiometric ratio to form a cured epoxy composition. The epoxy-terminated prepolymer is formed from a reaction product of an amine terminated polymeric polyol and a molar excess of epoxy groups in an epoxy monomer, relative to a molar amount of amine groups in the amine terminated polymeric polyol.
Abstract translation: 包含环氧基封端的预聚物,具有至少一个羟基的烷醇胺硬化剂和有机金属化合物的环氧组合物,其中链烷醇胺硬化剂的胺基以化学计量比与环氧基封端的预聚物的环氧基团反应,形成固化的 环氧组成。 环氧基封端的预聚物相对于胺封端的聚合多元醇中的胺基摩尔量,由胺封端的聚合多元醇与环氧单体中摩尔过量的环氧基的反应产物形成。
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公开(公告)号:US20180346637A1
公开(公告)日:2018-12-06
申请号:US15774827
申请日:2016-11-09
Applicant: Dow Global Technologies LLC
Inventor: Adam C. Colson , Dan Yu , Daniel A. Aguilar , Amber Marie Stephenson , William H. Heath , Shouren Ge
IPC: C08G18/48 , C08G18/76 , C08G18/10 , C09J175/08 , C09D175/08
CPC classification number: C08G18/4854 , C08G18/10 , C08G18/3206 , C08G18/4812 , C08G18/7614 , C08G18/7671 , C09D175/08 , C09J175/08 , C08G18/48
Abstract: A cured composition including a reaction product of a mixture that includes an isocyanate component having one or more isocyanates and an isocyanate-reactive component having a butylene oxide based polyol, which has a number average molecular weight greater than 2,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from (2) to (4). At least (50) wt % of a total weight of alkylene oxides used to form the butylene oxide based polyol is butylene oxide. An isocyanate index of the mixture is from (90) to (150). The cured composition in a cured state exhibits a first tan delta peak between a first temperature range of 50° C. to 0° C. and a second tan delta peak between a second temperature range of 75° C. and 150° C., according to a tan delta plot over a range of temperatures, and a value of the first tan delta peak and a value of the second tan delta peak each represents a ratio of a loss modulus of the cured composition and a storage modulus of the cured composition at a specific temperature within the range of temperatures, as measured according to dynamic mechanical thermal analysis. The values of the first and the second tan delta peaks are from (0.10) to (0.90).
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公开(公告)号:US09771450B2
公开(公告)日:2017-09-26
申请号:US14652295
申请日:2013-12-13
Applicant: Dow Global Technologies LLC
Inventor: Kwanho Chang , Jia Xie , Shouren Ge , Nathan Wilmot , Rajat Duggal
CPC classification number: C08G59/5006 , C08G59/066 , C08G59/64 , C08G59/682 , C08G59/685 , C08K5/098 , C08K5/56 , C08L63/00
Abstract: An epoxy composition that includes an epoxy-terminated prepolymer, an alkanolamine hardener having at least one hydroxyl group and an organometallic compound, where amine groups of the alkanolamine hardener react with epoxy groups of the epoxy-terminated prepolymer in a stoichiometric ratio to form a cured epoxy composition. The epoxy-terminated prepolymer is formed from a reaction product of an amine terminated polymeric polyol and a molar excess of epoxy groups in an epoxy monomer, relative to a molar amount of amine groups in the amine terminated polymeric polyol.
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公开(公告)号:US20200009511A1
公开(公告)日:2020-01-09
申请号:US16494948
申请日:2018-03-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor: Praveen Agarwal , Peter E. M. Aerts , Tamara Dikic , Shouren Ge , Robert E. Hefner , Yuanqiao Rao , Bart G. M. Rijksen , Ian A. Tomlinson
Abstract: A composite membrane including a porous support and a thin film layer comprising a reaction product of: i) a polymer comprising a sub-unit including a Troger's base moiety represented by Formula I: wherein L includes an arylene group substituted with at least one carboxylic acid or a corresponding salt or ester group, or a hydroxyl; and ii) a crosslinking agent selected from at least one of: a) a multifunctional epoxy compound and b) a multifunctional azide compound.
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