Transition metal complexes, catalysts composition containing the same, and process for preparing ethylene homopolymers or copolymers of ethylene and alpha-olefins using the same
    5.
    发明授权
    Transition metal complexes, catalysts composition containing the same, and process for preparing ethylene homopolymers or copolymers of ethylene and alpha-olefins using the same 有权
    过渡金属络合物,含有它们的催化剂组合物以及使用其制备乙烯均聚物或乙烯和α-烯烃的共聚物的方法

    公开(公告)号:US08344081B2

    公开(公告)日:2013-01-01

    申请号:US12808257

    申请日:2008-10-30

    CPC分类号: C07F17/00

    摘要: The present invention relates to a transition metal complex useful as a transition metal catalyst in the preparation of an ethylene homopolymer or a copolymer of ethylene and an α-olefin, a catalyst composition comprising the same and a process of preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same. More particularly, it relates to a transition metal complex having a cyclopentadiene derivative and at least one phenyl oxide ligand substituted at the 2-position of phenyl with, for example, a silyl group having a C1-C30 hydrocarbon group or a C1-C20 hydrocarbon group, around a group IV transition metal, with no crosslinkage between the ligands, a catalyst composition comprising the transition metal complex and a cocatalyst selected from the group consisting of an aluminoxane and a boron compound, and a process for preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same.

    摘要翻译: 本发明涉及在乙烯均聚物或乙烯与α-烯烃的共聚物的制备中用作过渡金属催化剂的过渡金属络合物,包含该过渡金属络合物的催化剂组合物和制备乙烯均聚物或共聚物的方法 的乙烯和使用其的α-烯烃。 更具体地说,本发明涉及具有环戊二烯衍生物和至少一个苯基氧化物配位体的过渡金属络合物,其在苯基的2-位被取代,例如具有C 1 -C 30烃基或C 1 -C 20烃的甲硅烷基 在IV族过渡金属周围,配体之间没有交联,包含过渡金属配合物的催化剂组合物和选自铝氧烷和硼化合物的助催化剂,以及制备乙烯均聚物或 乙烯与使用其的α-烯烃的共聚物。

    TRANSITION METAL COMPLEXES, CATALYSTS COMPOSITION CONTAINING THE SAME, AND PROCESS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND ALPHA-OLEFINS USING THE SAME
    6.
    发明申请
    TRANSITION METAL COMPLEXES, CATALYSTS COMPOSITION CONTAINING THE SAME, AND PROCESS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND ALPHA-OLEFINS USING THE SAME 有权
    过渡金属络合物,含有它们的催化剂组合物,以及使用其制备乙烯共聚物或乙烯和α-烯烃的共聚物的方法

    公开(公告)号:US20100298512A1

    公开(公告)日:2010-11-25

    申请号:US12808257

    申请日:2008-10-30

    CPC分类号: C07F17/00

    摘要: The present invention relates to a transition metal complex useful as a transition metal catalyst in the preparation of an ethylene homopolymer or a copolymer of ethylene and an α-olefin, a catalyst composition comprising the same and a process of preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same. More particularly, it relates to a transition metal complex having a cyclopentadiene derivative and at least one phenyl oxide ligand substituted at the 2-position of phenyl with, for example, a silyl group having a C1-C30 hydrocarbon group or a C1-C20 hydrocarbon group, around a group IV transition metal, with no crosslinkage between the ligands, a catalyst composition comprising the transition metal complex and a cocatalyst selected from the group consisting of an aluminoxane and a boron compound, and a process for preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same.

    摘要翻译: 本发明涉及在乙烯均聚物或乙烯与α-烯烃的共聚物的制备中用作过渡金属催化剂的过渡金属络合物,包含该过渡金属络合物的催化剂组合物和制备乙烯均聚物或共聚物的方法 的乙烯和使用其的α-烯烃。 更具体地说,本发明涉及具有环戊二烯衍生物和至少一个苯基氧化物配位体的过渡金属络合物,其在苯基的2-位被取代,例如具有C 1 -C 30烃基或C 1 -C 20烃的甲硅烷基 在IV族过渡金属周围,配体之间没有交联,包含过渡金属配合物的催化剂组合物和选自铝氧烷和硼化合物的助催化剂,以及制备乙烯均聚物或 乙烯与使用其的α-烯烃的共聚物。

    Quinoline compound extracted from scolopendra subspinipes, and
derivatives thereof
    10.
    发明授权
    Quinoline compound extracted from scolopendra subspinipes, and derivatives thereof 失效
    蛇舌草素提取的喹啉化合物及其衍生物

    公开(公告)号:US5824689A

    公开(公告)日:1998-10-20

    申请号:US865126

    申请日:1997-05-30

    CPC分类号: C07D215/26

    摘要: The jineol extracted from scolopendra subspinipes is represented as the following formula (I): ##STR1## The jineol is obtained from scolopendra subspinipes by extracting scolopendra subspinipes with a solvent, separating an activating portion from the extracted liquid with an organic solvent, and purifying an anticancerous activating portion from the activating portion by chromatography. The jineol derivatives prepared from the jineol extracted scolopendra subspinipes are represented as the following formula (II): ##STR2## wherein each R.sub.1 and R.sub.2, independently of each other, is a hydrogen; a lower alkyl group of C.sub.1 to C.sub.6 ; a cycloalkyl group of C.sub.5 to C.sub.7 having a substituting group; an alkyl group of C.sub.1 to C.sub.4 having a phenyl group with one to three substituting groups; a lower alkyl group of C.sub.1 to C.sub.6 having a hydroxy, an alkoxy having C.sub.1 to C.sub.5, or an aryloxy; a lower acyl group of C.sub.1 to C.sub.7 having a hydroxy, an alkoxy having C.sub.1 to C.sub.5, or an aryloxy; a cycloalkylcarbonyl group of C.sub.5 to C.sub.7 with one to three substituting groups; or an acyl group of C.sub.1 to C.sub.4 having a phenyl group with one to three substituting groups.

    摘要翻译: 从o藜提取的金枪鱼以下列公式(I)表示:ι(I)通过用溶剂提取槐叶子菜子,通过用有机溶剂从提取的液体中分离活化部分,从sc ra子菜子得到金银花, 并通过色谱法从活化部分纯化抗癌活化部分。 由金枪鱼提取的scolopendra subspinipes制备的jineol衍生物由下式(II)表示:其中每个R 1和R 2彼此独立地为氢; C1至C6的低级烷基; 具有取代基的C5〜C7的环烷基; 具有1-3个取代基的苯基的C1〜C4的烷基; 具有羟基的C1至C6的低级烷基,具有C1至C5的烷氧基或芳氧基; 具有羟基的C1至C7的低级酰基,具有C1至C5的烷氧基或芳氧基; 具有一至三个取代基的C5至C7的环烷基羰基; 或具有1-3个取代基的苯基的C1〜C4酰基。