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    Process for the production of acetic acid
    1.
    发明申请
    Process for the production of acetic acid 有权
    乙酸生产工艺

    公开(公告)号：US20050176996A1

    公开(公告)日：2005-08-11

    申请号：US10516623

    申请日：2003-05-29

    申请人： David Law ,  Andrew Poole ,  Stephen Smith ,  John Sunley

    发明人： David Law ,  Andrew Poole ,  Stephen Smith ,  John Sunley

    IPC分类号： C07B61/00 ,  C07C51/12 ,  C07C53/08 ,  C07C53/122 ,  C07C51/15

    CPC分类号： C07C51/12 ,  C07C53/08

    摘要： A process for the production of acetic acid by carbonylating methanol and/or a reactive derivative thereof with carbon monoxide in a carbonylation reactor containing a liquid reaction composition comprising an iridium carbonylation catalyst, methyl iodide co-catalyst, a finite concentration of water, acetic acid, methyl acetate, at least one promoter selected from ruthenium, osmium and rhenium and a stablising compound selected from the group consisting of alkali metal iodides, alkaline earth metal iodides, metal complexes capable of generating I—, salts capable of generating I—, and mixtures of two or more thereof wherein the molar ratio of promoter to iridium is greater than 2:1, and the molar ratio of stabilising compound to iridium is in the range [greater than 0 to 5]:1.

    摘要翻译： 在含有液体反应组合物的羰基化反应器中通过羰基化甲醇和/或其与一氧化碳的反应性衍生物生产乙酸的方法，所述液体反应组合物包含铱羰基化催化剂，甲基碘助催化剂，有限浓度的水，乙酸 乙酸甲酯，选自钌，锇和铼的至少一种助催化剂和选自碱金属碘化物，碱土金属碘化物，能够产生I-的金属络合物，能产生I-的盐的稳定化合物，和 其中两种或更多种的混合物，其中助催化剂与铱的摩尔比大于2:1，稳定化合物与铱的摩尔比在[大于0至5]：1范围内。

    Process For The Removal Of Corrosion Metals From Carbonylation Catalyst Solutions
    2.
    发明申请
    Process For The Removal Of Corrosion Metals From Carbonylation Catalyst Solutions 有权
    从羰基化催化剂溶液中去除腐蚀金属的工艺

    公开(公告)号：US20070298960A1

    公开(公告)日：2007-12-27

    申请号：US11587339

    申请日：2005-03-31

    申请人： Andrew Poole ,  Stephen Smith

    发明人： Andrew Poole ,  Stephen Smith

    IPC分类号： B01J38/74

    CPC分类号： B01J38/74 ,  B01J31/4038

    摘要： A process for the removal of corrosion metal contaminants from a carbonylation catalyst solution comprising an iridium and/or rhodium carbonylation catalyst, an alkali and/or alkaline earth metal and corrosion metal contaminants in which the catalyst solution is contacted with a cation exchange resin having its active sites partially loaded with a sufficient amount of alkali and/or alkaline earth metal to maintain the concentration of said alkali and/or alkaline earth metal in the catalyst solution and recovering a catalyst solution of reduced corrosion metal contaminant content.

    摘要翻译： 一种用于从包含铱和/或铑羰基化催化剂，碱金属和/或碱土金属以及腐蚀金属污染物的羰基化催化剂溶液中除去腐蚀金属污染物的方法，其中催化剂溶液与具有其的阳离子交换树脂接触 活性位点部分地装载足够量的碱金属和/或碱土金属，以保持催化剂溶液中所述碱金属和/或碱土金属的浓度，并回收具有降低的腐蚀金属污染物含量的催化剂溶液。

    Process for the production of acetic acid
    6.
    发明申请
    Process for the production of acetic acid 失效
    乙酸生产工艺

    公开(公告)号：US20060122422A1

    公开(公告)日：2006-06-08

    申请号：US10528387

    申请日：2003-09-03

    申请人： Lesley Key ,  Marc Payne ,  Andrew Poole

    发明人： Lesley Key ,  Marc Payne ,  Andrew Poole

    IPC分类号： C07C51/12

    CPC分类号： C07C51/12 ,  C07C53/08

    摘要： A process for the production of acetic acid by carbonylating methanol and/or a reactive derivative thereof with carbon monoxide in at least one carbonylation reaction zone containing a liquid reaction composition comprising an iridium carbonylation catalyst, methyl iodide co-catalyst, a finite concentration of water, acetic acid, methyl acetate, at least one promoter selected from ruthenium, osmium and rhenium and at least one catalyst system stabiliser selected from indium, cadmium, mercury, gallium and zinc and wherein the molar ratio of iridium:promoter:stabiliser in the liquid reaction composition is maintained in the range 1:(>2 to 15):(0.25 to 12).

    摘要翻译： 一种通过在含有铱羰基化催化剂，甲基碘助催化剂，有限浓度的水的液体反应组合物的至少一个羰基化反应区中使甲醇和/或其活性衍生物与一氧化碳羰基化来生产乙酸的方法 ，乙酸，乙酸甲酯，至少一种选自钌，锇和铼的促进剂和至少一种选自铟，镉，汞，镓和锌的催化剂体系稳定剂，其中铱：促进剂：稳定剂在液体中的摩尔比 反应组合物保持在1：（> 2〜15）：（0.25〜12）的范围内。

    Optimal provisioning and management of bandwidth in a video-on-demand services architecture
    7.
    发明授权
    Optimal provisioning and management of bandwidth in a video-on-demand services architecture 有权

    公开(公告)号：US09807460B2

    公开(公告)日：2017-10-31

    申请号：US10639006

    申请日：2003-08-11

    申请人： Joseph Matarese ,  Andrew Poole ,  George Scott Pinson

    发明人： Joseph Matarese ,  Andrew Poole ,  George Scott Pinson

    IPC分类号： H04N7/173 ,  H04N21/472 ,  H04N21/2225 ,  H04N21/2343 ,  H04N21/24

    CPC分类号： H04N21/47202 ,  H04N7/17336 ,  H04N21/2225 ,  H04N21/234381 ,  H04N21/2402

    摘要： A video-on-demand server includes interface modules each providing a communication interface between the video-on-demand server and a switching network; an interface to a management module to monitor and provide to the video-on-demand server information on video-on-demand bandwidth utilization of network resources allocated to particular service groups, each service group including video-on-demand customers sharing a same fixed network bandwidth allocation; each interface module communicatively coupled to service groups simultaneously via service gateways; a total bandwidth of the server is an aggregate bandwidth of all the interface modules, and is less than an aggregate bandwidth of all service groups assigned to be serviced by the server, the switching network configured to make the server available for receiving video on demand service requests from all of the service group customers simultaneously; the server adapted to dynamically assign bandwidth of the server to service groups, by adapting the switching network to dynamically change communication connections between interface modules and service groups, the adaptations to the switching network based upon information about the bandwidth utilization of network resources received from the management module.

    Dynamic zoning for targeted ad insertion
    8.
    发明申请
    Dynamic zoning for targeted ad insertion 有权
    针对广告插入的动态分区

    公开(公告)号：US20080034386A1

    公开(公告)日：2008-02-07

    申请号：US11821083

    申请日：2007-06-20

    申请人： Guy Cherry ,  Joseph Matarese ,  Andrew Poole

    发明人： Guy Cherry ,  Joseph Matarese ,  Andrew Poole

    IPC分类号： H04N7/10

    CPC分类号： H04N7/165 ,  H04N21/2385 ,  H04N21/2402 ,  H04N21/25883 ,  H04N21/2668 ,  H04N21/4383 ,  H04N21/6543 ,  H04N21/812

    摘要： A custom ad selection and delivery system may include an ad selector to select candidate ads for one or more ad avail opportunities, a bandwidth resource manager to provide information about available bandwidth in a content delivery system, and a policy manager to weight ad avail opportunity versus bandwidth costs to delivery customized advertising to subscribers, and to cause allocation of bandwidth and insertion of customized ads into multiple program streams comprising the same program content but different ad content, and to cause different subscriber equipment to map different program frequencies to similar content streams having advertising content inserted therein that is customized to different subscriber demographics.

    摘要翻译： 自定义广告选择和递送系统可以包括广告选择器以选择用于一个或多个广告可用机会的候选广告，带宽资源管理器，以提供关于内容递送系统中的可用带宽的信息，以及策略管理器，以将广告可用机会权重 为订户交付定制广告的带宽成本，并且使带宽分配和定制广告插入到包括相同节目内容但不同广告内容的多个节目流中，并且导致不同的用户设备将不同节目频率映射到具有 插入其中的广告内容是根据不同的用户人口统计特制定制的。