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1.发明授权Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins 失效用于乙烯低聚成直链α-烯烃的非对称配体及其催化剂体系公开(公告)号：US06710006B2
公开(公告)日：2004-03-23
申请号：US09775128
申请日：2001-02-01
申请人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
IPC分类号： B01J3122
CPC分类号： C07D213/53 , Y02P20/582
摘要： Non-symmetrical ligands of formula (I); bis-aryliminepyridine MXn complexes comprising a non-symmetrical ligand of formula (I), wherein M is a metal selected from Fe or Co, n is 2 or 3, and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; [bis-aryliminepyridine MYp.Ln+][NC−]q complexes, comprising a non-symmetrical ligand of formula (I), wherein Y is a ligand which may insert an olefin, M is Fe or Co, NC− is a non-coordinating anion and p+q is 2 or 3, matching the formal oxidation of the metal atom M, L is a neutral Lewis donor molecule and n=0, 1, or 2; and processes for the production of alpha-olefins from ethylene, using said complexes.
摘要翻译： 式（I）的非对称配体;包含式（I）的非对称配位体的双芳基亚氨基吡啶MXn络合物，其中M为选自Fe或Co的金属，n为2或3，X为卤化物，任选地 取代的烃基，醇盐，酰胺或氢化物; 包含式（I）的非对称配位体的[双芳基亚氨基吡啶MYp.Ln +] [NC n] q络合物，其中Y是可插入烯烃的配体，M是Fe或Co，NC 是一种非配位阴离子，p + q为2或3，匹配金属原子M的形式氧化，L为中性Lewis供体分子，n = 0,1或2; 以及使用所述复合物从乙烯生产α-烯烃的方法。
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2.发明授权Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins 失效用于乙烯低聚成直链α-烯烃的非对称配体及其催化剂体系公开(公告)号：US07179871B2
公开(公告)日：2007-02-20
申请号：US10320213
申请日：2002-12-16
申请人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
发明人： Eric Johannes Maria De Boer , Henderikus Hyacinthus Deuling , Harry Van Der Heijden , Nicolaas Meijboom , Aart Bartus Van Oort , Arie Van Zon
CPC分类号： C07D213/53 , Y02P20/582
摘要： Non-symmetrical ligands of formula (I); bis-aryliminepyridine MXn complexes comprising a non-symmetrical ligand of formula (I), wherein M is a metal selected from Fe or Co, n is 2 or 3, and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; [bis-aryliminepyridine MYp.Ln+][NC−]q complexes, comprising a non-symmetrical ligand of formula (I), wherein Y is a ligand which may insert an olefin, M is Fe or Co, NC− is a non-coordinating anion and p+q is 2 or 3, matching the formal oxidation of the metal atom M, L is a neutral Lewis donor molecule and n=0, 1, or 2; and processes for the production of alpha-olefins from ethylene, using said complexes.
摘要翻译： 式（I）的非对称配体; 包含式（I）的非对称配位体的双芳基亚氨基吡啶MX复合物，其中M为选自Fe或Co的金属，n为2或3，X为卤化物，任选取代的烃基 ，醇盐，酰胺或氢化物; [双 - 芳基亚氨基吡啶] n + 1 / n + >络合物，其包含式（I）的非对称配体，其中Y是可插入烯烃的配体，M是Fe或Co，NC是非配位阴离子，p + q是2或3，匹配金属原子M的形式氧化，L是中性Lewis供体分子，n = 0,1或2; 以及使用所述复合物从乙烯生产α-烯烃的方法。
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3.发明授权Ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins 失效用于乙烯低聚成直链α-烯烃的配体及其催化剂体系公开(公告)号：US06683187B2
公开(公告)日：2004-01-27
申请号：US09894680
申请日：2001-06-28
IPC分类号： C07D21361
CPC分类号： C07F15/065 , B01J31/1815 , B01J2231/20 , B01J2531/0244 , B01J2531/842 , B01J2531/845 , C07C2/32 , C07C2531/22 , C07D213/53 , C07F15/025 , Y02P20/582
摘要： Ligands of formula (V); bis-aryliminepyridine MXn complexes comprising a ligand of formula (V), wherein M is a metal selected from Fe and Co, n is 2 or 3, and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; [bis-aryliminepyridine MYp.Ln+] [NC31 ]q complexes, comprising a ligand of formula (V), wherein Y is a ligand which may insert an olefin, M is Fe or Co, NC− is a non-coordinating anion and p+q is 2 or 3, matching the formal oxidation of the metal atom M, L is a neutral Lewis donor molecule and n=0, 1, or 2; and processes for the production of alpha-olefins from ethylene, using said complexes.
摘要翻译： 式（Ⅴ）配体;包含式（Ⅴ）配位体的双芳基亚氨基吡啶MXn络合物，其中M为选自Fe和Co的金属，n为2或3，X为卤化物，任选取代的烃基，醇盐，酰胺 ，或氢化物; 包含式（Ⅴ）配位体的[双芳基亚氨基吡啶MYp.Ln +] [NC 31] q络合物，其中Y是可插入烯烃的配体，M是Fe或Co，NC 是非配位阴离子，p + q是2或3，匹配金属原子M的形式氧化，L是中性路易斯供体分子，n = 0,1或2; 以及使用所述复合物从乙烯生产α-烯烃的方法。
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公开(公告)号：US4994592A
公开(公告)日：1991-02-19
申请号：US364779
申请日：1989-06-12
IPC分类号： C07F9/50 , B01J23/10 , B01J23/44 , B01J23/58 , B01J31/04 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , B01J32/00 , B01J35/06 , C08G67/00 , C08G67/02
CPC分类号： C08G67/02 , B01J31/1608 , B01J31/2409 , B01J2531/824 , B01J31/2208
摘要： In the process of producing a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon in the presence of a palladium salt, the anion of a strong non-hydrohalogenic acid, and a phosphine ligand, improved polymerization rates are obtained when employing a novel catalyst composition formed from a novel 1,3-bis(phosphino)-2-silapropane, which can be produced with high yield, wherein the 2-silapropane moiety is additionally substituted at the silicon atom with two hydrocarbyl substituents.
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5.发明授权Carbon monoxide/olefin co-polymerization process with phosphino substituted sulfonic acid catalyst 失效一氧化碳/烯烃共聚过程与膦取代的磺酸催化剂
公开(公告)号：US4855399A
公开(公告)日：1989-08-08
申请号：US140013
申请日：1987-12-31
申请人： Johannes A. Van Doorn , Eit Drent , Petrus W. N. M. Van Leeuwen , Nicolaas Meijboom , Aart B. Van Oort , Richard L. Wife
发明人： Johannes A. Van Doorn , Eit Drent , Petrus W. N. M. Van Leeuwen , Nicolaas Meijboom , Aart B. Van Oort , Richard L. Wife
CPC分类号： C08G67/02 , C07F9/5004 , C07F9/5022
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a catalyst composition formed from a palladium salt and a phosphino-substituted sulfonic acid.
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公开(公告)号：US5118854A
公开(公告)日：1992-06-02
申请号：US771888
申请日：1991-10-07
CPC分类号： C07F9/28 , C07F9/5027
摘要： Alkali metal di(2-alkoxyphenyl)phosphide is produced in good yield by reaction of alkali metal and the corresponding tri(2-alkoxyphenyl)-phosphine in liquid ammonia.
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公开(公告)号：US4940683A
公开(公告)日：1990-07-10
申请号：US311260
申请日：1989-02-16
申请人： Johannes A. Van Doorn , Eit Drent , Petrus W. N. M. Van Leeuwen , Nicolaas Meijboom , Aart B. Van Oort , Richard L. Wife
发明人： Johannes A. Van Doorn , Eit Drent , Petrus W. N. M. Van Leeuwen , Nicolaas Meijboom , Aart B. Van Oort , Richard L. Wife
CPC分类号： C08G67/02 , C07F9/5004 , C07F9/5022
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a catalyst composition formed from a palladium salt and a phosphino-substituted sulfonic acid.
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公开(公告)号：US4935396A
公开(公告)日：1990-06-19
申请号：US364778
申请日：1989-06-12
IPC分类号： C07F9/50 , B01J23/10 , B01J23/44 , B01J23/58 , B01J31/04 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , B01J32/00 , B01J35/06 , C08G67/00 , C08G67/02
CPC分类号： C08G67/02 , B01J31/1608 , B01J31/2409 , B01J2531/824 , B01J31/2208
摘要： In the process of producing a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon in the presence of a palladium salt, the anion of a strong non-hydrohalogenic acid, and a phosphine ligand, improved polymerization rates are obtained when employing a novel catalyst composition formed from a novel 1,3-bis(phosphino)-2-silapropane, which can be produced with high yield, wherein the 2-silapropane moiety is additionally substituted at the silicon atom with two hydrocarbyl substituents.
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公开(公告)号：US4889956A
公开(公告)日：1989-12-26
申请号：US175018
申请日：1988-03-30
摘要： Benzyl- or allyl- di(polar-substituted-phenyl)phosphines are converted in good yield to the corresponding alkali metal di(polar-substituted-phenyl)phosphide by reaction with alkali metal in liquid ammonia.
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10.发明授权Carbon monoxide/olefin polymerization process with bis (diaryl phosphino) 2-silapropane containing catalyst 失效一氧化碳/烯烃聚合方法与双（二芳基膦基）2-硅烷丙烷的催化剂
公开(公告)号：US4880900A
公开(公告)日：1989-11-14
申请号：US222993
申请日：1988-07-22
IPC分类号： C07F9/50 , B01J23/10 , B01J23/44 , B01J23/58 , B01J31/04 , B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , B01J32/00 , B01J35/06 , C08G67/00 , C08G67/02
CPC分类号： C08G67/02 , B01J31/1608 , B01J31/2409 , B01J2531/824 , B01J31/2208
摘要： In the process of producing a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon in the presence of a palladium salt, the anion of a strong non-hydrohalogenic acid, and a phosphine ligand, improved polymerization rates are obtained when employing a novel catalyst composition formed from a novel 1,3-bis(phosphino)-2-silapropane, which can be produced with high yield, wherein the 2-silapropane moiety is additionally substituted at the silicon atom with two hydrocarbyl substituents.
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