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1.发明授权Use of hydrogen and an organozinc compound for polymerization and polymer property control 有权氢和有机锌化合物用于聚合和聚合物性质控制公开(公告)号：US08501882B2
公开(公告)日：2013-08-06
申请号：US13329404
申请日：2011-12-19
申请人： Errun Ding , Qing Yang , Albert P. Masino , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
发明人： Errun Ding , Qing Yang , Albert P. Masino , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
IPC分类号： C08F4/00 , C08F4/06 , C08F4/12 , C08F2/00 , C08F210/00
CPC分类号： C08F210/16 , C08F10/00 , C08F110/02 , C08F2400/02 , C08F2/00 , C08F2/42 , C08F2500/04 , C08F2500/12
摘要： Methods of controlling polymerization reactions using a synergistic amount of hydrogen and an organozinc compound are disclosed. The resulting polymers have lower molecular weights and higher melt flow indices.
摘要翻译： 公开了使用协同量的氢和有机锌化合物控制聚合反应的方法。 所得聚合物具有较低的分子量和较高的熔体流动指数。
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2.发明申请Use of Hydrogen and an Organozinc Compound for Polymerization and Polymer Property Control 有权氢和有机锌化合物用于聚合和聚合物性质控制的应用公开(公告)号：US20130158216A1
公开(公告)日：2013-06-20
申请号：US13329404
申请日：2011-12-19
申请人： Errun Ding , Qing Yang , Albert P. Masino , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
发明人： Errun Ding , Qing Yang , Albert P. Masino , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
CPC分类号： C08F210/16 , C08F10/00 , C08F110/02 , C08F2400/02 , C08F2/00 , C08F2/42 , C08F2500/04 , C08F2500/12
摘要： Methods of controlling polymerization reactions using a synergistic amount of hydrogen and an organozinc compound are disclosed. The resulting polymers have lower molecular weights and higher melt flow indices.
摘要翻译： 公开了使用协同量的氢和有机锌化合物控制聚合反应的方法。 所得聚合物具有较低的分子量和较高的熔体流动指数。
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3.发明授权公开(公告)号：US08431729B2
公开(公告)日：2013-04-30
申请号：US13198009
申请日：2011-08-04
申请人： Joel L. Martin , Qing Yang , Max P. McDaniel , Jim B. Askew
发明人： Joel L. Martin , Qing Yang , Max P. McDaniel , Jim B. Askew
IPC分类号： C07F17/00 , C08F4/642 , C08F4/6592 , B01J31/22
CPC分类号： C08F4/76 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F210/16 , C08F4/65927 , C08F210/14
摘要： The present invention discloses catalyst compositions employing silicon-bridged metallocene compounds with bulky substituents. Methods for making these silicon-bridged metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
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4.发明申请High Activity Catalyst Compositions Containing Silicon-Bridged Metallocenes with Bulky Substituents 有权含有大桥状金属茂的高活性催化剂组合物与大量取代基公开(公告)号：US20130035458A1
公开(公告)日：2013-02-07
申请号：US13198009
申请日：2011-08-04
申请人： Joel L. Martin , Qing Yang , Max P. McDaniel , Jim B. Askew
发明人： Joel L. Martin , Qing Yang , Max P. McDaniel , Jim B. Askew
IPC分类号： C08F4/76 , C08F2/01 , C08F4/6592 , C07F17/00 , C07F19/00
CPC分类号： C08F4/76 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F210/16 , C08F4/65927 , C08F210/14
摘要： The present invention discloses catalyst compositions employing silicon-bridged metallocene compounds with bulky substituents. Methods for making these silicon-bridged metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
摘要翻译： 本发明公开了使用具有庞大取代基的硅桥连金属茂化合物的催化剂组合物。 还提供了制备这些硅桥联金属茂化合物和在催化剂组合物中用于烯烃聚合的方法。
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公开(公告)号：US07750095B2
公开(公告)日：2010-07-06
申请号：US12229392
申请日：2008-08-22
申请人： Joel L. Martin , Jim B. Askew
发明人： Joel L. Martin , Jim B. Askew
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F2/005 , C08F210/14
摘要： The techniques disclosed provide a treatment method for passivating the interior surface of a polymerization reactor to minimize the formation of a polymer coating on the surface. The passivation is performed using a passivating agent that reacts with adsorbed water to form labile passivation products. Both the passivating agent and passivation products may be easily removed from the reactor prior to polymerization. Other embodiments provide a reactor system with a tank configured to automatically add a passivating agent to the reactor and processes for making polymers using a treated reactor.
摘要翻译： 所公开的技术提供了一种用于钝化聚合反应器的内表面以最小化表面上的聚合物涂层的形成的处理方法。 使用与吸附的水反应以形成不稳定钝化产物的钝化剂进行钝化。 在聚合之前，钝化剂和钝化产物都可以容易地从反应器中除去。 其他实施方案提供了一种反应器系统，其具有配置成自动将钝化剂添加到反应器中的罐和使用经处理的反应器制备聚合物的方法。
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公开(公告)号：US20100048837A1
公开(公告)日：2010-02-25
申请号：US12229392
申请日：2008-08-22
申请人： Joel L. Martin , Jim B. Askew
发明人： Joel L. Martin , Jim B. Askew
IPC分类号： C08F2/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F2/005 , C08F210/14
摘要： The techniques disclosed provide a treatment method for passivating the interior surface of a polymerization reactor to minimize the formation of a polymer coating on the surface. The passivation is performed using a passivating agent that reacts with adsorbed water to form labile passivation products. Both the passivating agent and passivation products may be easily removed from the reactor prior to polymerization. Other embodiments provide a reactor system with a tank configured to automatically add a passivating agent to the reactor and processes for making polymers using a treated reactor.
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