Abstract:
The present application provides for metal rings and ceramic collars for active brazing in sodium-based thermal batteries. The metal rings may be outer and inner Ni rings configured for sealing to an alpha-alumina collar via active brazing for use in NaMx cells. The inner and outer Ni metal rings may be sealed to differing portions of the alpha-alumina collar. The portions of the outer and inner Ni rings active brazed to the alpha-alumina collar may define a tapered thickness that reduces internal stresses at the active brazed joints resulting from differing coefficients of thermal expansion between the Ni metal rings and the alpha-alumina collar. The portions of the outer and inner Ni rings and alpha-alumina collar sealed by active brazing, and thereby the active braze joints themselves, may be oriented to control or dictate the stresses on the joints during use.
Abstract:
The present application provides configurations, components, assemblies and methods for sealing cells of sodium-based thermal batteries, such as NaMx cells, without a bridge member. In some embodimentsl the cells may include an electrically conductive case directly hermetically sealed to an electrically insulating ceramic collar of the cell to hermetically seal an anodic chamber of the cell. In some embodiments the ceramic collar and an electrolyte separator tube may be a cosintered one-piece member. In some embodiments the case and the ceramic collar and separator tube may form a hermetically sealed anodic chamber therebetween. In some embodiments the separator tube may define, at least in part, a cathodic chamber therein. In some embodiments the cells may include a current collector hermetically sealed to the ceramic collar, and a cap member hermetically sealed to the current collector to hermetically seal the cathodic chamber of the cell.
Abstract:
A method for joining a metal component to a ceramic component is presented. The method includes disposing a metallic barrier layer on a metallized portion of the ceramic component, and joining the metal component to the metallized portion of the ceramic component through the metallic barrier layer. The metallic barrier layer comprises nickel and a melting point depressant. The metallic barrier layer is disposed by a screen printing process, followed by sintering the layer at a temperature less than about 1000 degrees Celsius. A sealing structure including a joint between a ceramic component and a metal component is also presented.
Abstract:
The present application provides configurations, components, assemblies and methods for sealing cells of sodium-based thermal batteries, such as NaMx cells. In some embodiments the cells may include an integrated bridge member hermetically sealed to an electrically conductive case and a ceramic collar of the cell to hermetically seal an anodic chamber of the cell. In some embodiments the cells may include the ceramic collar hermetically sealed to an electrolyte separator tube of the cell to hermetically seal the anodic chamber of the cell. In some embodiments the anodic chamber may be defined, at least in part, by the case, integrated bridge member, ceramic collar and electrolyte separator tube. In some embodiments the cells may include a current collector hermetically sealed to the ceramic collar, and a cap member hermetically sealed to the current collector tube to hermetically seal a cathodic chamber of the cell.
Abstract:
The present application provides for ceramic collars and metal rings for active brazing in sodium-based thermal batteries. The ceramic collar may be an alpha-alumina collar configured for active brazing, and thereby sealing, to outer and inner Ni rings for use in NaMx cells. The portions of the alpha-alumina collar active brazed to the outer and inner Ni rings may be outwardly facing and include inwardly extending recesses. The portions of the outer and inner Ni rings active brazed to the outwardly facing portions of the collar may be inwardly facing. The alpha-alumina collar may include a greater coefficient of thermal expansion than each of the outer and inner Ni rings, and the alpha-alumina collar and outer and inner Ni rings may be configured such that a portion of the outer and inner Ni rings is deformed into the inwardly extending recesses of the alpha-alumina collar after active brazing thereof.