公开(公告)号：US3637818A

公开(公告)日：1972-01-25

申请号：US72163268

申请日：1968-04-16

Applicant: HOECHST AG

Inventor： KREKELER HANS ,  FERNHOLZ HANS ,  JACOBSEN GUNTER ,  SODEN BAD

IPC: B01J23/44 ,  C07C45/34 ,  C07C53/08 ,  C07C69/01 ,  C07C69/02 ,  C07C69/15 ,  C07C67/04

CPC classification number: C07C53/08 ,  B01J23/44 ,  C07C45/34 ,  C07C67/055 ,  C07C69/15

Abstract: PREPARATION OF MIXTURES OF ACETALDEHYDE, ACETIC ACID AND VINYL ACETATE BY REACTING ETHYLENE WITH MOLECULAR OXYGEN AT 20 TO 200* C. AND 5 TO 150 ATMOSPHERES IN THE LIQUID PHASE IN THE ABSENCE OF MINERAL ACIDS AND ANIONS OTHER THAN ACETATE IONS AND IN THE PRESENCE OF A GROUP VIII NOBLE METAL, MANGANESE AND/OR COBALT ACETATE, AND WATER.

公开(公告)号：US3651157A

公开(公告)日：1972-03-21

申请号：US3651157D

申请日：1968-10-08

Applicant: HOECHST AG

Inventor： KREKELER HANS ,  MEIDERT HELMUT ,  HORNIG LOTHAR

IPC: C07C17/361 ,  C07C19/041 ,  C07C17/00 ,  C07C17/24

CPC classification number: C07C19/041 ,  C07C17/361

Abstract: PROCESS FOR THE MANUFACTURE OF CARBON TETRACHLORIDE FROM BENZENE OR MIXTURES OF BENZENE AND CHLORINATED ALIPHATIC OR AROMATIC COMPOUNDS, OR CHLORINATED AROMATIC COMPOUNDS AND CHLORINE IN THE ABSENCE OF A CATALYST IN TWO REACTION STAGES AT TEMPERATURES WITHIN THE RANGE OF FROM 6* TO 400*C. IN THE FIRST, AND 400* TO 800*C. IN THE SECOND REACTION STAGE AND PRESSURES WITHIN THE RANGE OF FROM 20 TO 200 ATMOSPHERES GAGE, THE CHLORINE BEING USED IN AN EXCESS AMOUNT OF UP TO 300% AND THE STARTING PRODUCTS BEING INTRODUCED TOGETHER WITH THE CHLORINE ADVANTAGEOUSLY CONTINUOUSLY IN AMOUNTS OF 0.2 TO 4 MOLES PER LITER OF REACTOR VOLUME AND PER HOUR INTO A CORROSIONRESISTANT REACTOR.

公开(公告)号：US3607962A

公开(公告)日：1971-09-21

申请号：US3607962D

申请日：1969-01-28

Applicant: HOECHST AG

Inventor： KREKELER HANS ,  GUNTHER KLAUS ,  SCHMITZ HEINZ

IPC: C07C1/30 ,  C07C11/24

CPC classification number: C07C1/30 ,  C07C11/24 ,  C07C11/22

Abstract: Process for the manufacture of acetylene and its homologs by dehydrohalogenating dihalogen-alkanes or monohalogen-alkenes by means of alkaline earth metal oxides or alkaline earth metal hydroxides.

公开(公告)号：US3928479A

公开(公告)日：1975-12-23

申请号：US474770

申请日：1970-01-21

Applicant: HOECHST AG

Inventor： RIEMENSCHNEIDER WILHELM ,  HORNIG LOTHAR HEINZ ,  HORNIG NEE MUNICH CO-HEIRESS B ,  MEIDERT HELMUT ,  KREKELER HANS

IPC: C07C19/041 ,  C07C17/00 ,  C07C17/361 ,  C07C67/00

CPC classification number: C07C17/361 ,  C07C19/041

Abstract: Process for the continuous manufacture of carbon tetrachloride from benzene or mixtures of benzene with chloro-substituted aromatic or aliphatic hydrocarbons and chlorine wherein the chlorination is first carried out in the liquid phase in a reaction zone containing hexachlorobenzene and then continued in a second reaction zone in the gaseous phase.

Abstract translation: 用于从苯或氯与氯取代的芳族或脂族烃和氯的混合物连续制造四氯化碳的方法，其中氯化首先在含有六氯苯的反应区中在液相中进行，然后在第二反应区中继续 气相。

公开(公告)号：US3676508A

公开(公告)日：1972-07-11

申请号：US3676508D

申请日：1970-01-21

Applicant: HORNIG ANNELIESE ,  HOECHST AG

Inventor： KREKELER HANS ,  MEIDERT HELMUT ,  RIEMENSCHNEIDER WILHELM ,  HORNIG LOTHAR HEINZ

IPC: C07C19/041 ,  C07C17/00 ,  C07C17/361 ,  C07C67/00 ,  C07C19/06

CPC classification number: C07C17/361 ,  C07C19/041

Abstract: In the process for the manufacture of carbon tetrachloride from benzene, mixtures of benzene and chlorinated aliphatic or aromatic compounds, or chlorinated aromatic compounds, with chlorine in an excess amount of up to 300 percent, in the absence of catalysts in the gaseous phase in two reaction stages at a temperature in the first stage of from 6* to 400* C. and in the second stage of from 400* to 800* C. the space-time-yield is considerably increased by operating in both reaction stages under a pressure in the range of from 200 to 700 atmospheres. The reaction is carried out in a corrosion resistant reactor in continuous manner using 0.2 to 4 moles of organic compound or compounds per liter of reaction space per second.

Abstract translation: 在从苯中制造四氯化碳的过程中，苯和氯化脂族或芳族化合物或氯化芳族化合物的混合物，氯过量高达300％，在气相中不存在催化剂的情况下 在第一阶段的温度为6℃至400℃，第二阶段为400℃至800℃的反应阶段，通过在压力下在两个反应阶段中操作来显着提高空时收率 在200至700个大气压的范围内。 反应在耐腐蚀反应器中以连续的方式使用0.2至4摩尔有机化合物或化合物/升每秒反应空间进行。