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1.发明授权
公开(公告)号：US6156830A
公开(公告)日：2000-12-05
申请号：US323778
申请日：1999-06-01
IPC分类号： C08K5/15 , C07D239/54 , C07D239/545 , C07D239/557 , C08K5/3462 , C08K5/34 , C07D239/02
CPC分类号： C07D239/545 , C07D239/557 , C08K5/3462
摘要： A description is given of compounds of the general formula I ##STR1## n is 1 or 2, Y is oxygen or sulfur andR.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in claim 1which are suitable for stabilizing chlorine-containing polymers, especially PVC.
摘要翻译： 给出通式I n为1或2的化合物，Y为氧或硫，R 1，R 2，R 3和R 4如权利要求1中所定义，其适于稳定含氯聚合物，特别是PVC。
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公开(公告)号：US07671118B2
公开(公告)日：2010-03-02
申请号：US11391836
申请日：2006-03-28
IPC分类号： C08K5/3415 , C08G73/20 , C08G73/06 , C01B11/18
摘要： A stabilizer system for stabilizing halogen-containing polymers comprising a perchlorate salt and at least one indole compound, a composition comprising such a stabilizer system, process for stabilizing a chlorine-containing polymer using such a stabilizer system, and an article manufacture comprising PVC stabilized by such a stabilizer system.
摘要翻译： 用于稳定包含高氯酸盐和至少一种吲哚化合物的含卤聚合物的稳定剂体系，包含这种稳定剂体系的组合物，使用这种稳定剂体系稳定含氯聚合物的方法，以及包含由 这样的稳定系统。
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公开(公告)号：US07358286B2
公开(公告)日：2008-04-15
申请号：US10542562
申请日：2003-12-20
IPC分类号： C08K5/34
摘要： Disclosed are stabilizer mixtures comprising at least a) one alkanolamine or one reaction product of a monofunctional or polyfunctional epoxide and ammonia or a monofunctional or polyfunctional dialkyl(aryl)amine or monoalkyl(aryl)amine, and b) one uracil or one initial product and an optional perchlorate salt.
摘要翻译： 公开了稳定剂混合物，其包含至少一种链烷醇胺或单官能或多官能环氧化物与氨或单官能或多官能二烷基（芳基）胺或单烷基（芳基）胺的一种反应产物，和b）一种尿嘧啶或一种初始产物和 一种可选的高氯酸盐。
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公开(公告)号：US20060235124A1
公开(公告)日：2006-10-19
申请号：US10555021
申请日：2004-04-02
IPC分类号： C08K5/36
摘要： The invention relates to a mixture of stabilisers for the stabilisation of chlorinated polymers, comprising at least a) a sulphate ester salt and/or a sulphonate salt of formula (I): [R(O)aSO3]1M and b) an alkanolamine of formula (II), where M=alkali, earth alkali, lanthanide (Cer) or aluminium cation, t=metal cation valence of 1, 2 or 3; s=0 or 1, R=C1-C22 a phenyl, C7-C10 phenylalkyl, C7 -C24 alkylphenyl, x=1, 2 or 3: y=1, 2, 3, 4, 5 or 6; n=1-10. R1, R2 independently=H. C1-C22 alkyl, —[—(CHR3a)y—CHR3b—O—]a—H, —[—(CHR3a)y—CHR3b—O-]n-CO—R4, C2-C20 alkenyl, C2-C18 acyl, C4-C8 cycloalkyl, optionally substituted at the B-position by OH, C6-C10 aryl, C7-C10 alkaryl or C7-C10 aralkyl, or when x=1, R1 and R2 together with the N can form a closed 4-10 membered ring of carbon atoms with optionally up to 2 heteroatoms, or when x=2, R1 also=C2-C18 alkylene, optionally substituted at both B-carbon atoms with OH and/or interrupted by 1 or more O atoms and/or 1 or more NR2 groups, or dihydroxysubstituted tetrahydrodicyclopentadienylene, dihydroxysubstituted ethylcyclohexanylene, dihydroyxsubstituted 4,4′-bisphenol-A-dipropylether)ylene, isophoronylene, dimethylcyclohexanylene, dicyclohoxylmethanylene or 3,3′-dimethyldicyclohexylmethanylene and when x=3, R1 also=trihydroxysubstituted (tri-N-propylisocyanurate)triyl, R3a, R3b independently=C1-C22 alkyl, C2-C6 alkenyl) C6-C10 aryl, H or CH2—X—R5, where X═O, S, —O—CO— or —CO—O—; R4═C1-C18 alkyl/alkenyl or phenyl and R5═H, C1-C22 alkyl, C2-C22 alkenyl or C6-C10 aryl.
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公开(公告)号：US06211270B1
公开(公告)日：2001-04-03
申请号：US09323975
申请日：1999-06-02
IPC分类号： C08K521
摘要： A description is given of compositions comprising a chlorine-containing polymer and at least one compound of the general formula I where x is oxygen or sulfur, and R is C2-C22-acyloxyalkyl or C1-C12-alkyl which may be interrupted by 1 to 3 oxygen atoms and/or substituted by 1 to 3 OH groups, or is C3-C8-alkenyl, C7-C10-phenylalkyl, C5-C8-cycloalkyl, C7-C10-alkylphenyl, phenyl or naphthyl, where the aromatic radical in each case may be substituted by —OH, C1-C12-alkyl and/or OC1-C4-alkyl, and R1 is hydrogen or is as defined for R.
摘要翻译： 给出了包含含氯聚合物和至少一种通式I的化合物的组合物的描述，其中x是氧或硫，R是可被1至3个氧原子间隔的C 2 -C 22 - 酰氧基烷基或C 1 -C 12 - 烷基 或/或被1至3个OH基取代，或为C 3 -C 8 - 烯基，C 7 -C 10 - 苯基烷基，C 5 -C 8 - 环烷基，C 7 -C 10 - 烷基苯基，苯基或萘基，其中每种情况下的芳族基团可以是 被-OH，C 1 -C 12烷基和/或OC 1 -C 4烷基取代，R 1是氢或根据R定义。
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公开(公告)号：US06194494B1
公开(公告)日：2001-02-27
申请号：US09107848
申请日：1998-06-30
申请人： Wolfgang Wehner , Hans-Helmut Friedrich , Kornelia Malzacher , Hans-Ludwig Mehner , Rolf Drewes
发明人： Wolfgang Wehner , Hans-Helmut Friedrich , Kornelia Malzacher , Hans-Ludwig Mehner , Rolf Drewes
IPC分类号： C08K534
CPC分类号： C08K5/1515 , C08K3/014 , C08K3/34 , C08K5/005 , C08K5/3462 , C08K5/39 , C08L27/06 , C08L11/00 , C08L57/08
摘要： A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsonites), B10) alkali- (or alkaline earth-) carboxylates,-(bi)carbonates or -hydroxides, B11) antioxidants and lubricants and B12) organotin stabilisers.
摘要翻译： 描述了主要用于PVC的稳定剂组合物，其包含A）至少一种式I化合物，其中R * 1和R * 2各自独立地为未取代或取代的其它C 1 -C 12烷基，C 3 -C 6烯基，C 5 -C 8环烷基 C1-C4烷基，C1-C4烷氧基，C5-C8环烷基或羟基或氯原子，或未被取代或在苯环被1至3个C 1 -C 4烷基取代的C 7 -C 9苯基烷基，C 1 -C 4烷氧基 ，C 5 -C 8环烷基或羟基或氯原子，R * 1和R * 2可以另外是氢和C 1 -C 12烷基，Y是S或O，和B）至少一种下列化合物：B1）高氯酸盐化合物 ，B2）缩水甘油基化合物，B3）β-二酮和β-酮酯，B4）二氢吡啶和聚二氢吡啶，B5）多元醇和二糖醇，B6）空间位阻胺（四烷基哌啶化合物），B7）碱铝硅酸盐（沸石），B8） 水滑石，B9）碱金属铝酸盐（片钠铝石），B10）碱 - （或碱） （b）抗氧化剂和润滑剂和B12）有机锡稳定剂。
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公开(公告)号：US20090170988A1
公开(公告)日：2009-07-02
申请号：US12397137
申请日：2009-03-03
摘要： A stabilizer system for stabilizing halogen-containing polymers against thermal degradation, the stabilizer system comprising: (a) at least one perfluoroalkanesulphonate salt; and (b) at least one alkanolamine wherein the at least one alkanolamine has the general formula (I)
摘要翻译： 一种用于稳定含卤聚合物以防止热降解的稳定剂体系，所述稳定剂体系包含：（a）至少一种全氟烷基磺酸盐; 和（b）至少一种链烷醇胺，其中所述至少一种链烷醇胺具有通式（I）
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公开(公告)号：US20060192179A1
公开(公告)日：2006-08-31
申请号：US11391836
申请日：2006-03-28
IPC分类号： C09K15/32
摘要： A stabilizer system for stabilizing halogen-containing polymers comprising a perchlorate salt and at least one indole compound, a composition comprising such a stabilizer system, process for stabilizing a chlorine-containing polymer using such a stabilizer system, and an article manufacture comprising PVC stabilized by such a stabilizer system.
摘要翻译： 用于稳定包含高氯酸盐和至少一种吲哚化合物的含卤聚合物的稳定剂体系，包含这种稳定剂体系的组合物，使用这种稳定剂体系稳定含氯聚合物的方法，以及包含由 这样的稳定系统。
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9.发明授权Chlorate-containing stabilizer system with nitrogen-containing synergists for stabilizing halogen-containing polymers 失效含有氯酸盐的稳定剂体系，含有用于稳定含卤聚合物的含氮增效剂公开(公告)号：US07077981B2
公开(公告)日：2006-07-18
申请号：US10467947
申请日：2001-12-12
IPC分类号： C08K13/02
摘要： The invention relates to stabilizer systems, containing at least: a) a perchlorate salt; b) at least one or more compounds from the group consisting of carbamides, indole derivatives and enamines of formula (I), wherein n=1 or 2 and X=O or NR1; n=3–6 and X=O; R1=H, C1–C4-alkyl, C2–C6-alkenyl, C6–C10-aryl, C7–C18-alkaryl or C7–C18-aralkyl; R2 (if n=1)=C1–C22-alkyl, C2–C22-alkenyl or aryl, preferably phenyl, optionally substituted with up to 3 hydroxy, C1–C4-alkoxy or C1–C9-alkyl; or R2 (if n=2–6)=linear or branched C1-22-alkylene, optionally interrupted by one or more O or S atoms, wherein R2 (if n=3) can also be a C2–C3-alkyl trisubstituted isocyanurate; if X=NH R2 can also be H. Said stabilizer systems are suitable for stabilizing halogen-containing polymers, more particularly PVC.
摘要翻译： 本发明涉及稳定剂体系，其至少包含：a）高氯酸盐; b）至少一种或多种由式（I）的氨基甲酰胺，吲哚衍生物和烯胺组成的组，其中n = 1或2，X = O或NR 1; n = 3-6，X = O; R 1 = H，C 1 -C 4 - 烷基，C 2 -C 6 - 烷基，C 1 -C 4烷基，C 1 -C 4烷基， 亚烷基，C 6 -C 10 - 芳基，C 7 -C 18 - 烷芳基或C 1 -C 6 - C 7 -C 18 - 芳烷基; R 2（如果n = 1）= C 1 -C 22 - 烷基，C 2 -C 任选被至多3个羟基，C 1 -C 4 - 烷氧基或C 1 -C 6烷基取代的亚烷基或芳基，优选苯基 -C 9 - 烷基; 或R 2（如果n = 2-6）=直链或支链C 1-22 - 亚烷基，任选地被一个或多个O或S原子间隔，其中R' （如果n = 3）也可以是C 2 -C 3 - 烷基三取代的异氰脲酸酯; 如果X = NHR 2也可以是H.所述稳定剂体系适用于稳定含卤聚合物，更特别是PVC。
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10.发明授权公开(公告)号：US06274654B1
公开(公告)日：2001-08-14
申请号：US09338172
申请日：1999-06-22
IPC分类号： C08K534
CPC分类号： C08K5/3462 , C08L57/08
摘要： A description is given of compositions comprising a chlorine-containing polymer and at least one compound of the general formula I where Y is S or O, and R1 and R2 independently of one another are unsubstituted or C1-C4-alkyl-, C1-C4-alkoxy- and/or hydroxyl-substituted phenyl, phenyl-C1-C4-alkyl which is unsubstituted or substituted on the phenyl ring by C1-C4-alkyl, C1-C5-alkoxy and/or hydroxyl, or are C3-C6-alkenyl, C5-C8-cycloalkyl, or C2-C10-alkyl interrupted by at least 1 oxygen atom, or, if R1 and R2 are different from one another, one of the two radicals can be C2-C12-alkyl and the other can be C2-C12-alkyl or one of the above radicals, or, if R1 and R2 are identical, both can also be C5-C12-alkyl, and, if Y is sulfur, R1 and R2 cannot be octyl.
摘要翻译： 描述了包含含氯聚合物和至少一种通式I的化合物的组合物，其中Y是S或O，R 1和R 2彼此独立地是未取代的或C 1 -C 4烷基 - ，C 1 -C 4 - 烷氧基 - 和/或羟基取代的苯基，未被取代或在苯环上被C1-C4-烷基，C1-C5-烷氧基和/或羟基取代的苯基-C1-C4-烷基，或为C3-C6-烯基， C 5 -C 8 - 环烷基或被至少1个氧原子间断的C 2 -C 10烷基，或者如果R 1和R 2彼此不同，则两个基团之一可以是C 2 -C 12烷基，另一个可以是C 2 -C 12 - 烷基或上述基团之一，或者如果R 1和R 2相同，则两者也可以是C 5 -C 12 - 烷基，如果Y是硫，则R 1和R 2不能是辛基。
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