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公开(公告)号：US20080193793A1
公开(公告)日：2008-08-14
申请号：US11722599
申请日：2004-12-23
IPC分类号： H01L51/30 , C07C255/42 , C07C211/54
CPC分类号： H01L51/002 , C07C255/42 , H01L51/0051 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0097 , H01L51/0545 , Y02E10/549
摘要： The present invention relates to materials useful as an electron or hole transport or injection layer in organic electrooptic devices. The material can form or be part of an electrically conductive organic layer, suitable for the transport of so-called positive charges or holes. The inventive HTL compounds are intrinsically doped HTLs which allows their deposition with greater homogeneity and reproducibility than matrix compositions consisting of a matrix material and an admixed p-dopant.
摘要翻译： 本发明涉及用作有机电光装置中的电子或空穴传输或注入层的材料。 该材料可以形成或成为导电有机层的一部分，适于运输所谓的正电荷或空穴。 本发明的HTL化合物是固有掺杂的HTL，其允许它们与由基质材料和掺杂的p掺杂物组成的基质组合物具有更大的均匀性和再现性。
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公开(公告)号：US10385263B2
公开(公告)日：2019-08-20
申请号：US12296112
申请日：2007-04-03
申请人： Evelyn Fuchs , Martina Egen , Klaus Kahle , Christian Lennartz , Oliver Molt , Simon Nord , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Evelyn Fuchs , Martina Egen , Klaus Kahle , Christian Lennartz , Oliver Molt , Simon Nord , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
摘要： The present invention relates to heteroleptic carbene complexes comprising at least two different carbene ligands, to a process for preparing the heteroleptic carbene complexes, to the use of the heteroleptic carbene complexes in organic light-emitting diodes, to organic light-emitting diodes comprising at least one inventive heteroleptic carbene complex, to a light-emitting layer comprising at least one inventive heteroleptic carbene complex, to organic light-emitting diodes comprising at least one inventive light-emitting layer, and to devices which comprise at least one inventive organic light-emitting diode.
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公开(公告)号：US09748498B2
公开(公告)日：2017-08-29
申请号：US12901610
申请日：2010-10-11
申请人： Markus Bold , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Baete , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Markus Bold , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Baete , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
CPC分类号： H01L51/0085 , B01J31/2265 , B01J31/2273 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/57 , B01J2531/60 , B01J2531/70 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07F15/0033 , C09B57/00 , C09B57/10 , C09K11/06 , C09K2211/1007 , C09K2211/1018 , C09K2211/1044 , C09K2211/1059 , C09K2211/18 , C09K2211/185 , H01L51/0081 , H01L51/5016 , H01L51/5096 , Y02P20/582
摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
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公开(公告)号：US08278238B2
公开(公告)日：2012-10-02
申请号：US12066144
申请日：2006-09-07
申请人： Hans-Hermann Johannes , Wolfgang Kowalsky , Sven Ammermann , Michael Kroener , Ute Jana Weinaug
发明人： Hans-Hermann Johannes , Wolfgang Kowalsky , Sven Ammermann , Michael Kroener , Ute Jana Weinaug
CPC分类号： C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/104 , C09K2211/1044 , C09K2211/1051 , C09K2211/1059 , C09K2211/185 , H05B33/14 , Y10T428/31678
摘要： The present invention relates to light emitting compounds, especially to triplett emitters suitable for electrooptical applications. Compounds according to the invention are organometallic complexes of a metal, preferably Ir, having a backbone of one five-membered ring that is linked to a five- or six-membered ring, by an intermediate six-membered ring. These compounds are suitable for adaptation to the emission of light in the UV to NIR range by adaptation of atoms or groups within at least one of the five-membered or six-membered ring structures.
摘要翻译： 本发明涉及发光化合物，特别涉及适用于电光应用的三重发射体。 根据本发明的化合物是具有通过中间六元环连接至五元或六元环的五元环的主链的金属，优选Ir的有机金属络合物。 这些化合物适用于通过适应五元或六元环结构中的至少一个中的原子或基团来适应UV到NIR范围内的光的发射。
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公开(公告)号：US20110049501A1
公开(公告)日：2011-03-03
申请号：US12905112
申请日：2010-10-15
申请人： Markus BOLD , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Bäte , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Markus BOLD , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Bäte , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
CPC分类号： H01L51/0085 , B01J31/2265 , B01J31/2273 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/57 , B01J2531/60 , B01J2531/70 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07F15/0033 , C09B57/00 , C09B57/10 , C09K11/06 , C09K2211/1007 , C09K2211/1018 , C09K2211/1044 , C09K2211/1059 , C09K2211/18 , C09K2211/185 , H01L51/0081 , H01L51/5016 , H01L51/5096 , Y02P20/582
摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
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6.发明申请TRANSITION METAL COMPLEXES COMPRISING CARBENE LIGANDS SERVING AS EMITTERS FOR ORGANIC LIGHT-EMITTING DIODES (OLED'S) 有权包含作为有机发光二极管发光体的碳配体的过渡金属复合物（OLED）公开(公告)号：US20110049499A1
公开(公告)日：2011-03-03
申请号：US12901610
申请日：2010-10-11
申请人： Markus BOLD , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Bäte , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Markus BOLD , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Bäte , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
CPC分类号： H01L51/0085 , B01J31/2265 , B01J31/2273 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/57 , B01J2531/60 , B01J2531/70 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07F15/0033 , C09B57/00 , C09B57/10 , C09K11/06 , C09K2211/1007 , C09K2211/1018 , C09K2211/1044 , C09K2211/1059 , C09K2211/18 , C09K2211/185 , H01L51/0081 , H01L51/5016 , H01L51/5096 , Y02P20/582
摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
摘要翻译： 在有机发光二极管中使用式（I）的过渡金属配合物，其中：M1是金属原子; 卡宾是卡宾配体; L是单阴离子或双阴离子配体; K是选自磷化氢的不带电荷的单齿或双齿配体; CO; 吡啶 腈和共轭二烯，形成＆pgr; 与M1复合; n是卡宾配体的数目，至少为1; m是配体L的数目，其中m可以是0或≥1; o是配体K的数目，其中o可以是0或≥1; 其中总和n + m + o取决于金属原子的氧化态和配位数以及配体卡宾，L和K的配位数，以及配体卡宾和L上的电荷，条件是n 包含这些过渡金属络合物的OLED，包含这些过渡金属络合物的发光层，包含该发光层的OLED，包含根据本发明的OLED的器件和特定的过渡金属络合物，其包含 至少两个卡宾配体。
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公开(公告)号：US20090165846A1
公开(公告)日：2009-07-02
申请号：US12066144
申请日：2006-09-07
申请人： Hans-Hermann Johannes , Wolfgang Kowalsky , Sven Ammermann , Michael Kroener , Ute Jana Weinaug
发明人： Hans-Hermann Johannes , Wolfgang Kowalsky , Sven Ammermann , Michael Kroener , Ute Jana Weinaug
CPC分类号： C07F15/0033 , C09K11/06 , C09K2211/1029 , C09K2211/1037 , C09K2211/104 , C09K2211/1044 , C09K2211/1051 , C09K2211/1059 , C09K2211/185 , H05B33/14 , Y10T428/31678
摘要： The present invention relates to light emitting compounds, especially to triplett emitters suitable for electrooptical applications. Compounds according to the invention are organometallic complexes of a metal, preferably Ir, having a backbone of one five-membered ring that is linked to a five- or six-membered ring, by an intermediate six-membered ring. These compounds are suitable for adaptation to the emission of light in the UV to NIR range by adaptation of atoms or groups within at least one of the five-membered or six-membered ring structures.
摘要翻译： 本发明涉及发光化合物，特别涉及适用于电光应用的三重发射体。 根据本发明的化合物是具有通过中间六元环连接至五元或六元环的五元环的主链的金属，优选Ir的有机金属络合物。 这些化合物适用于通过适应五元或六元环结构中的至少一个中的原子或基团来适应UV到NIR范围内的光的发射。
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8.发明申请HETEROLEPTIC TRANSITION METAL-CARBENE COMPLEXES AND THEIR USE IN ORGANIC LIGHT-EMITTING DIODES (OLEDS) 审中-公开异质过渡金属碳复合物及其在有机发光二极管（OLEDs）中的应用公开(公告)号：US20090096367A1
公开(公告)日：2009-04-16
申请号：US12296112
申请日：2007-04-03
申请人： Evelyn Fuchs , Martina Egen , Klaus Kahle , Christian Lennartz , Oliver Molt , Simon Nord , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Evelyn Fuchs , Martina Egen , Klaus Kahle , Christian Lennartz , Oliver Molt , Simon Nord , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1007 , C09K2211/1044 , C09K2211/1059 , C09K2211/185 , H01L51/005 , H01L51/0059 , H01L51/0085 , H01L51/5012 , H01L51/5016 , H05B33/14
摘要： The present invention relates to heteroleptic carbene complexes comprising at least two different carbene ligands, to a process for preparing the heteroleptic carbene complexes, to the use of the heteroleptic carbene complexes in organic light-emitting diodes, to organic light-emitting diodes comprising at least one inventive heteroleptic carbene complex, to a light-emitting layer comprising at least one inventive heteroleptic carbene complex, to organic light-emitting diodes comprising at least one inventive light-emitting layer, and to devices which comprise at least one inventive organic light-emitting diode.
摘要翻译： 本发明涉及包含至少两种不同卡宾配位体的异吲哚卡宾络合物，涉及制备异吲哚卡宾配合物的方法，将有机发光二极管中的异亮氨酸配合物用于有机发光二极管，至少包括 一种本发明的异吲哚卡宾复合物，至少包含至少一种本发明的杂光卡宾复合物的发光层，至少包括至少一个本发明的发光层的有机发光二极管，以及包含至少一种本发明的有机发光 二极管。
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9.发明授权Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's) 有权包含用作有机发光二极管（OLED）的发射体的卡宾配体的过渡金属络合物公开(公告)号：US08916853B2
公开(公告)日：2014-12-23
申请号：US12905112
申请日：2010-10-15
申请人： Markus Bold , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Baete , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Markus Bold , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Baete , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
IPC分类号： H01L51/54 , C07F15/00 , C09K11/06 , C09B57/00 , C09B57/10 , H01L51/50 , B01J31/22 , H01L51/00
CPC分类号： H01L51/0085 , B01J31/2265 , B01J31/2273 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/57 , B01J2531/60 , B01J2531/70 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07F15/0033 , C09B57/00 , C09B57/10 , C09K11/06 , C09K2211/1007 , C09K2211/1018 , C09K2211/1044 , C09K2211/1059 , C09K2211/18 , C09K2211/185 , H01L51/0081 , H01L51/5016 , H01L51/5096 , Y02P20/582
摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
摘要翻译： 在有机发光二极管中使用式（I）的过渡金属配合物，其中：M1是金属原子; 卡宾是卡宾配体; L是单阴离子或双阴离子配体; K是选自磷化氢的不带电荷的单齿或双齿配体; CO; 吡啶 腈和共轭二烯，形成＆pgr; 与M1复合; n是卡宾配体的数目，至少为1; m是配体L的数目，其中m可以是0或≥1; o是配体K的数目，其中o可以是0或≥1; 其中总和n + m + o取决于金属原子的氧化态和配位数以及配体卡宾，L和K的配位数，以及配体卡宾和L上的电荷，条件是n 包含这些过渡金属络合物的OLED，包含这些过渡金属络合物的发光层，包含该发光层的OLED，包含根据本发明的OLED的器件和特定的过渡金属络合物，其包含 至少两个卡宾配体。
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10.发明授权Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's) 有权包含用作有机发光二极管（OLED）的发射体的卡宾配体的过渡金属络合物公开(公告)号：US08377740B2
公开(公告)日：2013-02-19
申请号：US12904290
申请日：2010-10-14
申请人： Markus Bold , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Baete , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
发明人： Markus Bold , Christian Lennartz , Martina Prinz , Hans-Werner Schmidt , Mukundan Thelakkat , Markus Baete , Christian Neuber , Wolfgang Kowalsky , Christian Schildknecht , Hans-Hermann Johannes
CPC分类号： H01L51/0085 , B01J31/2265 , B01J31/2273 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/57 , B01J2531/60 , B01J2531/70 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07F15/0033 , C09B57/00 , C09B57/10 , C09K11/06 , C09K2211/1007 , C09K2211/1018 , C09K2211/1044 , C09K2211/1059 , C09K2211/18 , C09K2211/185 , H01L51/0081 , H01L51/5016 , H01L51/5096 , Y02P20/582
摘要： Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
摘要翻译： 在有机发光二极管中使用式（I）的过渡金属配合物，其中：M1是金属原子; 卡宾是卡宾配体; L是单阴离子或双阴离子配体; K是选自磷化氢的不带电荷的单齿或双齿配体; CO; 吡啶 腈和共轭二烯，形成＆pgr; 与M1复合; n是卡宾配体的数目，至少为1; m是配体L的数目，其中m可以是0或≥1; o是配体K的数目，其中o可以是0或≥1; 其中总和n + m + o取决于金属原子的氧化态和配位数以及配体卡宾，L和K的配位数，以及配体卡宾和L上的电荷，条件是n 包含这些过渡金属络合物的OLED，包含这些过渡金属络合物的发光层，包含该发光层的OLED，包含根据本发明的OLED的器件和特定的过渡金属络合物，其包含 至少两个卡宾配体。
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