摘要:
A pitch-based carbon or graphite fiber having a leafy lamella arrangement in at least 30% of the fiber cross-sectional area and having a tensile strength of at least 300 kg/mm.sup.2. The fiber is prepared by melt-spinning an optically anisotropic pitch having an optically anisotropic phase content of at least 50% through a spinneret in which at least one central line distance in a spinning hole simultaneously satisfies the following requirements I and II,Ln
摘要翻译:纤维横截面积至少为30%的具有叶状薄片布置并具有至少300kg / mm2的拉伸强度的沥青基碳或石墨纤维。 通过纺丝孔中的至少一个中心线距离同时满足以下要求I和II的喷丝头熔融纺丝具有至少50%的光学各向异性相含量的光学各向异性沥青,Ln <10 I 1.5其中Ln表示纺丝孔中的中心线距离(mm),Wn表示纺丝孔中的湿润周长(mm),并且使形成的沥青纤维不熔化和碳化。
摘要:
A wholly aromatic polyamide fiber non-woven sheet having satisfactory density, impregnating property, heat resistance, and surface evenness, comprises mutually, randomly entangled fibers consisting essentially of a wholly aromatic polyamide having 85 molar % or more of at least one type of recurring units selected from those of the formulae (I) and (II): ##STR1## The non-woven sheet is characterized in that the wholly aromatic polyamide fibers have portions thereof having a flattened cross-sectional profile; the aromatic polyamide fibers are fuse-bonded to each other at least at portions thereof intersecting each other; and the sheet includes pores connected to each other, and having a size at the peak of pore size distribution, of 13 microns or less determined by means of a mercury porosimeter, and no voids isolated from each other, and has a porosity of from 5% to 40% and an air permeability rate of from 0.1 to 10,000 sec/100 ml.
摘要:
The invention provides carbon fibers having mechanical properties equival to or even better than those of the polyacrylonitrile-based carbon fibers from a bituminous material, e.g. coal tar pitch, as the starting material. The starting pitch is first partially hydrogenated in tetrahydroquinoline under specific conditions followed by a heat treatment to give a pitch composition suitable for spinning which can be characterized by several parameters including the proportions of the carbons and hydrogens having different chemical shifts in the NMR analysis. The pitch composition for spinning is then subjected to spinning under specific conditions including the temperature condition for controlling the viscosity behavior of the molten pitch composition determined by use of the Andrade's equation and the pitch filament is then infusibilized in an oxidative atmosphere and carbonized in an inert atmosphere into carbon fibers having a tensile strength of at least 200 kg/mm.sup.2 and a tensile modulus of at least 10 tons/mm.sup.2.
摘要翻译:本发明提供具有与来自沥青材料的聚丙烯腈基碳纤维相当或甚至更好的机械性能的碳纤维,例如沥青。 煤焦油沥青,作为原料。 起始沥青在特定条件下首先在四氢喹啉中部分氢化,接着进行热处理,得到适用于纺丝的沥青组合物,其可以通过几个参数来表征,包括在NMR分析中具有不同化学位移的碳和氢的比例。 然后将纺丝沥青组合物在特定条件下进行纺丝,包括用于通过使用安德拉德方程确定的用于控制熔融沥青组合物的粘度行为的温度条件,然后将沥青丝在氧化气氛中不熔化并以惰性碳化 气氛变成具有至少200kg / mm 2的拉伸强度和至少10吨/ mm 2的拉伸模量的碳纤维。
摘要:
High modulus shaped articles such as fibers and films, composed of a wholly aromatic copolyamide, are provided. The wholly aromatic copolyamide is comprised of recurring units of the formulae:--NH--AR.sub.1 --NH--CO--Ar.sub.2 --CO-- (A)and--NH--Ar.sub.3 --CO-- (B)wherein Ar.sub.1, Ar.sub.2 and Ar.sub.3 independently stand for divalent groups selected from ##STR1## in which X's independently stand for a group selected from halogeno, alkyl, aralkyl, aromatic, alkoxy, acetyl and cyano, n is 1 to 3 and Y is selected from ##STR2## in which R' stands for an 1-5C alkyl group, and the copolymerization ratio expressed by the molar ratio of the total of Ar.sub.1, Ar.sub.2 and Ar.sub.3 fails within the square hatched region in a triangular coordinate of FIG. 1, and said copolyamide has an intrinsic viscosity of at least 1.5. The shaped articles are prepared by a process wherein a solution comprised of the above-defined wholly aromatic copolyamide, a halide of a metal of Group I or II of the Periodic Table and an amide type organic solvent is subjected to wet or dry shaping; and then, the shaped article is stretched at a stretch ratio of at least 1.5 at an elevated temperature.
摘要:
A method of manufacture of pitch-based carbon fiber by infusibilization of pitch fiber followed by carbonization, comprising doping the pitch fiber with at least 0.05 percent by weight of iodine, heating under an oxidizing atmosphere for infusibilization, and then heating under an inert atmosphere for carbonization, whereby it is carbonized or graphitized.
摘要:
A process for the preparation of high-performance grade carbon fibers, which comprises attaching a fine powder of at least one member selected from oxides and carbides of silicon, aluminum, titanium, and boron to a precursor fiber bundle of as spun pitch fibers, subjecting the fiber bundle to an infusibilization treatment, and subjecting the fiber bundle to a carbonization treatment.
摘要:
A process for manufacturing a carbon fiber having a fiber diameter of 0.001 to 5 μm and a narrow fiber size distribution, and a resin composition suitable for the manufacture of a carbon fiber. A resin composition comprising 100 parts by weight of a thermoplastic resin, 1 to 150 parts by weight of a carbon precursor organic compound (A) and 0.001 to 40 parts by weight of acopolymer of polymer segments (e1) and (e2) which satisfy a specific range of surface tension for the thermoplastic resin and a specific range of surface tension for the carbon precursor organic compound (A) at the same time. A process for manufacturing a carbon fiber, comprising the steps of producing a molded article of a precursor fiber (B) by treating the resin composition, subjecting the carbon precursor organic compound (A) contained in the precursor fiber (B) to a stabilization treatment so as to produce a stabilized precursor fiber (C), removing the thermoplastic resin contained in the stabilized precursor fiber (C), and carbonizing or graphitizing a fibrous carbon precursor (D) obtained by removing the thermoplastic resin.
摘要:
An aromatic polycarbonate composition which contains 0.05 to 65 ppm of bonded phosphorus atoms to polycarbonate chains and free phosphorus compounds consisting of a tervalent phosphorus compound and a pentavalent phosphorus compound in a specific ratio. It is excellent in transparency, color stability and residence stability at the time of molding and is suitably used in disk substrates.
摘要:
A carbon fiber having a total content of Li, Na, Ti, Mn, Fe, Ni and Co metal elements of no more than 50 ppm and a fiber diameter of 0.001 to 2 μm and not branched and a assembly of a plurality of the carbon fibers.
摘要:
Disclosed is a fibrous activated carbon wherein fine pores in the surface of the activated carbon have diameters of 0.1-200 nm and the activated carbon is in the form of fiber having a fiber diameter of not more than 1000 nm.