公开(公告)号：US5196531A

公开(公告)日：1993-03-23

申请号：US929496

申请日：1992-08-18

申请人： Hiroyuki Umetani ,  Hiroshi Mera ,  Hiroo Inata ,  Shunichi Matsumura

发明人： Hiroyuki Umetani ,  Hiroshi Mera ,  Hiroo Inata ,  Shunichi Matsumura

IPC分类号： C07D263/28 ,  C07D265/08 ,  C08G59/50

CPC分类号： C07D265/08 ,  C07D263/28 ,  C08G59/5046

摘要： A novel poly(N-cyclic iminoether) compound and a process for production thereof which comprises (a) reacting a polyisocyanate compound with a haloalkyleneamine or (b) reacting a polyamine with an alkyl isocyanate, and then (c) cyclizing the resulting polyurea compound. Several thermosetting compositions containing the novel poly(N-cyclic iminoether) and thermoset resins therefrom are also proposed.

摘要翻译： 一种新型聚（N-环亚氨基醚）化合物及其制备方法，其包括（a）使多异氰酸酯化合物与卤代亚烷基胺反应或（b）使多胺与异氰酸烷基酯反应，然后（c）使得到的聚脲化合物 。 还提出了几种含有新型聚（N-环亚氨基醚）和热固性树脂的热固性组合物。

公开(公告)号：US4749753A

公开(公告)日：1988-06-07

申请号：US880828

申请日：1986-07-01

申请人： Toshio Nishihara ,  Hiroshi Mera ,  Zenichiro Endo

发明人： Toshio Nishihara ,  Hiroshi Mera ,  Zenichiro Endo

IPC分类号： C08L77/10 ,  C08L77/00

CPC分类号： C08L77/10 ,  B01F13/0059

摘要： An intimate mixture comprising (A) a substantially linear aromatic polyazole and (B) a sparingly crystallizable aromatic copolyamide having a glass transition temperature of at least 200.degree. C. and a flow initiation temperature of not more than 500.degree. C. in such proportions represented by A/(A+B)=0.15-0.70 by weight, and a process for producing the intimate mixture, which comprises dissolving the aromatic polyazole (A) and the aromatic copolyamide (B) in a weight ratio represented by A/(A+B)=0.15-0.70 in a common solvent, and forming an intimate mixture of the aromatic polyazole (A) and the aromatic copolyamide (B) from the solution using a coagulating agent.

摘要翻译： 一种紧密混合物，其包含（A）基本上线性的芳族聚唑和（B）具有至少200℃的玻璃化转变温度和不高于500℃的流动起始温度的可微结晶的芳族共聚酰胺， 通过A /（A + B）= 0.15-0.70重量比，以及制备密实混合物的方法，其包括以A /（A（A））表示的重量比溶解芳族聚唑（A）和芳族共聚酰胺（B） + B）= 0.15-0.70，并使用凝结剂从溶液中形成芳族聚唑（A）和芳族共聚酰胺（B）的紧密混合物。

公开(公告)号：US4018735A

公开(公告)日：1977-04-19

申请号：US594130

申请日：1975-07-08

申请人： Yasuo Nakagawa ,  Takashi Noma ,  Hiroshi Mera

发明人： Yasuo Nakagawa ,  Takashi Noma ,  Hiroshi Mera

IPC分类号： C08L77/00 ,  C08G69/12 ,  C08G69/32 ,  C08J3/02 ,  C08L79/00 ,  C08L79/04 ,  D01F6/80 ,  C08K3/16 ,  C08K5/20 ,  C08K5/21 ,  C08K5/36

CPC分类号： C08G69/12 ,  C08G69/32

摘要： An anisotropic aromatic polyamide dope comprising more than 10% by weight of an aromatic polyamide and a solvent for the polyamide, said polyamide consisting essentially of, at least 5 mole% but less than 35 moles%, based on its entire units, of an only partially p-oriented structural unit expressed by the following formula ##STR1## wherein Ar.sup.1 is a divalent aromatic ring whose chain-extending bonds are coaxial or parallel, X is a member selected from the group consisting of O, S and NH, and the NH group bonded to the benzene ring of the above benzoxazole, benzothiazole or benzimidazole ring is meta or para to the carbon atom of said benzene ring.

摘要翻译： 包含大于10重量％的芳族聚酰胺和用于聚酰胺的溶剂的各向异性芳族聚酰胺涂料，所述聚酰胺基本上由至少5摩尔％但小于35摩尔％，基于其整个单元，仅含有 由下式（1）表示的部分p取向结构单元其中Ar1是链延伸键同轴或平行的二价芳环，X是选自O，S和NH的成员， 并且与上述苯并恶唑，苯并噻唑或苯并咪唑环的苯环键合的NH基是所述苯环的碳原子的间位或对位。

公开(公告)号：US5189094A

公开(公告)日：1993-02-23

申请号：US680005

申请日：1991-04-01

申请人： Hiroyuki Umetani ,  Hiroo Inata ,  Shunichi Matsumura ,  Hiroshi Mera

发明人： Hiroyuki Umetani ,  Hiroo Inata ,  Shunichi Matsumura ,  Hiroshi Mera

IPC分类号： C08F299/04 ,  C08L67/06

CPC分类号： C08F299/0478 ,  C08L67/06

摘要： A process for producing a thermoset resin, which comprises reacting (A) a poly(cyclic iminoether), (B) an ethylenically unsaturated compound having a functional group reactive with the poly(cyclic iminoether), and (C) an ethylenically unsaturated monomer having no functional group reactive with the poly(cyclic iminoether), in the presence of an acid catalyst and a radical catalyst. Instead of the compound (B), there may be used the compound (D), i.e. a compound having at least two equivalents of at least one group selected from the class consisting of carboxyl, hydroxyl, amino, epoxy and carboxylic anhydride groups in the molecule and being free from an ethylenically unsaturated bond. The present application provides also a thermosetting composition and a thermoset resin.

摘要翻译： 一种制备热固性树脂的方法，其包括使（A）聚（环亚胺基醚），（B）具有与聚（环亚胺醚）反应的官能团的烯键式不饱和化合物与（C）烯属不饱和单体 在酸催化剂和自由基催化剂的存在下，没有与聚（环亚胺醚）反应的官能团。 代替化合物（B），可以使用化合物（D），即具有至少两当量的选自羧基，羟基，氨基，环氧基和羧酸酐基团中的至少一个基团的化合物 分子并且不含烯属不饱和键。 本申请还提供了热固性组合物和热固性树脂。

公开(公告)号：US4413114A

公开(公告)日：1983-11-01

申请号：US363485

申请日：1982-03-30

申请人： Keizo Shimada ,  Hiroshi Mera ,  Noriaki Sasaki ,  Akihiro Aoki

发明人： Keizo Shimada ,  Hiroshi Mera ,  Noriaki Sasaki ,  Akihiro Aoki

IPC分类号： C08G69/00 ,  C08G69/32 ,  C08G69/40 ,  C08G69/42 ,  D01F6/80

CPC分类号： D01F6/805 ,  C08G69/32 ,  C08G69/40 ,  C08G69/42

摘要： An aromatic copolyamide comprising recurring units (A) of the formula (I), (B) of the formula (II) and (C) of the formula (III): ##STR1## wherein in (I), (II) and (III), Ar.sub.1 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented meta; Ar.sub.2 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented coaxially or in parallel to each other and radicals of the formula (IV): ##STR2## wherein Y.sub.1 and Y.sub.2 are independently ##STR3## and; X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 respectively are independently --NH-- and --CO-- radicals, connected to each other to form an amide bond (--NHCO-- or --CHNH--), and the molar proportions of said recurring units (A), (B), and (C) fall within a quadrilateral defined by the co-ordinates P, Q, R and S or on a twice-turned line defined by the co-ordinates Q, R, S and P:P (A 50, B 5, C 45)Q (A 5, B 5, C 90)R (A 5, B 40, C 55) andS (A 50, B 15, C 35)on a triangular composition diagram.

摘要翻译： 包含式（I）的重复单元（A），式（II）的（B）和式（III）的（C））的芳族共聚酰胺：（I）X3Ar1X4和（II）X5Ar2X6 ）其中在（I），（II）和（III）中，Ar 1是亚苯基，亚萘基或亚联苯基，其各自具有取代的元素的两个价键; Ar 2是亚苯基，亚萘基或亚联苯基，其各自具有彼此同轴或平行取向的两个价键和式（IV）的基团：其中Y1和Y2独立地为＆lt; IMAGE＆gt;和 X1，X2，X3，X4，X5和X6分别独立地为-NH-和-CO-基团，彼此连接形成酰胺键（-NHCO-或-CHNH-），所述重复单元的摩尔比例 （A），（B）和（C）落在由坐标P，Q，R和S所定义的四边形内，或者在由坐标Q，R，S和P定义的两倍线上： 在三角形组成图上的P（A 50，B 5，C 45）Q（A 5，B 5，C 90）R（A 5，B 40，C 55）和S（A 50，B 15，C 35） 。

公开(公告)号：US4389521A

公开(公告)日：1983-06-21

申请号：US322892

申请日：1981-11-19

申请人： Keizo Shimada ,  Hiroshi Mera ,  Tsutomu Nakamura ,  Akihiro Aoki

发明人： Keizo Shimada ,  Hiroshi Mera ,  Tsutomu Nakamura ,  Akihiro Aoki

IPC分类号： C08G69/28 ,  C08G73/06 ,  C08G73/18 ,  C08G75/32 ,  C08G69/26

CPC分类号： C08G73/0688 ,  C08G69/28 ,  C08G73/06 ,  C08G73/0616 ,  C08G73/0672 ,  C08G73/18 ,  C08G75/32

摘要： An aromatic and/or heterocyclic polyamide-amide type polar solvent composition is prepared by prepolymerizing an aromatic or heterocyclic diamine with an aromatic or heterocyclic or heterocyclic dicarboxylic acid chloride in a smaller molar equivalent than that of the diamine to prepare a prepolymer solution having a solution viscosity of 20 poise or less; by removing a by-product, hydrochloric acid, from the resultant prepolymer solution by neutralizing it with ammonia to such an extent that the pH of a mixture of 10 g of the neutralized mixture with 200 ml of water becomes 3.7 to 8.0; by high polymerizing the prepolymer with an additional amount of aromatic or heterocyclic dicarboxylic acid chloride, and; finally, by converting the entire amount of hydrochloric acid and 10 to 70% NH.sub.4 Cl in the resultant polyamide solution into an amide type polar solvent-soluble salt, with a neutralizing agent, the amount of the salt being in a range of from 5 to 95% by weight of the theoretical amount of the salt to be derived from the entire amount of the dicarboxylic acid chloride.

摘要翻译： 芳族和/或杂环聚酰胺 - 酰胺型极性溶剂组合物通过使芳族或杂环二胺与二胺的摩尔当量摩尔当量的芳族或杂环或杂环二羧酰氯预聚合来制备具有溶液的预聚物溶液 粘度20泊以下; 通过用氨中和它从所得预聚物溶液中除去副产物盐酸，使得10g的中和混合物与200ml水的混合物的pH变为3.7-8.0; 通过使预聚物与另外量的芳族或杂环二羧酸氯化物高度聚合， 最后，通过将所得聚酰胺溶液中的全部量的盐酸和10〜70％的NH 4 Cl转化为酰胺型极性溶剂可溶性盐，用中和剂将盐的量在5〜95的范围内 由二羧酸氯化物的全部量衍生的盐的理论量的重量％。

公开(公告)号：US4355151A

公开(公告)日：1982-10-19

申请号：US120992

申请日：1980-02-13

申请人： Keizo Shimada ,  Hiroshi Mera ,  Noriaki Sasaki ,  Akihiro Aoki

发明人： Keizo Shimada ,  Hiroshi Mera ,  Noriaki Sasaki ,  Akihiro Aoki

IPC分类号： C08G69/00 ,  C08G69/32 ,  C08G69/40 ,  C08G69/42 ,  D01F6/80

CPC分类号： D01F6/805 ,  C08G69/32 ,  C08G69/40 ,  C08G69/42

摘要： An aromatic copolyamide comprising recurring units (A) of the formula (I), (B) of the formula (II) and (C) of the formula (III): ##STR1## wherein in (I), (II) and (III) Ar.sub.1 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented meta; Ar.sub.2 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented coaxially or in parallel to each other and radicals of the formula (IV): ##STR2## wherein Y.sub.1 and Y.sub.2 are independently; ##STR3## and; X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 respectively are independently --NH-- and --CO-- radicals, connected to each other to form an amide bond (--NHCO-- or --CHNH--), and the molar proportions of said recurring units (A), (B) and (C) fall within a quadrilateral defined by the co-ordinates P, Q, R and S or on a twice-turned line defined by the co-ordinates Q,R,S, and P:P (A 50, B 5, C 45)Q (A 5, B 5, C 90)R (A 5, B 40, C 55) andS (A 50, B 15, C 35)on a triangular composition diagram.

摘要翻译： 包含式（I）的重复单元（A），式（II）的（B）和式（III）的（C））的芳族共聚酰胺：（I）X3Ar1X4（II）和X5Ar2X6 ）其中在（I），（II）和（III）中，Ar 1是亚苯基，亚萘基或亚联苯基，每个具有取代的二价键; Ar 2是亚苯基，亚萘基或亚联苯基，其各自具有彼此同轴或平行取向的两个价键和式（IV）的基团：其中Y1和Y2独立地表示： 和 X1，X2，X3，X4，X5和X6分别独立地为-NH-和-CO-基团，彼此连接形成酰胺键（-NHCO-或-CHNH-），所述重复单元的摩尔比例 （A），（B）和（C）落在由坐标P，Q，R和S所定义的四边形内，或者在由坐标Q，R，S和P定义的两次转弯线上： 在三角形组成图上的P（A 50，B 5，C 45）Q（A 5，B 5，C 90）R（A 5，B 40，C 55）和S（A 50，B 15，C 35） 。

公开(公告)号：US4342715A

公开(公告)日：1982-08-03

申请号：US201701

申请日：1980-10-29

申请人： Keizo Shimada ,  Akihiro Aoki ,  Hiroshi Mera ,  Tsutomu Nakamura

发明人： Keizo Shimada ,  Akihiro Aoki ,  Hiroshi Mera ,  Tsutomu Nakamura

IPC分类号： D01F6/60 ,  D01F6/00

CPC分类号： D01F6/605

摘要： A wholly aromatic polyamide shaped article is prepared by a process wherein a solution of a wholly aromatic polyamide is extruded through an orifice and introduced into a first coagulating bath comprising an aqueous coagulating liquid and, then, the coagulated extrudate is introduced into a second coagulating bath comprising an aqueous solution of an inorganic salt.

摘要翻译： 通过一种方法制备全芳族聚酰胺成型制品，其中将全芳族聚酰胺的溶液通过孔挤出并引入包含含水凝固液的第一凝固浴中，然后将凝固的挤出物引入第二凝固浴 包括无机盐的水溶液。

公开(公告)号：US5068296A

公开(公告)日：1991-11-26

申请号：US644664

申请日：1991-02-25

申请人： Shigeyoshi Hara ,  Zen-ichiro Endo ,  Hiroshi Mera

发明人： Shigeyoshi Hara ,  Zen-ichiro Endo ,  Hiroshi Mera

IPC分类号： C08G61/08

CPC分类号： C08G61/08

摘要： A cross-linked copolymer containing repeating units derived from a mixture comprising the following monomers: ##STR1## and occasionally other repeating units derived from other metathesis polymerizable cyclic compounds such as dicyclopentadiene, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.

公开(公告)号：US5064919A

公开(公告)日：1991-11-12

申请号：US442428

申请日：1989-11-24

申请人： Shigeyoshi Hara ,  Zen-ichiro Endo ,  Hiroshi Mera

发明人： Shigeyoshi Hara ,  Zen-ichiro Endo ,  Hiroshi Mera

IPC分类号： C08F232/08 ,  B29C45/00 ,  B29K86/00 ,  C08F32/00 ,  C08F34/00 ,  C08F234/00 ,  C08G61/06 ,  C08G61/08

CPC分类号： C08G61/08

摘要： A process for producing a molded article by introducing a reactive liquid mixture which comprises a cycloalkene containing dicyclopentadiene, a norbornene-type monomer containing at least one N-substituted 5-membered cyclic imide group and a metathesis polymerization catalyst system and which has moderated metathesis polymerizability into a mold in which the liquid mixture is metathesis polymerized, and a multi-part polymerizable composition for producing the molded article.