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公开(公告)号:US07153611B2
公开(公告)日:2006-12-26
申请号:US10673610
申请日:2003-09-30
申请人: Hiroshi Minami , Katsunobu Sayama , Hiromasa Yagi , Atsushi Fukui , Mariko Torimae , Yasuyuki Kusumoto , Hisaki Tarui
发明人: Hiroshi Minami , Katsunobu Sayama , Hiromasa Yagi , Atsushi Fukui , Mariko Torimae , Yasuyuki Kusumoto , Hisaki Tarui
CPC分类号: H01M4/622 , H01M2/1673 , H01M4/0404 , H01M4/0419 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/386 , H01M4/40 , H01M4/661 , H01M10/052 , H01M10/0565 , H01M10/058 , H01M2300/0085 , Y10T29/49108 , Y10T29/49115
摘要: A lithium secondary battery comprising an electrode in which an active material layer which includes an active material that electrochemically occludes and releases lithium is formed on a current collector, wherein cracks are formed in the active material layer by occlusion and release of lithium ions and thereafter a solid electrolyte is formed in the cracks in the active material layer.
摘要翻译: 一种锂二次电池,其特征在于,在集电体上形成有包含电化学吸留和释放锂的活性物质的活性物质层的电极,其中,通过锂离子的闭塞和释放在活性物质层中形成裂纹, 在活性物质层的裂纹中形成固体电解质。
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公开(公告)号:US08211569B2
公开(公告)日:2012-07-03
申请号:US10531047
申请日:2004-06-04
申请人: Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
发明人: Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
IPC分类号: H01M6/14 , H01M4/134 , H01M4/1395
CPC分类号: H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要: A rechargeable lithium battery including a negative electrode made by sintering, on a surface of a conductive metal foil as a current collector, a layer of a mixture of active material particles containing silicon and/or a silicon alloy and a binder, a positive electrode and a nonaqueous electrolyte, characterized in that the nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译: 一种可再充电锂电池,包括通过烧结制成的负极,作为集电体的导电金属箔的表面,含有硅和/或硅合金和粘合剂的活性物质颗粒的混合物层,正极和 非水电解质,其特征在于,所述非水电解质含有溶解在其中的二氧化碳。
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公开(公告)号:US20060003226A1
公开(公告)日:2006-01-05
申请号:US10531047
申请日:2004-06-04
申请人: Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
发明人: Shouichirou Sawa , Hiroshi Minami , Mariko Torimae , Atsushi Fukui , Yasuyuki Kusumoto , Katsunobu Sayama , Maruo Kamino
CPC分类号: H01M10/052 , H01M4/0471 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0567 , H01M10/058 , H01M2004/027 , Y10T29/49108
摘要: A rechargeable lithium battery including a negative electrode made by sintering, on a surface of a conductive metal foil as a current collector, a layer of a mixture of active material particles containing silicon and/or a silicon alloy and a binder, a positive electrode and a nonaqueous electrolyte, characterized in that the nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译: 一种可再充电锂电池,包括通过烧结制成的负极,作为集电体的导电金属箔的表面,含有硅和/或硅合金和粘合剂的活性物质颗粒的混合物层,正极和 非水电解质,其特征在于,所述非水电解质含有溶解在其中的二氧化碳。
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公开(公告)号:US20080124631A1
公开(公告)日:2008-05-29
申请号:US11771552
申请日:2007-06-29
CPC分类号: H01M4/134 , H01M4/0404 , H01M4/38 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/622 , H01M4/625 , H01M4/64 , H01M4/661 , H01M2004/027
摘要: A lithium secondary battery includes an electrode assembly having a positive electrode (1), a negative electrode (2) having a negative electrode current collector and a negative electrode active material layer formed on a surface of the negative electrode current collector and composed of a binder and negative electrode active material particles containing silicon and/or a silicon alloy, and a separator (3) interposed between the electrodes. The electrode assembly is impregnated with a non-aqueous electrolyte. The binder contains a polyimide resin represented by the following chemical formula (1): where R contains at least a benzene ring, and n is within the range of from 10 to 100,000, and the negative electrode active material particles have an average particle size of 5 μm or greater.
摘要翻译: 锂二次电池包括具有正极(1)的电极组件,负极集电体的负极(2)和形成在负极集电体的表面上并由粘合剂构成的负极活性物质层 和含有硅和/或硅合金的负极活性物质粒子,以及夹在电极之间的隔膜(3)。 电极组件浸渍有非水电解质。 粘合剂含有下述化学式(1)表示的聚酰亚胺树脂:其中,R至少含有苯环,n在10〜100,000的范围内,负极活性物质粒子的平均粒径为 5岁以上。
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公开(公告)号:US08771873B2
公开(公告)日:2014-07-08
申请号:US11771552
申请日:2007-06-29
IPC分类号: H01M4/13
CPC分类号: H01M4/134 , H01M4/0404 , H01M4/38 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/622 , H01M4/625 , H01M4/64 , H01M4/661 , H01M2004/027
摘要: A lithium secondary battery includes an electrode assembly having a positive electrode (1), a negative electrode (2) having a negative electrode current collector and a negative electrode active material layer formed on a surface of the negative electrode current collector and composed of a binder and negative electrode active material particles containing silicon and/or a silicon alloy, and a separator (3) interposed between the electrodes. The electrode assembly is impregnated with a non-aqueous electrolyte. The binder contains a polyimide resin represented by the following chemical formula (1): where R contains at least a benzene ring, and n is within the range of from 10 to 100,000, and the negative electrode active material particles have an average particle size of 5 μm or greater.
摘要翻译: 锂二次电池包括具有正极(1)的电极组件,负极集电体的负极(2)和形成在负极集电体的表面上并由粘合剂构成的负极活性物质层 和含有硅和/或硅合金的负极活性物质粒子,以及夹在电极之间的隔膜(3)。 电极组件浸渍有非水电解质。 粘合剂含有下述化学式(1)表示的聚酰亚胺树脂:其中,R至少含有苯环,n在10〜100,000的范围内,负极活性物质粒子的平均粒径为 5μm以上。
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公开(公告)号:US08338022B2
公开(公告)日:2012-12-25
申请号:US11001192
申请日:2004-12-02
申请人: Atsushi Fukui , Hiroshi Minami , Shoichiro Sawa , Mariko Torimae , Yasuyuki Kusumoto , Maruo Kamino
发明人: Atsushi Fukui , Hiroshi Minami , Shoichiro Sawa , Mariko Torimae , Yasuyuki Kusumoto , Maruo Kamino
IPC分类号: H01M2/02
CPC分类号: H01M10/052 , H01M4/0471 , H01M4/131 , H01M4/134 , H01M4/386 , H01M4/525 , H01M4/622 , H01M4/661 , H01M4/70 , H01M10/0587 , H01M2004/021 , Y10T29/49108
摘要: A lithium secondary battery of the present invention comprises a positive electrode formed by disposing a positive-electrode mixture layer containing a positive-electrode active material and a positive-electrode binder, on a surface of a positive-electrode current collector; a negative electrode formed by sintering a negative-electrode mixture layer containing a negative-electrode binder and a negative-electrode active material containing silicon and/or a silicon alloy, disposed on a surface of a negative-electrode current collector; a separator disposed between the positive electrode and the negative electrode; and a nonaqueous electrolyte; wherein an electrode unit obtained by setting the positive electrode and the negative electrode opposed to each other through the separator and rolling them in spirally rolled state is placed in a cylindrical battery container and wherein a curvature radius of the negative-electrode mixture layer opposed to the positive-electrode mixture layer through the separator in the spirally rolled state is 1.5 mm or larger.
摘要翻译: 本发明的锂二次电池包括在正极集电体的表面上设置含有正极活性物质和正极粘合剂的正极合剂层而形成的正极, 通过在负极集电体的表面上烧结含有负极粘合剂的负极混合层和含有硅和/或硅合金的负极活性物质而形成的负极, 设置在所述正极和所述负极之间的隔膜; 和非水电解质; 其特征在于,将通过隔板相对的正极和负极通过将螺旋卷绕状态进行轧制而得到的电极单元配置在圆筒状的电池容器中,其中与负极混合层相对的曲率半径 螺旋状卷取状态的正极混合层通过隔膜的厚度为1.5mm以上。
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公开(公告)号:US20050123829A1
公开(公告)日:2005-06-09
申请号:US11001192
申请日:2004-12-02
申请人: Atsushi Fukui , Hiroshi Minami , Shoichiro Sawa , Mariko Torimae , Yasuyuki Kusumoto , Maruo Kamino
发明人: Atsushi Fukui , Hiroshi Minami , Shoichiro Sawa , Mariko Torimae , Yasuyuki Kusumoto , Maruo Kamino
IPC分类号: H01M4/66 , H01M2/02 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/62 , H01M4/70 , H01M10/04 , H01M10/05 , H01M10/052 , H01M10/0587 , H01M4/58
CPC分类号: H01M10/052 , H01M4/0471 , H01M4/131 , H01M4/134 , H01M4/386 , H01M4/525 , H01M4/622 , H01M4/661 , H01M4/70 , H01M10/0587 , H01M2004/021 , Y10T29/49108
摘要: A lithium secondary battery of the present invention comprises a positive electrode formed by disposing a positive-electrode mixture layer containing a positive-electrode active material and a positive-electrode binder, on a surface of a positive-electrode current collector; a negative electrode formed by sintering a negative-electrode mixture layer containing a negative-electrode binder and a negative-electrode active material containing silicon and/or a silicon alloy, disposed on a surface of a negative-electrode current collector; a separator disposed between the positive electrode and the negative electrode; and a nonaqueous electrolyte; wherein an electrode unit obtained by setting the positive electrode and the negative electrode opposed to each other through the separator and rolling them in spirally rolled state is placed in a cylindrical battery container and wherein a curvature radius of the negative-electrode mixture layer opposed to the positive-electrode mixture layer through the separator in the spirally rolled state is 1.5 mm or larger.
摘要翻译: 本发明的锂二次电池包括在正极集电体的表面上设置含有正极活性物质和正极粘合剂的正极合剂层而形成的正极, 通过在负极集电体的表面上烧结含有负极粘合剂的负极混合层和含有硅和/或硅合金的负极活性物质而形成的负极, 设置在所述正极和所述负极之间的隔膜; 和非水电解质; 其特征在于,将通过隔板相对的正极和负极通过螺旋卷绕状态进行轧制而得到的电极单元配置在圆筒状的电池容器中,其中负极混合层的曲率半径与 螺旋状卷取状态的正极混合层通过隔膜的厚度为1.5mm以上。
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公开(公告)号:US08609279B2
公开(公告)日:2013-12-17
申请号:US10531045
申请日:2004-06-03
申请人: Daizo Jito , Noriyuki Tamura , Nobuhiro Sakitani , Hiroshi Minami , Hiromasa Yagi , Maruo Kamino , Katsunobu Sayama , Yoshio Kato , Shigeki Matsuta
发明人: Daizo Jito , Noriyuki Tamura , Nobuhiro Sakitani , Hiroshi Minami , Hiromasa Yagi , Maruo Kamino , Katsunobu Sayama , Yoshio Kato , Shigeki Matsuta
CPC分类号: H01M10/052 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0585 , H01M10/4235 , H01M2300/0017 , Y10T29/49115
摘要: A rechargeable lithium battery including a negative electrode made by depositing a noncrystalline thin film composed entirely or mainly of silicon on a current collector, a positive electrode and a nonaqueous electrolyte, characterized in that said nonaqueous electrolyte contains carbon dioxide dissolved therein.
摘要翻译: 一种可再充电锂电池,其包括通过在集电体上沉积完全或主要由硅构成的非晶薄膜而制成的负极,正极和非水电解质,其特征在于,所述非水电解质含有溶解于其中的二氧化碳。
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公开(公告)号:US20060024588A1
公开(公告)日:2006-02-02
申请号:US10531045
申请日:2004-06-03
申请人: Daizo Jito , Noriyuki Tamura , Nobuhiro Sakitani , Hiroshi Minami , Hiromasa Yagi , Maruo Kamino , Katsunobu Sayama , Yoshio Kato , Shigeki Matsuta
发明人: Daizo Jito , Noriyuki Tamura , Nobuhiro Sakitani , Hiroshi Minami , Hiromasa Yagi , Maruo Kamino , Katsunobu Sayama , Yoshio Kato , Shigeki Matsuta
CPC分类号: H01M10/052 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0585 , H01M10/4235 , H01M2300/0017 , Y10T29/49115
摘要: A rechargeable lithium battery including a negative electrode made by depositing a noncrystalline thin film composed entirely or mainly of silicon on a current collector, a positive electrode and a nonaqueous electrolyte, characterized in that said nonaqueous electrolyte contains carbon dioxide dissolved therein.
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公开(公告)号:US20050106465A1
公开(公告)日:2005-05-19
申请号:US10992081
申请日:2004-11-19
申请人: Hiroshi Minami , Hiromasa Yagi , Katsunobu Sayama , Maruo Kamino
发明人: Hiroshi Minami , Hiromasa Yagi , Katsunobu Sayama , Maruo Kamino
IPC分类号: C01G51/00 , H01M2/26 , H01M2/28 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/525 , H01M4/66 , H01M6/16 , H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M4/58
CPC分类号: H01M10/052 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/386 , H01M4/525 , H01M10/0567 , H01M10/0569 , H01M2004/021 , H01M2004/028
摘要: Charge-discharge cycle performance is improved in a lithium secondary battery including a negative electrode containing a negative electrode active material having silicon as its main component, provided on a surface of a current collector, a positive electrode containing a positive electrode active material, and a non-aqueous electrolyte. The positive electrode active material is a lithium transition metal oxide containing Li and Co and having a layered structure, and further containing a group IVA element of the periodic table, such as Zr, Ti, or Tf, and a group IIA element of the periodic table, such as Mg.
摘要翻译: 在集电体的表面设置有含有作为主要成分的负极活性物质的负极的锂二次电池,含有正极活性物质的正极和含有正极活性物质的正极的锂二次电池的充放电循环性能提高, 非水电解质。 正极活性物质是包含Li和Co并具有层状结构的锂过渡金属氧化物,并且还含有周期表中的IVA族元素,例如Zr,Ti或Tf,以及周期表的第IIA族元素 表,如Mg。
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