Abstract:
A chiral catalyst represented by formula (I) is provided. In formula (I), Z═Z1 or Z2, and the combination of Z1 and Z2 in formula (I) includes Y independently includes hydrogen, fluorine, trifluoromethyl, isopropyl, tert-butyl, CmH2m+1 or OCmH2m+1, m=1-10, and n=1-10. A heterogeneous chiral catalyst including the chiral catalyst is also provided.
Abstract:
In an embodiment of the present disclosure, a liquid crystal display is provided. The liquid crystal display includes an upper substrate, a lower substrate opposite to the upper substrate, and a liquid crystal layer disposed between the upper substrate and the lower substrate, wherein the liquid crystal layer includes a first chiral compound and a second chiral compound, and the first chiral compound and the second chiral compound are enantiomeric and separated from each other.
Abstract:
An embodiment of the disclosure provides a liquid crystal compound having the following formula: wherein A1, A2, and A3 are independently hydrogen, halogen, cyano, thiocyanato, or —OCF3; R1 is hydrogen, halogen, C1-C12 alkyl, C1-C12 alkoxy, C1-C12 haloalkly, C2-C12 alkenyl, or C2-C12 alkynyl; R2 and R3 are independently hydrogen, halogen, C1-C6 alkyl, C1-C6 haloalkly, cyano, thiocyanato, or —OCF3; and Z is a single bond, —O—, —CH2O—, —C(O)O—, —OCO—, —C(O)NH—, or —CH═CH—. In another embodiment, a liquid crystal display including the liquid crystal compound is also provided.
Abstract:
A method for preparing a nitrate ester is provided. The method includes providing a first solution including a compound (which has at least one hydroxyl group) and a carboxylic acid having 2-5 carbon atoms; providing a second solution including nitric acid, acetic anhydride, and acetic acid; and transferring the first solution and the second solution to a microreactor, obtaining a nitrate ester after a residence time. In particular, the ratio of the weight of nitric acid to the total volume of the acetic anhydride and acetic acid is 1:1 to 1:3.5. The ratio of the molar amount of nitric acid to the hydroxyl group equivalent of the compound is from 1:1 to 15:1.
Abstract:
A chiral catalyst represented by formula (II) is provided. In formula (II), Y independently includes hydrogen, fluorine, trifluoromethyl, isopropyl, tert-butyl, CmH2m+1 or OCmH2m+1, wherein m=1-10 and n=1-10. A heterogeneous chiral catalyst is also provided. The heterogeneous chiral catalyst includes the chiral catalyst represented by formula (II), and a substrate connected to the chiral catalyst.
Abstract:
A compound and a liquid-crystal composition employing the same are provided. The compound has a structure represented by Formula (I) wherein Za and Zb are independently A1, A2, A3 and A4 are independently single bond, Z1, Z2, Z3, and Z4 are independently single bond, R is independently hydrogen, or C1-4 alkyl group; R1 and R2 are independently single bond, —O—(CH2)n—, —CH═CH—(CH2)2—, —(CH2)2—CH═CH—, —CH═CH—, or —C≡C—; n is an integer from 1 to 6; B1 and B2 are independently and, R3 is hydrogen, or methyl group.
Abstract:
A compound and a liquid-crystal composition employing the same are provided. The compound has a structure represented by Formula (I) wherein Za and Zb are independently A1, A2, A3, and A4 are independently Z1, Z2, Z3, and Z4 are independently single bond, R is independently hydrogen, or C1-4 alkyl group; R1 and R2 are independently —O—(CH2)n—, —CH═CH—(CH2)2—, —(CH2)2—CH═CH—, —CH═CH—, or —C≡C—; n is an integer from 1 to 6; B1 and B2 are independently and, R3 is hydrogen, or methyl group.
Abstract:
Organic metal compounds, organic light-emitting devices, and lighting devices employing the same are provided. The organic metal compound has a chemical structure represented by Formula (I): , wherein M is Ir, Pt, Ru, Os, Cu, Au, or Pd; n is 1, 2, or 3; m is 0, 1, or 2, and the sum of m and n is equal to a valence of M; L is a bidentate ligand; R1 is hydrogen, C1-9 alkyl group, C5-10 cycloalkyl group, or C5-12 aromatic group; each of R2 is independent and can be hydrogen, halogen, cyano group, C1-9 alkyl group, C1-6 fluoroalkyl group, C5-10 cycloalkyl group, or C5-12 aromatic group; R3 is halogen; and, R4 and R5 are independently the same or different hydrogen, hydroxyl group, amine group, alkyl amine group, halogen, cyano group, C1-9 alkyl group, C1-6 fluoroalkyl group, C5-10 cycloalkyl group, or C5-12 aromatic group.