Abstract:
A chiral catalyst represented by formula (I) is provided. In formula (I), Z═Z1 or Z2, and the combination of Z1 and Z2 in formula (I) includes Y independently includes hydrogen, fluorine, trifluoromethyl, isopropyl, tert-butyl, CmH2m+1 or OCmH2m+1, m=1-10, and n=1-10. A heterogeneous chiral catalyst including the chiral catalyst is also provided.
Abstract:
Disclosed is a liquid crystal compound with negative dielectric anisotropy, having a general formula as Formula 1. In Formula 1, each of L1, L2, L3, and L4, being same or different, is hydrogen, halogen, or cyano group. Each of R1 and R2, being same or different, is hydrogen, halogen, C1-12 alkyl group, C1-12 alkoxy group, C1-12 haloalkyl group, C2-12 alkenyl group, C2-12 ether group, or C2-12 alkynyl group. Each of A1 and A2, being same or different, is benzene, cyclohexane, or cyclohexene.Z1 is —CF2O—, or —OCF2—, and Z2 is —CF2O—, or —OCF2—.
Abstract:
In an embodiment of the present disclosure, a liquid crystal display is provided. The liquid crystal display includes an upper substrate, a lower substrate opposite to the upper substrate, and a liquid crystal layer disposed between the upper substrate and the lower substrate, wherein the liquid crystal layer includes a first chiral compound and a second chiral compound, and the first chiral compound and the second chiral compound are enantiomeric and separated from each other.
Abstract:
An embodiment of the disclosure provides a liquid crystal compound having the following formula: wherein A1, A2, and A3 are independently hydrogen, halogen, cyano, thiocyanato, or —OCF3; R1 is hydrogen, halogen, C1-C12 alkyl, C1-C12 alkoxy, C1-C12 haloalkly, C2-C12 alkenyl, or C2-C12 alkynyl; R2 and R3 are independently hydrogen, halogen, C1-C6 alkyl, C1-C6 haloalkly, cyano, thiocyanato, or —OCF3; and Z is a single bond, —O—, —CH2O—, —C(O)O—, —OCO—, —C(O)NH—, or —CH═CH—. In another embodiment, a liquid crystal display including the liquid crystal compound is also provided.
Abstract:
A method for preparing a nitrate ester is provided. The method includes providing a first solution including a compound (which has at least one hydroxyl group) and a carboxylic acid having 2-5 carbon atoms; providing a second solution including nitric acid, acetic anhydride, and acetic acid; and transferring the first solution and the second solution to a microreactor, obtaining a nitrate ester after a residence time. In particular, the ratio of the weight of nitric acid to the total volume of the acetic anhydride and acetic acid is 1:1 to 1:3.5. The ratio of the molar amount of nitric acid to the hydroxyl group equivalent of the compound is from 1:1 to 15:1.
Abstract:
An optical device is provided, which includes a first transparent substrate, a second transparent substrate, and a liquid-crystal material disposed between the first transparent substrate and the second transparent substrate. The liquid-crystal material includes a photo responsive material with a chemical structure of: wherein A1 is A2 and A3 are independently X is halogen. R is H, C1-12 alkyl group, or C1-12 alkoxy group. R′ is C1-12 alkyl group.
Abstract:
A chiral catalyst represented by formula (II) is provided. In formula (II), Y independently includes hydrogen, fluorine, trifluoromethyl, isopropyl, tert-butyl, CmH2m+1 or OCmH2m+1, wherein m=1-10 and n=1-10. A heterogeneous chiral catalyst is also provided. The heterogeneous chiral catalyst includes the chiral catalyst represented by formula (II), and a substrate connected to the chiral catalyst.
Abstract:
A compound and a liquid-crystal composition employing the same are provided. The compound has a structure represented by Formula (I) wherein Za and Zb are independently A1, A2, A3 and A4 are independently single bond, Z1, Z2, Z3, and Z4 are independently single bond, R is independently hydrogen, or C1-4 alkyl group; R1 and R2 are independently single bond, —O—(CH2)n—, —CH═CH—(CH2)2—, —(CH2)2—CH═CH—, —CH═CH—, or —C≡C—; n is an integer from 1 to 6; B1 and B2 are independently and, R3 is hydrogen, or methyl group.
Abstract:
A compound and a liquid-crystal composition employing the same are provided. The compound has a structure represented by Formula (I) wherein Za and Zb are independently A1, A2, A3, and A4 are independently Z1, Z2, Z3, and Z4 are independently single bond, R is independently hydrogen, or C1-4 alkyl group; R1 and R2 are independently —O—(CH2)n—, —CH═CH—(CH2)2—, —(CH2)2—CH═CH—, —CH═CH—, or —C≡C—; n is an integer from 1 to 6; B1 and B2 are independently and, R3 is hydrogen, or methyl group.
Abstract:
Organic metal compounds, organic light-emitting devices, and lighting devices employing the same are provided. The organic metal compound has a chemical structure represented by Formula (I): , wherein M is Ir, Pt, Ru, Os, Cu, Au, or Pd; n is 1, 2, or 3; m is 0, 1, or 2, and the sum of m and n is equal to a valence of M; L is a bidentate ligand; R1 is hydrogen, C1-9 alkyl group, C5-10 cycloalkyl group, or C5-12 aromatic group; each of R2 is independent and can be hydrogen, halogen, cyano group, C1-9 alkyl group, C1-6 fluoroalkyl group, C5-10 cycloalkyl group, or C5-12 aromatic group; R3 is halogen; and, R4 and R5 are independently the same or different hydrogen, hydroxyl group, amine group, alkyl amine group, halogen, cyano group, C1-9 alkyl group, C1-6 fluoroalkyl group, C5-10 cycloalkyl group, or C5-12 aromatic group.