公开(公告)号：US4162908A

公开(公告)日：1979-07-31

申请号：US874965

申请日：1978-02-03

申请人： Karlheinz Rau ,  Fritz Simmat ,  Albert Muhlich ,  Norbert Treber

发明人： Karlheinz Rau ,  Fritz Simmat ,  Albert Muhlich ,  Norbert Treber

IPC分类号： C03B37/014 ,  C03B37/018 ,  C03C3/06 ,  C03C17/00 ,  C03C17/02 ,  C03C25/02

CPC分类号： C03B37/01426 ,  C03B37/01413 ,  C03B37/01823 ,  C03C3/06 ,  C03B2201/075 ,  C03B2201/12 ,  C03B2207/85 ,  C03C2201/12 ,  C03C2203/40 ,  Y10S65/16

摘要： An improvement in a method for producing a synthetic hydroxyl ion-free quartz glass wherein a hydrogen free silicon compound is heated in a hydrogen-free gas stream while the gas stream is passed through an induction coupled plasma burner, the gas stream containing elemental and/or bound oxygen and the oxidation product is deposited on a refractory support as a vitreous mass, the improvement lying in including in the gas stream a gaseous hydrogen-free, thermally decomposable compound which yields fluorine in an amount of at least 500 gms. per kilogram of silica to be produced; an apparatus for producing a synthetic OH ion-free quartz glass comprising an induction coupled plasma burner which burner has disposed thereabout 3 concentric quartz glass tubes disposed in stepped configuration of which the outermost tube is the longest and the innermost tube is the shortest. The apparatus includes means for passing through the innermost tube a hydrogen-free gas stream containing elemental oxygen and/or bound oxygen together with a gaseous hydrogen free thermally decomposable compound which yields fluorine. The apparatus further contains means for passing a separating gas such as oxygen through the space defined by the innermost tube and the middle tube and the middle tube and the outermost tube.

摘要翻译： 一种制备合成的无羟基离子的石英玻璃的方法的改进，其中在气流通过感应耦合等离子体燃烧器的同时，在无氢气体气流中加热无氢硅化合物，所述气流含有元素和/ 或结合氧，并且氧化产物作为玻璃体堆积在耐火载体上，其改进在于在气流中包含无气态的可热分解化合物，其产生至少500gms的量的氟。 每千克生产的二氧化硅; 一种用于生产合成的无OH离子的石英玻璃的装置，包括感应耦合等离子体燃烧器，该燃烧器设置在三个同心的石英玻璃管上，该同心石英玻璃管以阶梯状构造，其中最外面的管是最长的并且最内的管是最短的。 该装置包括用于通过最内管将含有元素氧和/或结合氧的无氢气体气流与产生氟的无氢气的可热分解化合物通过的装置。 该装置还包括用于使诸如氧的分离气体通过由最内管和中管以及中管和最外管限定的空间的装置。

公开(公告)号：US4165915A

公开(公告)日：1979-08-28

申请号：US713479

申请日：1976-08-11

申请人： Karlheinz Rau ,  Albert Muhlich ,  Fritz Simmat ,  Norbert Treber

发明人： Karlheinz Rau ,  Albert Muhlich ,  Fritz Simmat ,  Norbert Treber

IPC分类号： C03B23/047 ,  C03B23/207 ,  C03B37/012 ,  C03C13/04 ,  G02B6/00 ,  G02B5/14 ,  C03C25/02

CPC分类号： C03B23/207 ,  C03B23/047 ,  C03B37/01211 ,  C03C13/045 ,  C03B2201/02 ,  C03B2201/04 ,  C03B2201/12 ,  Y10S65/16 ,  Y10T428/2933

摘要： A semiproduct for use in the manufacture of light conducting fibers comprising a core of synthetic quartz glass having a thickness of 6 to 400 mm, the quartz glass containing less than 10 ppm hydroxyl ions and having, in the near infrared spectral range, an optical loss totaling less than 4 dB/km, measured in the mass, the core being fused with a jacket having a wall thickness of 2 to 20 mm and consisting essentially of synthetic quartz glass containing more than 4,000 ppm of fluorine, the jacket having a length of at least 200 mm; a method of producing the same and light conducting fibers derived therefrom.

摘要翻译： 一种用于制造导光纤维的半成品，其包括厚度为6至400mm的合成石英玻璃芯，所述石英玻璃含有小于10ppm的羟基离子，并且在近红外光谱范围内具有光损耗 总共小于4dB / km，以质量测量，芯部与壁厚为2至20mm的护套熔合并且基本上由含有大于4,000ppm氟的合成石英玻璃组成，该护套的长度为 至少200毫米; 其制造方法和由其衍生的导光纤维。

公开(公告)号：US4045198A

公开(公告)日：1977-08-30

申请号：US717075

申请日：1976-08-24

申请人： Karlheinz Rau ,  Albert Muhlich ,  Fritz Simmat ,  Norbert Treber

发明人： Karlheinz Rau ,  Albert Muhlich ,  Fritz Simmat ,  Norbert Treber

IPC分类号： C03B37/018 ,  G02B6/00 ,  C03C17/00 ,  G02B5/14

CPC分类号： C03B37/018 ,  C03B37/01853 ,  C03B2203/22 ,  Y10S65/16

摘要： There is disclosed a process for preparing a foreproduct useful in the production of an optical self-focusing lightconductor in which the index of refraction of the lightconductor diminishes with increasing distance from the conductor axis such that, when plotted against the conductor diameter, the refractive index curve is parabolic and the apex of the parabola lies over the center of the conductor diameter wherein a plurality of layers of doped silica are deposited on a cylindrical support, the layers being formed of a mixture of a vaporous silicon compound and a vaporous doping agent at elevated temperature. The invention involves depositing at least one layer of undoped silica between layers of doped silica and following each deposition of each doped or undoped silica layer by heating step in which the material is heated to a temperature of at least 900.degree. C to vitrify the same. Each layer is deposited in a thickness ranging from 0.1 to 20 .mu.m.

摘要翻译： 公开了一种制备可用于生产光学自聚焦光导体的前体产物的方法，其中光导体的折射率随着与导体轴线的距离的增加而减小，使得当相对于导体直径作图时，折射率 曲线是抛物线的，并且抛物线的顶点位于导体直径的中心之上，其中多个掺杂的二氧化硅层沉积在圆柱形支撑件上，这些层由气态硅化合物和气相掺杂剂的混合物形成， 升温 本发明涉及在掺杂二氧化硅的层之间沉积至少一层未掺杂的二氧化硅，并且随后通过加热步骤对每个掺杂或未掺杂的二氧化硅层进行每次沉积，其中将材料加热至至少900℃的温度以使其玻璃化。 每层沉积厚度为0.1至20微米。

公开(公告)号：USRE30883E

公开(公告)日：1982-03-16

申请号：US121078

申请日：1980-02-13

申请人： Karlheinz Rau ,  Fritz Simmat ,  Albert Muhlich ,  Norbert Treber

发明人： Karlheinz Rau ,  Fritz Simmat ,  Albert Muhlich ,  Norbert Treber

IPC分类号： C03B37/014 ,  C03B37/018 ,  C03C3/06 ,  G02B6/00

CPC分类号： C03C3/06 ,  C03B37/01413 ,  C03B37/01426 ,  C03B37/01823 ,  C03B2201/075 ,  C03B2201/12 ,  C03B2207/85 ,  C03C2201/12 ,  C03C2203/40

摘要： An improvement in a method for producing a synthetic hydroxyl ion-free quartz glass wherein a hydrogen free silicon compound is heated in a hydrogen-free gas stream while the gas stream is passed through an induction coupled plasma burner, the gas stream containing elemental and/or bound oxygen and the oxidation product is deposited on a refractory support as a vitreous mass, the improvement lying in including in the gas stream a gaseous hydrogen-free, thermally decomposable compound which yields fluorine in an amount of at least 500 gms. per kilogram of silica to be produced; an apparatus for producing a synthetic OH ion-free quartz glass comprising an induction coupled plasma burner which burner has disposed thereabout 3 concentric quartz glass tubes disposed in stepped configuration of which the outermost tube is the longest and the innermost tube is the shortest. The apparatus includes means for passing through the innermost tube a hydrogen-free gas stream containing elemental oxygen and/or bound oxygen together with a gaseous hydrogen free thermally decomposable compound which yields fluorine. The apparatus further contains means for passing a separating gas such as oxygen through the space defined by the innermost tube and the middle tube and the middle tube and the outermost tube.

公开(公告)号：US4235615A

公开(公告)日：1980-11-25

申请号：US11267

申请日：1979-02-09

申请人： Karlheinz Rau ,  Albert Muhlich ,  Fritz Simmat ,  Norbert Treber

发明人： Karlheinz Rau ,  Albert Muhlich ,  Fritz Simmat ,  Norbert Treber

IPC分类号： C03B23/047 ,  C03B23/207 ,  C03B37/012 ,  C03C13/04 ,  G02B6/00 ,  C03C25/02

CPC分类号： C03B23/207 ,  C03B23/047 ,  C03B37/01211 ,  C03C13/045 ,  C03B2201/02 ,  C03B2201/04 ,  C03B2201/12 ,  Y10S65/16 ,  Y10T428/2933

摘要： A semiproduct for use in the manufacture of light conducting fibers comprising a core of synthetic quartz glass having a thickness of 6 to 400 mm, the quartz glass containing less than 10 ppm hydroxyl ions and having, in the near infrared spectral range, an optical loss totaling less than 4 dB/km, measured in the mass, the core being fused with a jacket having a wall thickness of 2 to 20 mm and consisting essentially of synthetic quartz glass containing more than 4,000 ppm of fluorine, the jacket having a length of at least 200 mm; a method of producing the same and light conducting fibers derived therefrom.

摘要翻译： 一种用于制造导光纤维的半成品，其包括厚度为6至400mm的合成石英玻璃芯，所述石英玻璃含有小于10ppm的羟基离子，并且在近红外光谱范围内具有光损耗 总共小于4dB / km，以质量测量，芯部与壁厚为2至20mm的护套熔合并且基本上由含有大于4,000ppm氟的合成石英玻璃组成，该护套的长度为 至少200毫米; 其制造方法和由其衍生的导光纤维。

公开(公告)号：US07089765B2

公开(公告)日：2006-08-15

申请号：US10151846

申请日：2002-05-20

申请人： Hartwig Schaper ,  Norbert Treber ,  Oliver Humbach ,  Uwe Haken ,  Donald Paul Jablonowski

发明人： Hartwig Schaper ,  Norbert Treber ,  Oliver Humbach ,  Uwe Haken ,  Donald Paul Jablonowski

IPC分类号： C03B37/018

CPC分类号： C03B37/01892 ,  C03B37/01205 ,  C03B37/01211 ,  C03B2201/12 ,  C03B2201/31 ,  C03B2203/22 ,  C03B2203/36

摘要： On the basis of a known process for the production of a preform for an optical fiber for optical data transmission technology, the productivity of the process for the production of complex refractive index profiles is to be improved by providing a quartz glass substrate tube which exhibits different doping in radial direction, introducing a core glass made of synthetic quartz glass into the substrate tube and covering the substrate tube with a jacket tube. A substrate tube suitable therefor is also being provided which tube requires less core glass material for the production of the preform, whether during the internal deposition or for the core glass rod in the rod-in-tube technique. Regarding the process it is proposed according to the invention that a substrate tube be used which was obtained by vitrification of a porous tube-shaped SiO2 blank, the substrate tube being provided with a core glass layer which is produced in that to the first radial portion of the SiO2 blank there is added before the vitrification a first dopant which increases the refractive index of quartz glass. The substrate tube according to the invention has in the radial direction regions of different doping whereby it incorporates a core glass layer which has a refractive index of at least 1.459.

摘要翻译： 在制造用于光学数据传输技术的光纤预制件的已知方法的基础上，通过提供具有不同的折射率分布的石英玻璃基板管来提高制造复合折射率分布的方法的生产率 在径向上进行掺杂，将由合成石英玻璃制成的芯玻璃引入衬底管中并用套管覆盖衬底管。 还提供了一种适用于其的基底管，该管需要较少的核心玻璃材料用于生产预成型件，无论是在内部沉积期间还是在棒状管技术中用于芯玻璃棒。 关于该方法，根据本发明提出了使用通过多孔管状SiO 2空白玻璃化而获得的衬底管，衬底管设置有芯玻璃层，其为 在玻璃化之前加入到SiO 2的坯料的第一径向部分的第一掺杂剂增加了石英玻璃的折射率。 根据本发明的衬底管具有不同掺杂的径向区域，由此其包含折射率至少为1.459的芯玻璃层。

公开(公告)号：US5429653A

公开(公告)日：1995-07-04

申请号：US961696

申请日：1993-01-29

申请人： Helmut Leber ,  Hartwig Schaper ,  Norbert Treber ,  Gerhart Vilsmeier ,  Klaus Reimann

发明人： Helmut Leber ,  Hartwig Schaper ,  Norbert Treber ,  Gerhart Vilsmeier ,  Klaus Reimann

IPC分类号： C03B23/047 ,  C03B37/012 ,  C03B23/04 ,  C03B23/11

CPC分类号： C03B37/01225 ,  C03B23/047 ,  Y02P40/57

摘要： Starting from a process for producing a rod-like preform, in particular for optical fibers, in which a tubular blank whose refractive index changes, viewed in the radial direction is fed to a heating zone, is softened there, and in the softened state is shaped to give the preform, a method is described for producing preforms which are hyperpure and low in defects, in which the blank used is one whose refractive index decreases, viewed in the radial direction, from the outside inwards, starting from at least one interface which is at a sufficient distance from the outer surface of the blank, of which that part which has been softened in the heating zone is introverted apart from an outer skin, and by which the preform is formed in the longitudinal axis of the tubular blank, counter to the direction in which the latter is fed to the heating zone, and in which the remaining outer skin is drawn off as a rod in the feed direction of the blank.

摘要翻译： 从制造棒状预成型体的方法，特别是对于光纤而言，其中从径向观察的折射率变化的管状坯料被供给到加热区，在那里软化，并且在软化状态是 形成为预成型件的方法，描述了一种用于制造超纯钛和低缺陷的预成型件的方法，其中使用的坯料是从外部向内从折射率减小的折射率从外部向内从起始于至少一个界面 其与坯料的外表面相距足够的距离，其中已经在加热区中被软化的部分向内伸出外表皮，并且预制件在管坯的纵向轴线上形成， 与后者被供给到加热区的方向相反，并且其中剩余的外皮作为沿着坯料的进给方向的杆被拉出。

公开(公告)号：US20100186453A1

公开(公告)日：2010-07-29

申请号：US12730784

申请日：2010-03-24

申请人： Gerhard Schötz ,  Karsten Bräuer ,  Michael Hünermann ,  Richard Schmidt ,  Heinz Fabian ,  Norbert Treber

发明人： Gerhard Schötz ,  Karsten Bräuer ,  Michael Hünermann ,  Richard Schmidt ,  Heinz Fabian ,  Norbert Treber

IPC分类号： C03B37/018

CPC分类号： C03B37/01291 ,  C03B37/01211 ,  C03B37/01426 ,  C03B37/01466 ,  C03B2201/12 ,  Y02P40/57

摘要： In a known method for the production of a blank mold for optical fibers, a fluorine-doped SiO2 enveloping glass is produced on a core glass cylinder that rotates about its longitudinal axis, wherein a silicon-containing starting substance is fed to a plasma burner, said substance is then oxidized in a plasma flame assigned to the plasma burner to obtain SiO2 particles, the SiO2 particles are deposited by layers on the enveloping surface of the cylinder of the core glass cylinder in the presence of fluorine and sintered into the enveloping glass. The invention aims at providing an economical method, which builds upon the above-mentioned method, in order to produce a blank mold from which optical multi-mode fibers (52) can be obtained. In comparison with fibers (51) produced according to standard methods, said optical multi-mode fibers are characterized by high initial transmission in the UV wavelength range and good resistance with respect to brief UV radiation, more particularly in the 210-300 nm wavelength range. According to the invention, a plasma flame that irradiates an ultraviolet light having a wavelength of 214 nm with an intensity of at least 0.9 μW—determined on the basis of plasma flame intensity measurement—is used for the formation and deposition of the SiO2 particles on the core glass.

摘要翻译： 在用于生产光纤空白模具的已知方法中，在围绕其纵向轴线旋转的芯玻璃圆筒上产生氟掺杂的SiO 2包封玻璃，其中含硅原料被供给到等离子体燃烧器， 然后将所述物质在分配给等离子体燃烧器的等离子体火焰中氧化以获得SiO 2颗粒，SiO 2颗粒在氟存在下通过层沉积在芯玻璃圆筒的圆筒的包络表面上并烧结到包封玻璃中。 本发明的目的在于提供一种以上述方法为基础的经济的方法，以便制造可得到光学多模光纤（52）的坯模。 与根据标准方法生产的纤维（51）相比，所述光学多模光纤的特征在于在UV波长范围内的初始透射率高，并且对于短暂的UV辐射具有良好的电阻，更特别地在210-300nm波长范围 。 根据本发明，使用基于等离子体火焰强度测量来测量具有至少0.9μW的强度的波长为214nm的紫外光的等离子体火焰，用于SiO 2颗粒的形成和沉积 核心玻璃。

公开(公告)号：US07716952B2

公开(公告)日：2010-05-18

申请号：US10552539

申请日：2004-04-06

申请人： Gerhard Schötz ,  Karsten Bräuer ,  Heinz Fabian ,  Norbert Treber

发明人： Gerhard Schötz ,  Karsten Bräuer ,  Heinz Fabian ,  Norbert Treber

IPC分类号： C03B37/075 ,  C03B37/07 ,  C03B37/018 ,  C03C13/00 ,  C03C25/00 ,  G02B6/00 ,  G01N23/00

CPC分类号： C03B37/01291 ,  C03B37/01211 ,  C03B37/01426 ,  C03B37/01466 ,  C03B2201/12 ,  Y02P40/57

摘要： In a known method for the production of a blank mold for optical fibers, a fluorine-doped SiO2 enveloping glass is produced on a core glass cylinder that rotates about its longitudinal axis, wherein a silicon-containing starting substance is fed to a plasma burner, said substance is then oxidized in a plasma flame assigned to the plasma burner to obtain SiO2 particles, the SiO2 particles are deposited by layers on the enveloping surface of the cylinder of the core glass cylinder in the presence of fluorine and sintered into the enveloping glass. The invention aims at providing an economical method, which builds upon the above-mentioned method, in order to produce a blank mold from which optical multi-mode fibers (52) can be obtained. In comparison with fibers (51) produced according to standard methods, said optical multi-mode fibers are characterized by high initial transmission in the UV wavelength range and good resistance with respect to brief UV radiation, more particularly in the 210-300 nm wavelength range. According to the invention, a plasma flame that irradiates an ultraviolet light having a wavelength of 214 nm with an intensity of at least 0.9 ?W—determined on the basis of plasma flame intensity measurement—is used for the formation and deposition of the SiO2 particles on the core glass.

摘要翻译： 在用于生产光纤空白模具的已知方法中，在围绕其纵向轴线旋转的芯玻璃圆筒上产生氟掺杂的SiO 2包封玻璃，其中含硅原料被供给到等离子体燃烧器， 然后将所述物质在分配给等离子体燃烧器的等离子体火焰中氧化以获得SiO 2颗粒，SiO 2颗粒在氟存在下通过层沉积在芯玻璃圆筒的圆筒的包络表面上并烧结到包封玻璃中。 本发明的目的在于提供一种以上述方法为基础的经济的方法，以便制造可得到光学多模光纤（52）的坯模。 与根据标准方法生产的纤维（51）相比，所述光学多模光纤的特征在于在UV波长范围内的初始透射率高，并且对于短暂的UV辐射具有良好的电阻，更特别地在210-300nm波长范围 。 根据本发明，使用基于等离子体火焰强度测量来测定波长为214nm的强度至少为0.9≤W的紫外光的等离子体火焰，用于SiO 2颗粒的形成和沉积 在核心玻璃上。

公开(公告)号：US20060213228A1

公开(公告)日：2006-09-28

申请号：US10552539

申请日：2004-04-06

申请人： Gerhard Schotz ,  Karsten Brauer ,  Michael Hunermann ,  Richard Schmidt ,  Heinz Fabian ,  Norbert Treber

发明人： Gerhard Schotz ,  Karsten Brauer ,  Michael Hunermann ,  Richard Schmidt ,  Heinz Fabian ,  Norbert Treber

IPC分类号： C03B37/07 ,  C03B37/018

CPC分类号： C03B37/01291 ,  C03B37/01211 ,  C03B37/01426 ,  C03B37/01466 ,  C03B2201/12 ,  Y02P40/57

摘要： In a known method for the production of a blank mold for optical fibers, a fluorine-doped SiO2 enveloping glass is produced on a core glass cylinder that rotates about its longitudinal axis, wherein a silicon-containing starting substance is fed to a plasma burner, said substance is then oxidized in a plasma flame assigned to the plasma burner to obtain SiO2 particles, the SiO2 particles are deposited by layers on the enveloping surface of the cylinder of the core glass cylinder in the presence of fluorine and sintered into the enveloping glass. The invention aims at providing an economical method, which builds upon the above-mentioned method, in order to produce a blank mold from which optical multi-mode fibers (52) can be obtained. In comparison with fibers (51) produced according to standard methods, said optical multi-mode fibers are characterized by high initial transmission in the UV wavelength range and good resistance with respect to brief UV radiation, more particularly in the 210-300 nm wavelength range. According to the invention, a plasma flame that irradiates an ultraviolet light having a wavelength of 214 nm with an intensity of at least 0.9 ?W—determined on the basis of plasma flame intensity measurement—is used for the formation and deposition of the SiO2 particles on the core glass.

摘要翻译： 在用于生产光纤空白模具的已知方法中，在围绕其纵向轴线旋转的芯玻璃圆筒上产生氟掺杂的SiO 2包封玻璃，其中含硅起始 将物质进料到等离子体燃烧器，然后将所述物质在分配给等离子体燃烧器的等离子体火焰中氧化以获得SiO 2颗粒，SiO 2颗粒通过层 在氟化物存在下在芯玻璃圆筒的圆筒的包络表面上，并烧结到包络玻璃中。 本发明的目的在于提供一种以上述方法为基础的经济的方法，以便制造可得到光学多模光纤（52）的坯模。 与根据标准方法生产的纤维（51）相比，所述光学多模光纤的特征在于在UV波长范围内的初始透射率高，并且对于短暂的UV辐射具有良好的电阻，更特别地在210-300nm波长范围 。 根据本发明，使用基于等离子体火焰强度测量来测量具有至少0.9≤W的强度的波长为214nm的紫外光的等离子体火焰，用于形成和沉积SiO 2， 核心玻璃上的SUB> 2 颗粒。