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1.发明申请Non-aqueous electrolyte for secondary batteries and non-aqueous electrolyte secondary batteries using the same 审中-公开用于二次电池的非水电解质和使用其的非水电解质二次电池公开(公告)号：US20050233222A1
公开(公告)日：2005-10-20
申请号：US11077504
申请日：2005-03-11
IPC分类号： H01M10/05 , H01M4/587 , H01M6/16 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/40 , H01M4/58
CPC分类号： H01M10/0568 , H01M4/587 , H01M10/0525 , H01M10/0569 , H01M2300/0037
摘要： Charge-discharge characteristics are improved in a non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte containing a phosphoric ester compound as a solvent. In a non-aqueous electrolyte for secondary batteries containing a phosphoric ester compound, a lithium salt having an oxalato complex as an anion is contained as a solute. Preferably, the non-aqueous electrolyte contains lithium bis(oxalato)borate at a concentration of 0.01 to 0.2 mol/L with respect to the solvent, and more preferably, the non-aqueous electrolyte also contains vinylene carbonate.
摘要翻译： 在包含正极，负极和含有磷酸酯化合物作为溶剂的非水电解质的非水电解质二次电池中，充放电特性得到改善。 在含有磷酸酯化合物的二次电池用非水电解质中，作为阴离子含有作为阴离子的草酸盐络合物的锂盐。 优选地，非水电解质含有相对于溶剂浓度为0.01〜0.2mol / L的双（草酸）硼酸锂，更优选非水电解质也含有碳酸亚乙烯酯。
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公开(公告)号：US20050196674A1
公开(公告)日：2005-09-08
申请号：US11064112
申请日：2005-02-23
IPC分类号： H01M4/131 , H01M4/1391 , H01M4/36 , H01M4/525 , H01M10/05 , H01M10/052 , H01M10/0566 , H01M4/48 , H01M4/58
CPC分类号： H01M10/0525 , H01M4/0471 , H01M4/131 , H01M4/136 , H01M4/366 , H01M4/485 , H01M4/525 , H01M4/5825
摘要： Cycle performance is improved without degrading initial efficiency of a non-aqueous electrolyte secondary battery that includes a positive electrode, a negative electrode, a non-aqueous electrolyte containing a solute and a solvent, the positive electrode including a positive electrode active material made of a lithium-containing transition metal oxide that contains lithium and cobalt and has a layered structure. The lithium-containing transition metal oxide is at least partially covered with a surface-treatment layer containing a phosphate compound represented by the chemical formula M1POk, where M1 is at least one element that can have a valency of 3 and k is an integer in a range of 2 to 4, and the lithium-containing transition metal oxide contains a group IVA element M2 and a group IIA element M3 of the periodic table.
摘要翻译： 提高循环性能而不降低包含正极，负极，含有溶质的非水电解质和溶剂的非水电解质二次电池的初期效率，所述正极包含由 含有锂和钴的含锂过渡金属氧化物并具有层状结构。 所述含锂过渡金属氧化物至少部分被表面处理层覆盖，所述表面处理层含有由化学式M 1 PO 3表示的磷酸盐化合物，其中M 1 是至少一种可以具有3价的元素，k是2至4的整数，含锂过渡金属氧化物含有IVA族元素M 2， / SUP>和元素周期表的IIA族元素M 3。
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公开(公告)号：US07335446B2
公开(公告)日：2008-02-26
申请号：US11064112
申请日：2005-02-23
IPC分类号： H01M4/58
CPC分类号： H01M10/0525 , H01M4/0471 , H01M4/131 , H01M4/136 , H01M4/366 , H01M4/485 , H01M4/525 , H01M4/5825
摘要： Cycle performance is improved without degrading initial efficiency of a non-aqueous electrolyte secondary battery that includes a positive electrode, a negative electrode, a non-aqueous electrolyte containing a solute and a solvent, the positive electrode including a positive electrode active material made of a lithium-containing transition metal oxide that contains lithium and cobalt and has a layered structure. The lithium-containing transition metal oxide is at least partially covered with a surface-treatment layer containing a phosphate compound represented by the chemical formula M1POk, where M1 is at least one element that can have a valency of 3 and k is an integer in a range of 2 to 4, and the lithium-containing transition metal oxide contains a group IVA element M2 and a group IIA element M3 of the periodic table.
摘要翻译： 提高循环性能而不降低包含正极，负极，含有溶质的非水电解质和溶剂的非水电解质二次电池的初期效率，所述正极包含由 含有锂和钴的含锂过渡金属氧化物并具有层状结构。 所述含锂过渡金属氧化物至少部分被表面处理层覆盖，所述表面处理层含有由化学式M 1 PO 3表示的磷酸盐化合物，其中M 1 是至少一种可以具有3价的元素，k是2至4的整数，含锂过渡金属氧化物含有IVA族元素M 2， / SUP>和元素周期表的IIA族元素M 3。
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公开(公告)号：US06869546B1
公开(公告)日：2005-03-22
申请号：US09576211
申请日：2000-05-23
申请人： Katsunori Yanagida , Atsushi Yanai , Takeshi Maeda , Yoshinori Kida , Atsuhiro Funahashi , Toshiyuki Nohma , Ikuo Yonezu
发明人： Katsunori Yanagida , Atsushi Yanai , Takeshi Maeda , Yoshinori Kida , Atsuhiro Funahashi , Toshiyuki Nohma , Ikuo Yonezu
CPC分类号： H01M4/583 , H01B1/04 , H01M4/13 , H01M4/366 , H01M10/0525 , H01M2004/021
摘要： For us in nonaqueous electrolyte secondary cells, the invention provides an electrode which comprises a first carbon material serving as a core material, and a second carbon material coating the first carbon material over the surface thereof and containing boron. When used as an active substance for negative electrode to provide a nonaqueous electrolyte secondary cell, the electrode diminishes the reduction of the cell capacity that would result if the cell is allowed to store, giving improved storage characteristics to the cell.
摘要翻译： 对于我们在非水电解质二次电池中，本发明提供了一种电极，其包括用作芯材料的第一碳材料和在其表面上涂覆第一碳材料并含有硼的第二碳材料。 当用作负极的活性物质以提供非水电解质二次电池时，电极减小了如果电池被允许存储而导致的电池容量的降低，给电池提供改进的储存特性。
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公开(公告)号：US06620552B2
公开(公告)日：2003-09-16
申请号：US09841033
申请日：2001-04-25
申请人： Yoshinori Kida , Katsunori Yanagida , Atsushi Yanai , Atsuhiro Funahashi , Toshiyuki Nohma , Ikuo Yonezu
发明人： Yoshinori Kida , Katsunori Yanagida , Atsushi Yanai , Atsuhiro Funahashi , Toshiyuki Nohma , Ikuo Yonezu
IPC分类号： H01M1040
CPC分类号： H01M4/661 , H01M4/666 , H01M10/04 , H01M10/052 , H01M10/0567 , H01M10/0568
摘要： A lithium secondary battery according to the present invention includes a positive electrode in which an aluminum foil containing manganese is used as a current collector, a negative electrode, and a non-aqueous electrolyte solution formed by dissolving lithium salt in a non-aqueous solvent wherein divalent manganese salt is added to said non-aqueous electrolyte solution.
摘要翻译： 根据本发明的锂二次电池包括其中使用含有锰的铝箔作为集电体的正极，负极和通过将锂盐溶解在非水溶剂中而形成的非水电解质溶液，其中 向所述非水电解液中加入二价锰盐。
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公开(公告)号：US20050053838A1
公开(公告)日：2005-03-10
申请号：US10897409
申请日：2004-07-23
IPC分类号： H01M4/131 , H01M4/525 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0569 , H01M4/52 , H01M10/40
CPC分类号： H01M10/052 , H01M4/131 , H01M4/525 , H01M10/0569
摘要： Storage performance in a charged state is improved in a non-aqueous electrolyte battery that contains 10 volume % or more of γ-butyrolactone, which is highly safe and reliable, as a solvent. A non-aqueous electrolyte secondary battery has a positive electrode containing a positive electrode active material composed of a lithium-containing transition metal oxide containing lithium and cobalt, a negative electrode, and a non-aqueous electrolyte solution composed of a solute and a solvent. The solvent contains 10 volume % or more of γ-butyrolactone with respect to the total solvent, and the positive electrode active material contains a Group IVA element and a Group IIA element of the periodic table.
摘要翻译： 作为溶剂，含有10体积％以上的γ-丁内酯的非水电解质电池的充电状态的保存性能得到改善，其是高度安全和可靠的。 非水电解质二次电池具有含有由含锂和钴的含锂过渡金属氧化物，负极和由溶质和溶剂构成的非水电解质溶液构成的正极活性物质的正极。 相对于总溶剂，溶剂含有10体积％以上的γ-丁内酯，正极活性物质含有周期表的IVA族元素和IIA族元素。
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公开(公告)号：US07452636B2
公开(公告)日：2008-11-18
申请号：US10792281
申请日：2004-03-04
IPC分类号： H01M10/40
CPC分类号： H01M10/0525 , H01M4/133 , H01M4/587 , H01M10/0567 , H01M10/0569
摘要： A lithium secondary battery including a positive electrode, a negative electrode including a carbon material as an active material, and a nonaqueous electrolyte comprising a solute dissolved in a nonaqueous solvent in which γ-butyrolactone is the main solvent, wherein the carbon material has a ratio (ID/IG) of a Raman spectrum intensity (a peak intensity ratio) (R) obtained by Raman spectroscopy of 0.2 or greater, and the nonaqueous electrolyte includes at least 0.1 part by weight of vinylene carbonate and at least 0.1 part by weight of vinyl ethylene carbonate in 100 parts by weight of the nonaqueous electrolyte.
摘要翻译： 一种锂二次电池，包括正极，负极包含碳材料作为活性材料，以及非水电解质，其包含溶解在γ-丁内酯为主要溶剂的非水溶剂中的溶质，其中，所述碳材料的比例 （拉曼光谱学获得的拉曼光谱强度（峰值强度比）（R））为0.2以上的非水电解质，其中，非水电解质包含：（A / D） 至少0.1重量份的碳酸亚乙烯酯和至少0.1重量份的乙烯基碳酸亚乙酯在100重量份的非水电解质中。
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公开(公告)号：US06537697B2
公开(公告)日：2003-03-25
申请号：US09737936
申请日：2000-12-18
申请人： Yoshinori Kida , Katsunori Yanagida , Atsushi Yanai , Atsuhiro Funahashi , Toshiyuki Nohma , Ikuo Yonezu
发明人： Yoshinori Kida , Katsunori Yanagida , Atsushi Yanai , Atsuhiro Funahashi , Toshiyuki Nohma , Ikuo Yonezu
IPC分类号： H01M1040
CPC分类号： H01M10/0568 , H01M6/168 , H01M6/40 , H01M10/052 , H01M2300/0037
摘要： The lithium secondary battery of this invention uses a nonaqueous electrolyte including lithium tetrakis(pentafluorophenyl)borate as a part or whole of an electrolytic salt. As a result, the lithium secondary battery exhibits better charge-discharge cycle performance than a lithium secondary battery using a conventional lithium salt as the electrolytic salt.
摘要翻译： 本发明的锂二次电池使用包含四（五氟苯基）硼酸锂的非水电解质作为电解盐的一部分或全部。 结果，与使用常规锂盐作为电解盐的锂二次电池相比，锂二次电池表现出更好的充放电循环性能。
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9.发明申请公开(公告)号：US20090181308A1
公开(公告)日：2009-07-16
申请号：US12318916
申请日：2009-01-12
申请人： Takanobu Chiga , Katsunori Yanagida
发明人： Takanobu Chiga , Katsunori Yanagida
CPC分类号： H01M10/0568 , H01M4/364 , H01M4/366 , H01M4/38 , H01M4/525 , H01M10/052 , Y10T29/49108
摘要： A nonaqueous electrolyte secondary battery is obtained which shows good cycle characteristics even when charged to a high voltage.The nonaqueous electrolyte secondary battery has a positive electrode containing a positive active material, a negative electrode containing a negative active material and a nonaqueous electrolyte, wherein a lithium-containing transition metal oxide having a layered structure is contained in the positive electrode as the positive active material, an additive which is reductively decomposed in the range of +3.0-1.3 V versus metallic lithium is contained in the nonaqueous electrolyte, and the battery after assembled is overdischarged until a potential of the positive electrode falls down to a reductive potential of the additive or below.
摘要翻译： 得到即使充电到高电压也显示良好的循环特性的非水电解质二次电池。 非水电解质二次电池具有包含正极活性物质的正极，含有负极活性物质的负极和非水电解质，其中，在正极中含有层状结构的含锂过渡金属氧化物作为正极活性物质 材料中，在非水电解质中含有相对于金属锂在+ 3.0-1.3V范围内还原分解的添加剂，组装后的电池过放电直到正极的电位下降至添加剂的还原电位 或以下。
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10.发明授权公开(公告)号：US06235426B1
公开(公告)日：2001-05-22
申请号：US09398209
申请日：1999-09-17
申请人： Atsushi Yanai , Kazunari Ohkita , Katsunori Yanagida , Takeshi Maeda , Atsuhiro Funahashi , Yoshito Chikano , Toshiyuki Nohma , Ikuo Yonezu , Koji Nishio
发明人： Atsushi Yanai , Kazunari Ohkita , Katsunori Yanagida , Takeshi Maeda , Atsuhiro Funahashi , Yoshito Chikano , Toshiyuki Nohma , Ikuo Yonezu , Koji Nishio
IPC分类号： H01M466
CPC分类号： H01M10/4235 , H01M2/263 , H01M4/02 , H01M4/64 , H01M6/10 , H01M10/052 , H01M2200/106
摘要： A nonaqueous electrolyte secondary cell having a rolled-up electrode unit housed in a cell can and comprising a positive electrode and a negative electrode each formed by coating a surface of a striplike current collector with an electrode material. According to a first embodiment, the current collector of at least one of the positive electrode and the negative electrode comprises a plurality of current collector pieces 42 arranged along one direction and a PTC element 5 interconnecting each pair of adjacent current collector pieces 42. Alternatively with a second embodiment, at least one of the positive electrode and the negative electrode comprises a PTC element held between opposed faces of an uncoated portion of the current collector thereof and a base end portion of a current collector tab. The PTC element serves to prevent continuous occurrence of a current in excess of a predetermined value and realizes a high energy density.
摘要翻译： 具有容纳在电池中的卷绕电极单元的非水电解质二次电池可以包括通过用电极材料涂覆带状集电体的表面而形成的正极和负极。 根据第一实施例，正电极和负电极中的至少一个的集电器包括沿着一个方向布置的多个集电器片42和连接每对相邻集电器片42的PTC元件5。 在第二实施例中，正电极和负电极中的至少一个包括保持在其集电器的未涂覆部分的相对面和集电极片的基端部之间的PTC元件。 PTC元件用于防止超过预定值的电流的连续发生并且实现高能量密度。
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