摘要:
A lithium secondary battery including a positive electrode, a negative electrode including a carbon material as an active material, and a nonaqueous electrolyte comprising a solute dissolved in a nonaqueous solvent in which γ-butyrolactone is the main solvent, wherein the carbon material has a ratio (ID/IG) of a Raman spectrum intensity (a peak intensity ratio) (R) obtained by Raman spectroscopy of 0.2 or greater, and the nonaqueous electrolyte includes at least 0.1 part by weight of vinylene carbonate and at least 0.1 part by weight of vinyl ethylene carbonate in 100 parts by weight of the nonaqueous electrolyte.
摘要:
For us in nonaqueous electrolyte secondary cells, the invention provides an electrode which comprises a first carbon material serving as a core material, and a second carbon material coating the first carbon material over the surface thereof and containing boron. When used as an active substance for negative electrode to provide a nonaqueous electrolyte secondary cell, the electrode diminishes the reduction of the cell capacity that would result if the cell is allowed to store, giving improved storage characteristics to the cell.
摘要:
A lithium secondary battery according to the present invention includes a positive electrode in which an aluminum foil containing manganese is used as a current collector, a negative electrode, and a non-aqueous electrolyte solution formed by dissolving lithium salt in a non-aqueous solvent wherein divalent manganese salt is added to said non-aqueous electrolyte solution.
摘要:
Storage performance in a charged state is improved in a non-aqueous electrolyte battery that contains 10 volume % or more of γ-butyrolactone, which is highly safe and reliable, as a solvent. A non-aqueous electrolyte secondary battery has a positive electrode containing a positive electrode active material composed of a lithium-containing transition metal oxide containing lithium and cobalt, a negative electrode, and a non-aqueous electrolyte solution composed of a solute and a solvent. The solvent contains 10 volume % or more of γ-butyrolactone with respect to the total solvent, and the positive electrode active material contains a Group IVA element and a Group IIA element of the periodic table.
摘要:
The lithium secondary battery of this invention uses a nonaqueous electrolyte including lithium tetrakis(pentafluorophenyl)borate as a part or whole of an electrolytic salt. As a result, the lithium secondary battery exhibits better charge-discharge cycle performance than a lithium secondary battery using a conventional lithium salt as the electrolytic salt.
摘要:
A nonaqueous electrolyte secondary cell having a rolled-up electrode unit housed in a cell can and comprising a positive electrode and a negative electrode each formed by coating a surface of a striplike current collector with an electrode material. According to a first embodiment, the current collector of at least one of the positive electrode and the negative electrode comprises a plurality of current collector pieces 42 arranged along one direction and a PTC element 5 interconnecting each pair of adjacent current collector pieces 42. Alternatively with a second embodiment, at least one of the positive electrode and the negative electrode comprises a PTC element held between opposed faces of an uncoated portion of the current collector thereof and a base end portion of a current collector tab. The PTC element serves to prevent continuous occurrence of a current in excess of a predetermined value and realizes a high energy density.
摘要:
The present invention provides a positive electrode of a nonaqueous electrolyte secondary cell which is prepared using an active substance containing a composition of LiNiaCobMcO2 (a+b+c=1;0≦c≦0.5) wherein M is at least one metal selected from among Mn, Fe, Zn, Ti, Cr, Mg, Al, Cu, or Ga and a composition of AlX(SO4)2 wherein X is at least one material selected from among Na, Rb, Cs, or NH4. This enables the secondary cell to diminish the reduction of a cell capacity when allowed to store and thus the storage characteristics of the secondary cell is improved.
摘要翻译:本发明提供一种非水电解质二次电池的正极,其使用含有LiNiaCobMcO2(a + b + c = 1; 0 <= c <0.5)的组成的活性物质制备,其中M为至少一种选择的金属 Mn,Fe,Zn,Ti,Cr,Mg,Al,Cu或Ga中的一种以及Al(SO 4)2的组成,其中X为选自Na,Rb,Cs或NH 4中的至少一种。 这使得二次电池在允许存储时能够减小电池容量的降低,从而提高二次电池的存储特性。
摘要:
A nonaqueous electrolyte secondary cell having a rolled-up electrode unit housed in a cell can and comprising a positive electrode and a negative electrode each formed by coating a surface of a striplike current collector with an electrode material. According to a first embodiment, the current collector of at least one of the positive electrode and the negative electrode comprises a plurality of current collector pieces 42 arranged along one direction and a PTC element 5 interconnecting each pair of adjacent current collector pieces 42. Alternatively with a second embodiment, at least one of the positive electrode and the negative electrode comprises a PTC element held between opposed faces of an uncoated portion of the current collector thereof and a base end portion of a current collector tab. The PTC element serves to prevent continuous occurrence of a current in excess of a predetermined value and realizes a high energy density.
摘要:
Storage performance in a charged state is improved with a non-aqueous electrolyte secondary battery using gamma-butyrolactone as a solvent. A non-aqueous electrolyte secondary battery includes a positive electrode (2) containing a positive electrode active material including a lithium-containing transition metal oxide; a negative electrode (1) containing a negative electrode active material capable of intercalating and deintercalating lithium; and a non-aqueous electrolyte including a solute and a solvent; wherein the solvent contains 50 volume % or more of gamma-butyrolactone with respect to the total volume of the solvent, and the positive electrode active material contains a phosphate salt M1PO4, where M1 is a metal element capable of having a valency of 3.
摘要翻译:使用γ-丁内酯作为溶剂的非水电解质二次电池改善了带电状态下的储存性能。 非水电解质二次电池包括含有含锂过渡金属氧化物的正极活性物质的正极(2) 含有能够嵌入和脱嵌锂的负极活性物质的负极(1) 和包含溶质和溶剂的非水电解质; 其中所述溶剂相对于所述溶剂的总体积含有50体积%以上的γ-丁内酯,所述正极活性物质含有磷酸盐M 1 PO 4 >,其中M 1是能够具有3价的金属元素。
摘要:
Storage performance in a charged state is improved with a non-aqueous electrolyte secondary battery using gamma-butyrolactone as a solvent. A non-aqueous electrolyte secondary battery includes a positive electrode (2) containing a positive electrode active material including a lithium-containing transition metal oxide; a negative electrode (1) containing a negative electrode active material capable of intercalating and deintercalating lithium; and a non-aqueous electrolyte including a solute and a solvent; wherein the solvent contains 50 volume % or more of gamma-butyrolactone with respect to the total volume of the solvent, and the positive electrode active material contains a phosphate salt M1PO4, where M1 is a metal element capable of having a valency of 3.
摘要翻译:使用γ-丁内酯作为溶剂的非水电解质二次电池改善了带电状态下的储存性能。 非水电解质二次电池包括含有含锂过渡金属氧化物的正极活性物质的正极(2) 含有能够嵌入和脱嵌锂的负极活性物质的负极(1) 和包含溶质和溶剂的非水电解质; 其中所述溶剂相对于所述溶剂的总体积含有50体积%以上的γ-丁内酯,所述正极活性物质含有磷酸盐M 1 PO 4 >,其中M 1是能够具有3价的金属元素。