Abstract:
Provided are a method of preparing a vinyl chloride-based polymer composite, a vinyl chloride-based polymer composite, and a vinyl chloride-based polymer composite composition including the composite, the method including: a first step of performing bulk polymerization of vinyl chloride-based monomers; and a second step of recovering unreacted vinyl chloride-based monomers after the completion of the bulk polymerization and obtaining a vinyl chloride-based polymer composite, wherein polyvinyl alcohol is added in at least one step of the first step and the second step, and the polyvinyl alcohol is added in an amount of 0.003 parts by weight to 0.500 parts by weight based on a total of 100 parts by weight of the vinyl chloride-based monomers.
Abstract:
The present invention relates to a method of preparing a vinyl chloride-based polymer, which includes inducing the nucleation of particles by adding a mercaptan-based chain transfer agent to a monomer composition including a vinyl chloride-based monomer and a preliminary polymerization initiator (preliminary polymerization); and preparing a polymer by mixing a vinyl chloride-based monomer and the particle nuclei and adding a main polymerization initiator (main polymerization). In the preparation method, a vinyl chloride-based polymer having a uniform molecular weight distribution and a desired number average molecular weight may be provided by controlling a degree of polymerization of a vinyl chloride-based polymer prepared in such a way that dispersibility is ensured by adjusting the point of time to add the mercaptan-based chain transfer agent to the point of time to reach a specific conversion rate of the preliminary polymerization.
Abstract:
The present invention relates to a method for preparing a vinyl chloride-based polymer, including: bulk polymerizing a vinyl chloride-based monomer in a polymerization reactor to prepare a vinyl chloride-based polymer; and adding water and vapor to the polymerization reactor, and heating to remove an unreacted vinyl chloride-based monomer, wherein an addition amount of the water is 0.500 to 5.000 parts by weight based on 100 parts by weight of the vinyl chloride-based polymer.
Abstract:
Provided is a method of preparing a vinyl chloride-based polymer composite, which includes: bulk-polymerizing vinyl chloride-based monomers to prepare a vinyl chloride-based polymer; and preparing a vinyl chloride-based polymer composite including the vinyl chloride-based polymer and polyvinylpyrrolidone.
Abstract:
A method of preparing a vinyl chloride polymer is provided. The method includes: preparing a mixture by adding an alcohol to a vinyl chloride polymer slurry (S1); separating a waste liquid from the mixture to obtain a vinyl chloride polymer (S2); and adding at least a portion of the separated waste liquid to the mixture (S3); wherein a content of the at least a portion of the separated waste liquid added in Step S3 is in the range of 33.0 to 35.0 parts by weight with respect to 100 parts by weight of the mixture.
Abstract:
The present disclosure provides a method of preparing a vinyl chloride-based polymer, and the method provides excellent productivity while having reduced amount of a volatile organic compound generated so as to provide the vinyl chloride-based polymer suitable for an eco-friendly material, and improved foaming and viscosity properties of a plastisol including the prepared polymer, by adding a carbonate-based metal salt and a transition metal catalyst together, and controlling input time and amount of the transition metal catalyst.
Abstract:
The present invention relates to a method of preparing a vinyl chloride-based polymer, which may prepare a vinyl chloride-based polymer with excellent surface properties by adjusting a foam level generated during a polymerization reaction to an appropriate value, a vinyl chloride-based polymer prepared thereby, and an apparatus for preparing a vinyl chloride-based polymer which may prepare the vinyl chloride-based polymer. The method of preparing a vinyl chloride-based polymer according to the present invention may prepare a vinyl chloride-based polymer with excellent surface properties, for example, fewer occurrences of fish-eyes and excellent transparency, by performing a polymerization reaction while maintaining the level of a foam generated during the polymerization reaction at an appropriate value.
Abstract:
Disclosed are a chloroethylene-based nanocomposite composition and a method of preparing the same. More particularly, disclosed are a chloroethylene-based nanocomposite composition comprising a chloroethylene-based resin; a nanoclay comprising a coupling agent bonded thereto; and at least one polymer selected from unsaturated organic acid-based resins or polycarboxylic acid-based resins, and a method of preparing the same.According to the present disclosure, a uniformly dispersed water dispersion suspension may be provided by enhancing water dispersion effects of the nanoclay, and superior tensile strength may be exhibited by using the uniformly dispersed water dispersion suspension in chloroethylene-based suspension polymerization, and a chloroethylene nanocomposite having superior transparency may be provided.
Abstract:
The present invention relates to a method of preparing a vinyl chloride-based polymer in a polymerization device including: a polymerization reactor; a reflux condenser connected to the polymerization reactor; and a recovery pipe connected to the reflux condenser, the method including: initiating a polymerization by adding a first vinyl chloride-based monomer and an initiator into the polymerization reactor; and recovering a second vinyl chloride-based monomer from the polymerization reactor through the recovery pipe, and performing a polymerization while adding a third vinyl chloride-based monomer into the polymerization reactor, wherein a content of the initiator is 0.105 to 0.110 parts by weight based on 100 parts by weight of a content of the first vinyl chloride-based monomer.
Abstract:
The present invention relates to a method for preparing a vinyl chloride-based polymer, to a vinyl chloride-based polymer, and to a vinyl chloride-based polymer composition comprising same, the method comprising: a first step of bulk polymerizing a vinyl chloride-based monomer under the presence of an initiator; and a second step of obtaining a vinyl chloride-based polymer after completing the bulk polymerization, wherein a phosphite is input in the first step.