Polymer and preparation method and application thereof

    公开(公告)号:US11407889B2

    公开(公告)日:2022-08-09

    申请号:US17150831

    申请日:2021-01-15

    摘要: Provided are a polymer having ultraviolet absorption functionality and preparation method thereof; specifically, three monomers having different ultraviolet absorption bands are used for copolymerization, achieving a significant expansion of the ultraviolet absorption range and achieving the effect of full-band ultraviolet shielding. The obtained polymer film has strong visible light transmittance, fluorescence, easy processing, excellent stability, and remarkable ultraviolet shielding performance, and can be broadly applied in such areas as aviation, construction, agriculture, and optical devices.

    PROCESS FOR REMOVING VOLATILE COMPONENTS FROM AN OLEFIN POLYMER AND ARTICLE OBTAINED

    公开(公告)号:US20210095058A1

    公开(公告)日:2021-04-01

    申请号:US16499382

    申请日:2018-05-25

    申请人: Borealis AG

    摘要: The invention relates to a process for removal of volatile components from an olefin polymer, the process carried out in an extruder comprising at least one vacuum degassing zone, said process comprising the steps of: (a) introducing a stream of an olefin polymer into the extruder; (b) extruding the olefin polymer in the extruder at a temperature which is higher than the melting temperature of the olefin polymer but lower than the decomposition temperature of the olefin polymer, thereby producing an olefin polymer melt having reduced amount of volatile components, wherein the process in the extruder has a residence time distribution broadness (σ2) in the range of 800 to 4000 as define by equation (1) wherein: σ2 is the residence time distribution broadness, T is the mean residence time, t is the interval of residence time a fluid element of the olefin polymer spends in the extruder, E(t) is the residence time distribution function, and wherein the process optionally comprises a step (c) where the melt of the olefin polymer is passed through a die zone to a pelletizer for pelletizing the obtained olefin polymer. σ2=∫0∞(t−τ)2E(t)dt   equation (1)

    Super absorbent polymer
    5.
    发明授权

    公开(公告)号:US10829630B2

    公开(公告)日:2020-11-10

    申请号:US15770359

    申请日:2017-01-03

    申请人: LG Chem, Ltd.

    摘要: The present invention relates to a super absorbent polymer which maintains excellent absorption performance and retains physical properties even after being physically damaged by an external force. The super absorbent polymer comprises: a base polymer powder including a first cross-linked polymer of a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer formed on the base polymer powder and including a second cross-linked polymer in which the first cross-linked polymer is further cross-linked via an alkylene carbonate having 2 to 5 carbon atoms, wherein the super absorbent polymer satisfies predetermined physical properties.

    Process for producing (meth)acrylic resin composition

    公开(公告)号:US10184015B2

    公开(公告)日:2019-01-22

    申请号:US15553714

    申请日:2016-02-26

    申请人: KURARAY Co., Ltd.

    摘要: A method for producing a (meth)acrylic resin composition, comprising: continuously feeding reaction starting materials to a tank reactor, the reaction starting materials comprising a polymerizable monomer component, a chain transfer agent and a radical polymerization initiator, the polymerizable monomer component comprising 50 to 100% by mass of methyl methacrylate, 0 to 20% by mass of an acrylic acid alkyl ester and 0 to 30% by mass of an additional monomer; conducting bulk polymerization of the polymerizable monomer component at a polymerization conversion ratio of 40 to 70% by mass to obtain a liquid containing a (meth)acrylic resin; continuously feeding the resulting liquid to a vented extruder to separate volatile component from the (meth)acrylic resin; conducting distillation using an atmospheric distillation column to separate the volatile component into a high boiling fraction (C1) and a low boiling fraction (A1); and conducting distillation using a vacuum distillation column having a pressure of −50 kPaG to −101 kPaG at the top of the vacuum distillation column to separate the high boiling fraction (C1) into a high boiling fraction (C2) and a low boiling fraction (A2); reusing the low boiling fraction (A1) and the low boiling fraction (A2) as part of the reaction starting materials.

    METHOD FOR PRODUCING (METH)ACRYLIC RESIN COMPOSITION

    公开(公告)号:US20170226237A1

    公开(公告)日:2017-08-10

    申请号:US15501586

    申请日:2015-08-06

    申请人: KURARAY CO., LTD.

    IPC分类号: C08F6/28 C08K5/09 C08K5/101

    摘要: A (meth)acrylic resin composition is obtained by a method comprising: continuously feeding a raw material solution essentially comprising methyl methacrylate, a chain transfer agent and a radical polymerization initiator, and optionally comprising an acrylic acid alkyl ester in a mass ratio of the acrylic acid alkyl ester to the methyl methacrylate of 0/100 to 20/80 into a tank reactor to allow bulk polymerization to proceed in the tank reactor at a polymerization conversion ratio of 40 to 70% by mass to obtain a reaction product while continuously discharging the reaction product from the tank reactor; heating the discharged reaction product with a heat exchanger; removing volatile matter from the heated reaction product; filtrating a liquid additive through a filter; and adding the filtrated liquid additive to the reaction product from which the volatile matter has been removed.

    Distilled epoxy novolac resins
    10.
    发明授权

    公开(公告)号:US09644067B2

    公开(公告)日:2017-05-09

    申请号:US15103100

    申请日:2014-12-17

    申请人: BLUE CUBE IP LLC

    IPC分类号: C08G59/02 C08G59/08 C08F6/28

    CPC分类号: C08G59/025 C08G59/08

    摘要: A continuous process comprising: a) separating a starting epoxy novolac resin comprising oligomers having an average functionality of greater than 2.5 and a hydrolyzable chlorine content of less than 450 ppm with a first continuous evaporator apparatus under a vaporization temperature in the range of from 150° C. to 250° C. and an absolute pressure of from 0.05 to 1 mmHg absolute to form a first vapor fraction comprising epoxy novolac resin having more than 95 weight percent of 2-functional components and wherein the mass of the first vapor fraction is in the range of from 5 to 20 weight percent of the starting epoxy novolac resin; and a first bottom fraction comprising epoxy novolac resin having a lower weight percent of 2-functional components in comparison with the weight percent of 2-functional components of the starting epoxy novolac resin; b) recovering the first bottom fraction; and c) condensing from 95 weight percent to 99.95 weight percent of the first vapor fraction at a temperature in the range of from 50° C. to 200° C. to form a first partially condensed vapor fraction product having at least 95 weight percent of 2-functional components and having a total chlorine content of less than 900 ppm and an uncondensed vapor product comprising halogenated impurities, is disclosed.