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    Reactive dyes with a triphendioxazine chromophore
    1.
    发明授权
    Reactive dyes with a triphendioxazine chromophore 失效
    与TRIPHENDIOXAZINE CHROMOPHORE的反应性染料

    公开(公告)号：US5194607A

    公开(公告)日：1993-03-16

    申请号：US722108

    申请日：1991-06-27

    申请人： Manfred Patsch ,  Claus Marschner ,  Claus-Ulrich Priester

    发明人： Manfred Patsch ,  Claus Marschner ,  Claus-Ulrich Priester

    IPC分类号： C09B19/00 ,  C09B62/02 ,  C09B62/04 ,  C09B62/44 ,  C09B62/503

    CPC分类号： C09B62/046 ,  C09B62/021 ,  C09B62/4405

    摘要： Triphendioxazine dyes suitable for dyeing or printing hydroxyl- or amido-containing substrates have the formula ##STR1## where n is 0 or 1,m is 1 or 2,R.sup.1 and R.sup.2 are each independently of the other hydrogen, chlorine, bromine, hydroxysulfonyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, substituted or unsubstituted phenyl or substituted or unsubstituted phenoxy,R.sup.3 is halogen, carboxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, vinylsulfonyl or the radical --SO.sub.2 --CH.sub.2 CH.sub.2 --Z, where Z is a leaving group, andQ.sup.1 and Q.sup.2 are each independently of the other a radical of the formula ##STR2## where R.sup.4 and R.sup.5 are each independently of the other hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,R.sup.6 is hydrogen or a fiber-reactive radical,L.sup.1 and L.sup.2 are each independently of the other substituted or unsubstituted C.sub.2 -C.sub.8 -alkylene or phenylene,X is a chemical bond, oxygen, sulfur, imino, C.sub.1 -C.sub.4 -alkylimino, carbonyl or methylene, andY is oxygen or sulfur,with the proviso that if n is 0, R.sup.6 is a fiber-reactive radical, and that the hydroxysulfonyl groups are each ortho to the substituents Q.sup.1 and Q.sup.2.

    摘要翻译： 适用于染色或印刷含羟基或酰胺基底物的三苯并二恶嗪染料具有式“IMAGE”，其中n为0或1，m为1或2，R 1和R 2各自独立地为氢，氯，溴，羟基磺酰基， C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，取代或未取代的苯基或取代或未取代的苯氧基，R 3是卤素，羧基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，乙烯基磺酰基或-SO 2 -CH 2 CH 2 - 其中Z是离去基团，并且Q 1和Q 2各自独立地为下式的基团：其中R 4和R 5各自独立地为氢，C 1 -C 4 - 烷基或苯基，R 6是氢或 纤维反应性基团L1和L2各自独立地为其它取代或未取代的C 2 -C 8亚烷基或亚苯基，X为化学键，氧，硫，亚氨基，C 1 -C 4烷基亚氨基，羰基或亚甲基，Y 是氧或硫，条件是如果n为0，则R6为纤维反应性基团，羟基磺酰基 s各自为取代基Q1和Q2的邻位。

    Reactive dyes with a benzo-fused heterocycle as anchor
    2.
    发明授权
    Reactive dyes with a benzo-fused heterocycle as anchor 失效
    具有苯并稠合杂环作为锚的活性染料

    公开(公告)号：US5929217A

    公开(公告)日：1999-07-27

    申请号：US620306

    申请日：1996-03-22

    申请人： Manfred Patsch ,  Hermann Loffler ,  Claus Marschner

    发明人： Manfred Patsch ,  Hermann Loffler ,  Claus Marschner

    IPC分类号： C07D401/12 ,  C07D209/34 ,  C07D209/46 ,  C07D401/14 ,  C07D403/12 ,  C07D403/14 ,  C07D413/14 ,  C07D498/04 ,  C09B62/44 ,  C09B62/503 ,  C09B62/006 ,  C09B62/08 ,  C09B62/22 ,  C09B62/507

    CPC分类号： C07D403/12 ,  C07D209/46 ,  C07D403/14 ,  C09B62/4403 ,  C09B62/503

    摘要： Reactive dyes of the formula I ##STR1## where a is 1 or 2,b is 0 or 1,Z.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen, nitro, amino, hydroxysulfonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, carbamoyl or C.sub.1 -C.sub.6 -mono- or dialkylcarbamoyl,A is methylene, carbonyl, sulfonyl or a radical of the formula CH.sub.2 --CO or CH.sub.2 --SO.sub.2,X is a direct linkage or a linker,Y.sup.1 is vinyl or a radical of the formula C.sub.2 H.sub.4 Q where Q is a group which can be eliminated under alkaline conditions,W is in case 1) the radical of a chromophore which may have further reactive groups, or in case 2) the radical of a coupling component to which additionally the radical of a diazo component may be linked via an azo bridge and which may have additional reactive groups, andL.sup.1 and L.sup.2 are each linkers,their intermediates and a process for dyeing or printing substrates having hydroxyl groups or nitrogen atoms using the novel dyes are described.

    摘要翻译： 式Ⅰ的反应性染料，其中a为1或2，b为0或1，Z1为氢，C1-C6-烷基，C1-C6-烷氧基，卤素，硝基，氨基，羟基磺酰基，C1-C6烷氧基羰基，氨基甲酰基 或C 1 -C 6单 - 或二烷基氨甲酰基，A为亚甲基，羰基，磺酰基或式CH 2 -CO或CH 2 -SO 2的基团，X为直接键或连接基，Y 1为乙烯基或式C 2 H 4 Q基 其中Q是可以在碱性条件下被除去的基团，W是在情况1的情况下）可以具有进一步反应性基团的发色团的基团，或者在情况2中，另外是重氮基团的偶合组分的基团 组分可以通过偶氮桥连接并且可以具有另外的反应性基团，并且L1和L2各自是连接体，它们的中间体以及使用新型染料染色或印刷具有羟基或氮原子的底物的方法。

    Aminophenols useful as intermediates for formazan reactive dyes
    4.
    发明授权
    Aminophenols useful as intermediates for formazan reactive dyes 失效
    氨基酚可用作甲an活性染料的中间体

    公开(公告)号：US5488127A

    公开(公告)日：1996-01-30

    申请号：US407956

    申请日：1995-03-22

    申请人： Claus Marschner ,  Manfred Patsch

    发明人： Claus Marschner ,  Manfred Patsch

    IPC分类号： C07C323/44 ,  C07C317/28 ,  C07D295/20 ,  C09B62/018 ,  C09B62/44 ,  C09B62/503

    CPC分类号： C09B62/4401 ,  C07C317/28 ,  C09B62/018 ,  C09B62/5036

    摘要： There are described formazan dyes of the formula ##STR1## where m and n are each 1 or 2,Kat.sup..sym. is the equivalent of a cation,Me is copper or nickel,X is oxygen or a radical of the formula CO--O or SO.sub.2 --0,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, wherein Q is a group that is detachable under alkaline reaction conditions,E is a fiber-reactive radical,the rings A and B may be substituted and benzofused, andthe ring C may be substituted,the use thereof for dyeing or printing hydroxyl- or nitrogen-containing organic substrates, novel aminophenols and a process for preparing same.

    摘要翻译： 描述了式IMAMA的甲an染料，其中m和n各自为1或2，Kat（+）为阳离子的当量，Me为铜或镍，X为氧或式CO-O基团 或SO 2 -O，Y为乙烯基或式C 2 H 4 -Q基团，其中Q为在碱性反应条件下可分离的基团，E为纤维反应性基团，环A和B可以被取代和苯并， 并且环C可以被取代，其用于染色或印刷羟基或含氮有机底物，新型氨基苯酚及其制备方法的用途。

    Arylsulfonyl compounds with unsaturated radicals
    6.
    发明授权
    Arylsulfonyl compounds with unsaturated radicals 失效
    具有不饱和基团的芳基磺酰基化合物

    公开(公告)号：US5225595A

    公开(公告)日：1993-07-06

    申请号：US971270

    申请日：1992-11-04

    申请人： Bernd Siegel ,  Claus Marschner ,  Manfred Patsch

    发明人： Bernd Siegel ,  Claus Marschner ,  Manfred Patsch

    IPC分类号： C07C317/14 ,  C07C317/32 ,  C07C317/36 ,  C07C317/40 ,  C09B62/447 ,  C09B62/82

    CPC分类号： C07C317/14 ,  C07C317/32 ,  C07C317/36 ,  C07C317/40 ,  C09B62/447 ,  C09B62/82

    摘要： Sulfonyl compounds of the formula ##STR1## where Ar is the radical of a benzene or naphthalene ring,R.sup.1 and R.sup.2 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano, halogen or hydroxysulfonyl,R.sup.3 is nitro, amino, C.sub.1 -C.sub.4 -alkanoylamino or benzoylamino, andR.sup.4 is a radical of the formula ##STR2## where X.sup.1, X.sup.2 and X.sup.3 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, andX.sup.4 is a group which is detachable under alkaline conditions,either in the free form or in the form of their salts, are useful for synthesizing reactive dyes.

    摘要翻译： 式（I）的磺酰化合物其中Ar是苯或萘环的基团，R 1和R 2各自为氢，取代或未取代的C 1 -C 4 - 烷基，取代或未取代的苯基，C 1 -C 4 - 烷氧基， 羧基，C 1 -C 4 - 烷氧基羰基，氰基，卤素或羟基磺酰基，R 3是硝基，氨基，C 1 -C 4 - 烷酰基氨基或苯甲酰基氨基，R 4是下式的基团：其中X 1，X 2和X 3各自为 氢，取代或未取代的C1-C4烷基或取代或未取代的苯基，X4是在碱性条件下以游离形式或其盐形式可分离的基团，可用于合成活性染料。

    Aromatic sulphonyl compounds having an additional thioether, sulphoxide or sulphonyl group
    7.
    发明授权
    Aromatic sulphonyl compounds having an additional thioether, sulphoxide or sulphonyl group 失效
    具有另外的硫醚，亚砜或磺酰基的芳族磺酰基化合物

    公开(公告)号：US5962730A

    公开(公告)日：1999-10-05

    申请号：US981497

    申请日：1998-01-09

    申请人： Claus Marschner ,  Manfred Patsch

    发明人： Claus Marschner ,  Manfred Patsch

    IPC分类号： C07C317/14 ,  C07C317/18 ,  C07C317/32 ,  C07C317/36 ,  C07C317/40 ,  C07C323/65 ,  C07C305/04

    CPC分类号： C07C317/18 ,  C07C317/36 ,  C07C317/40 ,  C07C323/65

    摘要： Sulfonyl compounds have the formula ##STR1## where n is 0, 1 or 2,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 Q, where Q is hydroxyl or an alkali-detachable group,E is C.sub.3 -C.sub.6 -alkylene with or without interruption by 1 or 2 oxygen atoms in ether function,Ar is the radical of benzene or naphthalene, andR.sup.1, R.sup.2 and R.sup.3 are each hydrogen, unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, hydroxyl, halogen, nitro, amino, hydroxysulfonyl, carboxyl, carbamoyl, sulfamoyl, cyano or a radical of the formula (NH--).sub.m (CH.sub.2 --).sub.q SO.sub.2 --Y, where m is 0 or 1, q is 0, 2 or 3, and Y is as defined above.

    摘要翻译： PCT No.PCT / EP96 / 02929 Sec。 371日期1998年1月9日 102（e）1998年1月9日PCT PCT 1996年7月4日PCT公布。 公开号WO97 / 03955 日期1997年2月6日磺酰化合物具有下式其中n为0,1或2，Y为乙烯基或式C2H4Q基团，其中Q为羟基或碱可分离基团，E为C 3 -C 6 - 没有中断1或2个氧原子的醚官能团，Ar是苯或萘的基团，R1，R2和R3各自是氢，未取代或取代的C1-C6-烷基，C1-C6-烷氧基，羟基，卤素， 硝基，氨基，羟基磺酰基，羧基，氨基甲酰基，氨磺酰基，氰基或式（NH-）m（CH2-）qSO2-Y的基团，其中m为0或1，q为0或2， 如上所述。

    Reactive formazan dyes and hydrazones
    9.
    发明授权
    Reactive formazan dyes and hydrazones 失效
    活性甲an染料和腙

    公开(公告)号：US5387674A

    公开(公告)日：1995-02-07

    申请号：US117686

    申请日：1993-09-08

    申请人： Claus Marschner ,  Manfred Patsch

    发明人： Claus Marschner ,  Manfred Patsch

    IPC分类号： C07C317/32 ,  C07C317/44 ,  C07C381/02 ,  C09B62/503 ,  D06P1/384

    CPC分类号： C09B62/5036 ,  C07C317/44 ,  C07C381/02

    摘要： There are described formazan dyes of the formula ##STR1## where n is 1 or 2,Kat.sup..sym. is the equivalent of a cation,Me is copper or nickel,X is a radical of the formula CO--O or SO.sub.2 --O,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, where Q is a group which is detachable under alkaline reaction conditions,the ring A may be substituted and benzofused, the ring B is substituted and may be benzofused, and the ring C may be substituted, the use thereof for dyeing or printing hydroxyl- or nitrogen-containing organic substrates, and novel hydrazones.

    摘要翻译： 描述了通式“IMAGE”的甲an染料，其中n是1或2，Kat（+）是阳离子的当量，Me是铜或镍，X是式CO-O或SO2-O的基团， Y是乙烯基或式C2H4-Q的基团，其中Q是在碱性反应条件下可分离的基团，环A可以被取代和苯并稠合，环B被取代并且可以是苯并稠合的，并且环C可以 被用于染色或印刷含羟基或含氮有机底物和新型腙的用途。

    Reactive dyes with a reactive system based on alkenylsulfonyl and benzyl compounds as intermediates therefor
    10.
    发明授权
    Reactive dyes with a reactive system based on alkenylsulfonyl and benzyl compounds as intermediates therefor 失效
    具有基于烯基磺酰基和苄基化合物的反应体系的活性染料作为其中间体

    公开(公告)号：US5241055A

    公开(公告)日：1993-08-31

    申请号：US899943

    申请日：1992-06-17

    申请人： Claus Marschner ,  Joerg L. Jessen ,  Klaus Pandl ,  Manfred Patsch

    发明人： Claus Marschner ,  Joerg L. Jessen ,  Klaus Pandl ,  Manfred Patsch

    IPC分类号： C07C317/14 ,  C07C317/36 ,  C09B62/44

    CPC分类号： C09B62/4403 ,  C07C317/14 ,  C07C317/36

    摘要： Reactive dyes useful for dyeing or printing hydroxyl- or nitrogen-containing substrates have the formula ##STR1## where U is vinyl, propenyl or the radical of the formula ##STR2## in which Z.sup.1 is hydrogen or methyl and Z.sup.2 is a group which is detachable under alkaline reaction conditions,X isa) the radical of a chromophore orb) the radical of a coupling component to which may be additionally attached the radical of a diazo component via an azo linkage and which may contain an additional reactive group, andL isa) a bridge member of the formula ##STR3## where Q.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, Q.sup.2 and Q.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl, and Q.sup.4 is a leaving group, orb) an azo linkage,the radical X-L being bonded to the benzene ring meta or para to the CH.sub.2 -SO.sub.3 H group,and their preparation may involve novel benzyl compounds as intermediates.

    摘要翻译： 可用于染色或印刷含羟基或含氮底物的活性染料具有式“IMAGE”，其中U是乙烯基，丙烯基或式（IMAGE）基团，其中Z1是氢或甲基，Z2是可分离的基团 在碱性反应条件下，X是a）发色团的基团或b）偶联组分的基团，其可以另外通过偶氮键连接重氮组分的基团，并且可以含有另外的反应性基团，并且L 是a）式为“IMAGE”的桥式成员，其中Q1为氢或C1-C4-烷基，Q2和Q3各自独立于另一个氢或C 1 -C 4 - 烷基，Q 4为离去基团，或b） 偶氮键，基团XL键合到CH2-SO3H基团的间位或对位的苯环上，它们的制备可以包括新的苄基化合物作为中间体。