-
公开(公告)号：US06730711B2
公开(公告)日：2004-05-04
申请号：US10149602
申请日：2002-06-13
申请人： Masazumi Sasabe , Kenji Kadonaga , Hiroki Inoue , Akiko Mitsuhashi , Hirotama Fujimaru , Masatoshi Yoshida , Masuji Izubayashi , Kazutomo Takahashi
发明人： Masazumi Sasabe , Kenji Kadonaga , Hiroki Inoue , Akiko Mitsuhashi , Hirotama Fujimaru , Masatoshi Yoshida , Masuji Izubayashi , Kazutomo Takahashi
IPC分类号： C08J928
摘要： A method for the production of a porous cross-linked polymer material by the polymerization of an HIPE containing a cross-linking agent, characterized by the fact at least one species of the cross-linking agent is a compound having a double bond equivalent f not less than 120 g/mol. The cross-linking agent is preferred to be a compound possessed of an alkylene oxide moiety or a vinyl polymer containing not less than two polymerizing double bonds in the molecular unit. Thus, it is made possible to produce a porous cross-linked polymer material excellent in absorbency and flexibility, permit the HIPE to be polymerized in a short time, and therefore improve the efficiency of production.
摘要翻译： 通过含有交联剂的HIPE的聚合制备多孔交联聚合物材料的方法，其特征在于至少一种交联剂是具有双键当量f的化合物 小于120g / mol。 交联剂优选为具有烯化氧部分的化合物或在分子单元中含有不少于两个聚合双键的乙烯基聚合物。 因此，可以制造吸水性和柔软性优异的多孔交联聚合物材料，能够在短时间内使HIPE聚合，从而提高生产效率。
-
公开(公告)号：US06395793B1
公开(公告)日：2002-05-28
申请号：US09712723
申请日：2000-11-14
申请人： Kenji Kadonaga , Akiko Mitsuhashi , Hirotama Fujimaru , Masazumi Sasabe , Kazutomo Takahashi , Masuji Izubayashi
发明人： Kenji Kadonaga , Akiko Mitsuhashi , Hirotama Fujimaru , Masazumi Sasabe , Kazutomo Takahashi , Masuji Izubayashi
IPC分类号： C08J928
CPC分类号： C08F2/32 , C08J2201/028
摘要： An object of this invention is to provide a method for the production of a porous material by polymerizing a water-in-oil type high internal phase emulsion in a briefer time than a conventional technique without impairing the stability of the emulsion. The object of this invention can be accomplished by a method for the production of a porous material comprising a step of polymerizing a water-in-oil type high internal phase emulsion containing a polymerization initiator, wherein the polymerization initiator is a redox type initiator combining a water-soluble oxidizing agent and a reducing agent, the reducing agent is preparatorily added to form the emulsion, and thereafter the water-soluble oxidizing agent is added to the emulsion to polymerize the added emulsion.
摘要翻译： 本发明的目的是提供一种通过在比传统技术更短的时间内将油包水型高内相乳液聚合而不损害乳液的稳定性来生产多孔材料的方法。 本发明的目的可以通过一种生产多孔材料的方法来实现，该方法包括使含有聚合引发剂的油包水型高内相乳液聚合的步骤，其中聚合引发剂是氧化还原型引发剂， 水溶性氧化剂和还原剂，预先添加还原剂以形成乳液，然后将水溶性氧化剂加入到乳液中以使所加入的乳液聚合。
-
公开(公告)号：US06323250B1
公开(公告)日：2001-11-27
申请号：US09712558
申请日：2000-11-14
申请人： Kenji Kadonaga , Akiko Mitsuhashi , Hirotama Fujimaru , Masazumi Sasabe , Kazutomo Takahashi , Masuji Izubayashi
发明人： Kenji Kadonaga , Akiko Mitsuhashi , Hirotama Fujimaru , Masazumi Sasabe , Kazutomo Takahashi , Masuji Izubayashi
IPC分类号： C08J928
CPC分类号： C08F2/32
摘要： An object of this invention is to provide a method for the production of a porous material by polymerizing a water-in-oil type high internal phase emulsion in a briefer time than a conventional technique without impairing the stability of the emulsion. The object of this invention can be accomplished by a method for the production of a porous material comprising a step of polymerizing a water-in-oil type high internal phase emulsion containing a polymerization initiator, wherein the polymerization initiator is a redox type initiator combining an oil-soluble oxidizing agent and a reducing agent, either of the oil-soluble oxidizing agent or the reducing agent is preparatorily added to form the emulsion, and thereafter the remainder of the reducing agent or the oil-soluble oxidizing agent is added to the emulsion to polymerize the added emulsion.
摘要翻译： 本发明的目的是提供一种通过在比传统技术更短的时间内将油包水型高内相乳液聚合而不损害乳液的稳定性来生产多孔材料的方法。 本发明的目的可以通过一种生产多孔材料的方法来实现，该方法包括使包含聚合引发剂的油包水型高内相乳液聚合的步骤，其中聚合引发剂是氧化还原型引发剂， 油溶性氧化剂和还原剂，油溶性氧化剂或还原剂中的任一种被预先加入以形成乳液，然后将剩余的还原剂或油溶性氧化剂加入到乳液中 以使所加入的乳液聚合。
-
公开(公告)号：US06395792B1
公开(公告)日：2002-05-28
申请号：US09689350
申请日：2000-10-12
申请人： Kinya Nagasuna , Hirotama Fujimaru , Kenji Kadonaga , Kozo Nogi , Katsuhiko Sakamoto , Masazumi Sasabe , Kenji Minami
发明人： Kinya Nagasuna , Hirotama Fujimaru , Kenji Kadonaga , Kozo Nogi , Katsuhiko Sakamoto , Masazumi Sasabe , Kenji Minami
IPC分类号： C08J928
CPC分类号： C08J9/283 , C08F2/32 , C08J2201/028
摘要： An object of this invention is to provide a method for the production of a porous cross-linked polymer, which permits the polymerization (curing) of a water in oil type high internal phase emulsion (HIPE) in such an exceptionally brief time as not more than 30 minutes, preferably not more than 10 minutes without impairing the stability of the HIPE. The object of this invention mentioned above can be accomplished by a method for the production of a porous cross-linked polymer which comprises steps of mixing an oil phase containing a polymerizing monomer, a cross-linking monomer, and a surfactant as essential components with a water phase containing water as an essential component thereby obtaining a water in oil type high internal phase emulsion and heating said emulsion to a prescribed curing temperature thereby polymerizing the emulsion, wherein said emulsion is formed in a thickness of not more than 50 mm and the temperature-increasing rate of the emulsion is not less than 5° C./minute.
摘要翻译： 本发明的目的是提供一种生产多孔交联聚合物的方法，其允许在非常短的时间内将油包水型高内相乳液（HIPE）中的聚合（固化）不再多 超过30分钟，优选不超过10分钟，而不损害HIPE的稳定性。 上述本发明的目的可以通过生产多孔交联聚合物的方法来实现，该方法包括以下步骤：将含有聚合单体的油相，交联单体和表面活性剂作为必需组分混合， 水相作为必要成分，由此获得油包水型高内相乳液，并将所述乳液加热到规定的固化温度，从而使乳液聚合，其中所述乳液的形成厚度不大于50mm，温度 - 乳液的增加速度不低于5℃/分钟。
-
公开(公告)号：US06822010B2
公开(公告)日：2004-11-23
申请号：US10474950
申请日：2003-10-14
IPC分类号： C08J928
CPC分类号： C08J9/28 , C08F2/32 , C08J2201/028
摘要： A method for producing a porous material excelling in stability of preservation is produced. A method for the production of a porous material comprising a step for obtaining a porous polymer by polymerizing an HIPE containing a polymerizable monomer is disclosed, which method comprises a step for adding a compound capable of reacting with a polymerization initiator and/or a compound capable of reacting with an unsaturated double bond to said emulsion, said porous polymer and/or said porous material having a conversion of not less than 70%. According to this invention, it is made possible to produce a porous material excelling in stability in storage and to decrease the polymerization initiator and the residual monomer very simply.
摘要翻译： 制造出具有良好的保存稳定性的多孔材料的制造方法。 公开了一种生产多孔材料的方法，其包括通过聚合含有可聚合单体的HIPE获得多孔聚合物的步骤，该方法包括添加能够与聚合引发剂和/或化合物反应的化合物的步骤 与所述乳液的不饱和双键反应，所述多孔聚合物和/或所述多孔材料具有不小于70％的转化率。 根据本发明，可以制备出具有良好的储存稳定性的多孔材料，并且非常简单地降低聚合引发剂和残留单体。
-
公开(公告)号：US06274638B1
公开(公告)日：2001-08-14
申请号：US09712557
申请日：2000-11-14
IPC分类号： C08J928
摘要： This invention is targeted at providing a method for producing a porous cross-linked polymer material excelling in absorption properties and mechanical strength in a short period of time. In the production of a porous cross-linked polymer material from an HIPE, the method of this invention is characterized by comprising a step of polymerizing the HIPE till the bromine value thereof falls to not more than 25% of the value existing prior to the polymerization and a subsequent step of after curing the porous cross-linked polymer material by means of an active energy ray or a temperature higher than the polymerization temperature.
摘要翻译： 本发明的目的在于提供一种制造在短时间内具有优异的吸收性能和机械强度的多孔交联聚合物材料的方法。 在从HIPE生产多孔交联聚合物材料时，本发明的方法的特征在于包括使HIPE聚合直到其溴值下降到聚合之前存在的值的25％以下的步骤 以及随后通过活性能量射线或高于聚合温度的温度固化多孔交联聚合物材料的步骤。
-
公开(公告)号：US06630519B2
公开(公告)日：2003-10-07
申请号：US10168847
申请日：2002-09-27
IPC分类号： C08J912
CPC分类号： C08F2/32
摘要： This invention concerns a method for the production of a porous polymer from a water-in-oil type high internal phase emulsion (HIPE). By using an oil-soluble polymerization initiator as the polymerization initiator, the method for producing a porous polymer with outstanding characteristics in a very short period even when the porous polymer is produced from an HIPE exhibiting a viscosity of not more than 500 mPa second at the emulsion formation temperature or when the porous polymer to be produced possesses a number-average pore diameter of not less than 80 &mgr;m is provided.
摘要翻译： 本发明涉及从油包水型高内相乳液（HIPE）生产多孔聚合物的方法。 通过使用油溶性聚合引发剂作为聚合引发剂，即使在多孔性聚合物由HIPE生产时，在非常短的时间内也具有突出特性的多孔性聚合物的制造方法， 乳液形成温度或当要生产的多孔聚合物具有不小于80μm的数均孔径时。
-
公开(公告)号：US06797735B2
公开(公告)日：2004-09-28
申请号：US10332219
申请日：2003-01-03
申请人： Kinya Nagasuna , Kenji Kadonaga , Hirotama Fujimaru , Kozo Nogi , Kenji Minami
发明人： Kinya Nagasuna , Kenji Kadonaga , Hirotama Fujimaru , Kozo Nogi , Kenji Minami
IPC分类号： C08J928
CPC分类号： C08J9/28 , C08F2/32 , C08J2201/028 , C08J2201/0504 , C08J2333/06
摘要： A method of production is provided which is capable of efficiently producing in a very short period of time a porous polymer possessing a uniform foam structure and truly excelling in absorption properties and physical properties. It is a method for the production of a porous polymer, characterized by comprising (a) an emulsifying step for forming a water-in-oil type high internal phase emulsion (HIPE) by mixing and stirring an oil phase containing a polymerizing monomer component and a surfactant as essential components, (b) a shaping step for shaping the HIPE in a specific form, and (c) a polymerizing step for polymerizing the shaped HIPE and controlling the temperatures of the emulsion at the component steps (a)-(c) so that they may not produce a change exceeding 10° C. or controlling all the component steps so that they may proceed at temperatures of not lower than 80° C.
-
公开(公告)号：US6166097A
公开(公告)日：2000-12-26
申请号：US548934
申请日：2000-04-13
CPC分类号： B01F17/0085 , B01D17/0217 , C02F1/04 , C02F1/38 , C02F1/66 , C02F2301/046 , C02F2303/16 , C08J2201/028
摘要： A method for producing a porous material by forming a water-in-oil type high internal phase emulsion, which method is characterized by causing waste water generated during the process of production to be put to reuse. The waste water is preferred to be reused after the removal of impurities or the adjustment of pH. According to this invention, the waste water can be reused up to 50 repetitions, with the result that the amount of feed water and the amount of waste water will be decreased. Incidentally, by adjusting the pH of the water-in-oil type high internal phase emulsion after the reaction thereof in the range of 4-9, it is made possible to continue the reuse of waste water and, at the same time, lower the stimulating property of the produced porous material.
摘要翻译： 一种通过形成油包水型高内相乳液制造多孔材料的方法，其特征在于使生产过程中产生的废水重新使用。 在除去杂质或调节pH后，废水优选重复使用。 根据本发明，废水可重复使用多达50次，从而减少给水量和废水量。 顺便提及，通过在4-9范围内调节油包水型高内相乳液的pH值，可以继续使用废水，同时降低 所产生的多孔材料的刺激性能。
-
公开(公告)号：US07196139B2
公开(公告)日：2007-03-27
申请号：US10746873
申请日：2003-12-24
CPC分类号： A61L15/60 , B01J20/26 , B01J20/28004 , B01J2220/44 , C08F2/14 , C08F2/32 , C08J3/005 , C08J2300/14 , Y10S524/916
摘要： A water-absorbent resin composition excelling in an absorption capacity under pressure, a first transition of initial absorption, and the small amount of rewet is provided. It comprises a water-absorbent resin obtained by aqueous solution polymerization and by reversed-phase suspension or reversed-phase emulsion polymerization and shows a CSF of not less than 20 g/g or an AAP of not less than 20 g/g or an SFC of not less than 10 (unit: 10−7×cm3×s×g−1). The gaps among resin particles owing to the difference in shape form optimum gap widths for the sake of capillarity. The resin composition consequently formed, therefore, manifests such excellent properties without the influences of a surfactant or an emulsifier.
摘要翻译： 提供了在压力下具有优异的吸水性树脂组合物，初始吸收的第一转变和少量的再湿润性。 它包括通过水溶液聚合和通过反相悬浮或反相乳液聚合获得的吸水性树脂，并且显示出不小于20g / g或不小于20g / g的AAP的CSF或SFC 不小于10（单位：10〜7×x 3×xsxg -1）。 为了毛细作用，由于形状差异，树脂颗粒之间的间隙形成最佳的间隙宽度。 因此，由此形成的树脂组合物在没有表面活性剂或乳化剂的影响的情况下表现出优异的性能。
-
-
-
-
-
-
-
-
-
搜索结果
36 条记录 (耗时 0.029 秒)
