摘要:
The invention provides a stable positive-electrode mixture slurry that is not subject to gelation, a positive electrode with abundant flexibility, and a lithium secondary battery with excellent battery characteristics. The slurry comprises a positive-electrode active material, a binder, and an organic solvent, the positive-electrode active material is a lithium-containing complex metal oxide represented by Formula: Lix M1yM21-yO2 (wherein 0.4≦x≦1; 0.3≦y≦1; M1 is at least one selected from Ni or Mn; and M2 is at least one selected from Co, Al, or Fe); and the binder comprises a fluorine-containing polymer represented by Composition Formula: (VDF)m(TFE)n(HFP)l (wherein VDF is a structural unit from vinylidene fluoride; TFE is a structural unit from tetrafluoroethylene; HFP is a structural unit from hexafluoropropylene; and 0.45≦m≦1; 0≦n≦0.5; and 0≦l≦0.1, and m+n+l=1).
摘要:
There is provided a lithium secondary cell having specifically excellent discharge capacity, rate characteristics and further cycle characteristics and improved incombustibility (safety). The lithium secondary cell comprises a negative electrode, a non-aqueous electrolytic solution and a positive electrode, in which an active material for the negative electrode comprises lithium titanate and the non-aqueous electrolytic solution comprises a fluorine-containing solvent.
摘要:
The present invention provides a binder composition for an electrode. The binder composition includes PTFE particles as primary particles uniformly dispersed in an organic solvent at a high concentration. The present invention relates to a binder composition for an electrode, comprising an organosol composition containing PTFE particles (A), a polymer (B), and a fluorine-free organic solvent (C); and no electrode active material (J), wherein the polymer (B) is soluble in the fluorine-free organic solvent (C).
摘要:
The present invention provides a conductive protective layer-forming paste for current collector laminates which can be used even for high voltage designs to protect current collectors from corroding without loss of cell characteristics, and a current collector laminate, an electrode laminate, and nonaqueous secondary cells (e.g. a lithium secondary cell, an electric double layer capacitor) that include a conductive protective layer formed therefrom. The paste for forming conductive protective layers for current collector protection includes: polytetrafluoroethylene; and a conductive filler (b). The current collector laminate includes: a conductive protective layer (A); and a current collector (B), the conductive protective layer (A) being formed by coating the paste for forming conductive protective layers onto the current collector (B).
摘要:
The present invention provides a conductive protective layer-forming paste for current collector laminates which can be used even for high voltage designs to protect current collectors from corroding without loss of cell characteristics, and a current collector laminate, an electrode laminate, and nonaqueous secondary cells (e.g. a lithium secondary cell, an electric double layer capacitor) that include a conductive protective layer formed therefrom. The paste for forming conductive protective layers for current collector protection includes: polytetrafluoroethylene; and a conductive filler (b). The current collector laminate includes: a conductive protective layer (A); and a current collector (B), the conductive protective layer (A) being formed by coating the paste for forming conductive protective layers onto the current collector (B).
摘要:
The present invention provides a solvent for a nonaqueous electrolyte solution enabling a lithium secondary battery to exhibit an excellent discharge capacity, load characteristics, and cycle characteristics even under high voltages, as well as a nonaqueous electrolyte solution that uses this solvent and a lithium secondary battery. This solvent for a nonaqueous electrolyte solution is a solvent for a nonaqueous electrolyte solution for a lithium secondary battery, wherein the solvent for a nonaqueous electrolyte solution contains a fluorine-free cyclic carbonate (I), a fluorine-free chain carbonate (II), and a 1,1-di(fluorinated alkyl)ethylene carbonate (III), and wherein with a sum of (I), (II), and (III) being 100 volume %, the fluorine-free cyclic carbonate (I) is 10 to 50 volume %, the fluorine-free chain carbonate (II) is 49.9 to 89.9 volume %, and the 1,1-di(fluorinated alkyl)ethylene carbonate (III) is from at least 0.1 volume % to not more than 30 volume %.
摘要:
A solvent for a non-aqueous electrolytic solution providing a lithium secondary cell being specifically excellent in discharge capacity, rate characteristic and cycle characteristic and having improved incombustibility (safety), a non-aqueous electrolytic solution using the solvent, and further a lithium secondary cell are provided. The solvent for dissolving an electrolyte salt of a lithium secondary cell comprises at least one fluorine-containing solvent (I) selected from the group consisting of fluorine-containing ether, fluorine-containing ester and fluorine-containing chain carbonate, a fluorine-containing aromatic compound (II), in which a part or the whole of hydrogen atoms are replaced by fluorine atoms, and other carbonate (III), the non-aqueous electrolytic solution comprises the solvent and an electrolyte salt, and the lithium secondary cell uses the non-aqueous electrolytic solution.
摘要:
The present invention provides a composite gel electrolyte film for a secondary battery which has improved ion conductivity and excellent ignition resistance and is insusceptible to discoloration. The present invention is a composite gel electrolyte film for a secondary battery comprising: a gel electrolyte for a secondary battery formed of an electrolyte retention film impregnated with a nonaqueous electrolyte; and a porous film formed of at least one resin selected from the group consisting of polyethylene, polypropylene, and polyimide, the electrolyte retention film containing a vinylidene fluoride copolymer resin that includes a vinylidene fluoride unit and a tetrafluoroethylene unit at a molar ratio of 55/45 to 95/5 and further includes 0 to 10 mol % of a hexafluoropropylene unit, the total of the vinylidene fluoride unit, the tetrafluoroethylene unit, and the hexafluoropropylene unit being 100 mol %.
摘要:
The invention provides a stable positive-electrode mixture slurry that is not subject to gelation, a positive electrode with abundant flexibility, and a lithium secondary battery with excellent battery characteristics. The slurry comprises a positive-electrode active material, a binder, and an organic solvent, the positive-electrode active material is a lithium-containing complex metal oxide represented by Formula: Lix M1yM21−yO2 (wherein 0.4≦x≦1; 0.3≦y≦1; M1 is at least one selected from Ni or Mn; and M2 is at least one selected from Co, Al, or Fe); and the binder comprises a fluorine-containing polymer represented by Composition Formula: (VDF)m(TFE)n(HFP)l (wherein VDF is a structural unit from vinylidene fluoride; TFE is a structural unit from tetrafluoroethylene; HFP is a structural unit from hexafluoropropylene; and 0.45≦m≦1; 0≦n≦0.5; and 0≦l≦0.1, and m+n+l=1).
摘要:
There is provided a lithium secondary cell having specifically excellent discharge capacity, rate characteristics and further cycle characteristics and improved incombustibility (safety). The lithium secondary cell comprises a negative electrode, a non-aqueous electrolytic solution and a positive electrode, in which an active material for the negative electrode comprises lithium titanate and the non-aqueous electrolytic solution comprises a fluorine-containing solvent.