摘要:
The present invention provides a binder composition for an electrode. The binder composition includes PTFE particles as primary particles uniformly dispersed in an organic solvent at a high concentration. The present invention relates to a binder composition for an electrode, comprising an organosol composition containing PTFE particles (A), a polymer (B), and a fluorine-free organic solvent (C); and no electrode active material (J), wherein the polymer (B) is soluble in the fluorine-free organic solvent (C).
摘要:
The present invention provides a conductive protective layer-forming paste for current collector laminates which can be used even for high voltage designs to protect current collectors from corroding without loss of cell characteristics, and a current collector laminate, an electrode laminate, and nonaqueous secondary cells (e.g. a lithium secondary cell, an electric double layer capacitor) that include a conductive protective layer formed therefrom. The paste for forming conductive protective layers for current collector protection includes: polytetrafluoroethylene; and a conductive filler (b). The current collector laminate includes: a conductive protective layer (A); and a current collector (B), the conductive protective layer (A) being formed by coating the paste for forming conductive protective layers onto the current collector (B).
摘要:
The present invention provides a conductive protective layer-forming paste for current collector laminates which can be used even for high voltage designs to protect current collectors from corroding without loss of cell characteristics, and a current collector laminate, an electrode laminate, and nonaqueous secondary cells (e.g. a lithium secondary cell, an electric double layer capacitor) that include a conductive protective layer formed therefrom. The paste for forming conductive protective layers for current collector protection includes: polytetrafluoroethylene; and a conductive filler (b). The current collector laminate includes: a conductive protective layer (A); and a current collector (B), the conductive protective layer (A) being formed by coating the paste for forming conductive protective layers onto the current collector (B).
摘要:
The present invention provides a composite gel electrolyte film for a secondary battery which has improved ion conductivity and excellent ignition resistance and is insusceptible to discoloration. The present invention is a composite gel electrolyte film for a secondary battery comprising: a gel electrolyte for a secondary battery formed of an electrolyte retention film impregnated with a nonaqueous electrolyte; and a porous film formed of at least one resin selected from the group consisting of polyethylene, polypropylene, and polyimide, the electrolyte retention film containing a vinylidene fluoride copolymer resin that includes a vinylidene fluoride unit and a tetrafluoroethylene unit at a molar ratio of 55/45 to 95/5 and further includes 0 to 10 mol % of a hexafluoropropylene unit, the total of the vinylidene fluoride unit, the tetrafluoroethylene unit, and the hexafluoropropylene unit being 100 mol %.
摘要:
The present invention provides a solvent for a nonaqueous electrolyte solution enabling a lithium secondary battery to exhibit an excellent discharge capacity, load characteristics, and cycle characteristics even under high voltages, as well as a nonaqueous electrolyte solution that uses this solvent and a lithium secondary battery. This solvent for a nonaqueous electrolyte solution is a solvent for a nonaqueous electrolyte solution for a lithium secondary battery, wherein the solvent for a nonaqueous electrolyte solution contains a fluorine-free cyclic carbonate (I), a fluorine-free chain carbonate (II), and a 1,1-di(fluorinated alkyl)ethylene carbonate (III), and wherein with a sum of (I), (II), and (III) being 100 volume %, the fluorine-free cyclic carbonate (I) is 10 to 50 volume %, the fluorine-free chain carbonate (II) is 49.9 to 89.9 volume %, and the 1,1-di(fluorinated alkyl)ethylene carbonate (III) is from at least 0.1 volume % to not more than 30 volume %.
摘要:
The present invention provides a solvent for a nonaqueous electrolyte solution enabling a lithium secondary battery to exhibit an excellent discharge capacity, load characteristics, and cycle characteristics even under high voltages, as well as a nonaqueous electrolyte solution that uses this solvent and a lithium secondary battery. This solvent for a nonaqueous electrolyte solution is a solvent for a nonaqueous electrolyte solution for a lithium secondary battery, wherein the solvent for a nonaqueous electrolyte solution contains a fluorine-free cyclic carbonate (I), a fluorine-free chain carbonate (II), and a 1,1-di(fluorinated alkyl)ethylene carbonate (III), and wherein with a sum of (I), (II), and (III) being 100 volume %, the fluorine-free cyclic carbonate (I) is 10 to 50 volume %, the fluorine-free chain carbonate (II) is 49.9 to 89.9 volume %, and the 1,1-di(fluorinated alkyl)ethylene carbonate (III) is from at least 0.1 volume % to not more than 30 volume %.
摘要:
Provided is an electrolytic solution exhibiting excellent withstand voltage and satisfactory characteristics even at low and high temperatures. The invention is an electrolytic solution that includes a cyclic carbonate (I-1) represented by formula (I-1): (in the formula, R is an alkyl group having two or more carbon atoms, a fluorine-containing alkyl group having two or more carbon atoms, an alkoxy group or a fluorine-containing alkoxy group, in which an oxygen atom may be inserted between carbon atoms); a cyclic carbonate (I-2) different from the cyclic carbonate (I-1); and an electrolyte salt (II)).
摘要:
The present invention directs to a non-aqueous electrolyte solution, including (I) at least one compound selected from the group consisting of fluorinated linear sulfones and fluorinated linear sulfonic acid esters, and (II) an electrolyte salt. Such a non-aqueous electrolyte solution has high oxidation resistance, minimizes its decomposition even when hydrofluoric acid is produced. Also, the solution is less likely to cause, in the case of being used for a secondary cell, swelling of the cell and lowering of the battery performance.
摘要:
The present invention directs to a non-aqueous electrolyte solution, including (I) at least one compound selected from the group consisting of fluorinated linear sulfones and fluorinated linear sulfonic acid esters, and (II) an electrolyte salt. Such a non-aqueous electrolyte solution has high oxidation resistance, minimizes its decomposition even when hydrofluoric acid is produced. Also, the solution is less likely to cause, in the case of being used for a secondary cell, swelling of the cell and lowering of the battery performance.
摘要:
The present invention provides a lithium ion secondary cell excellent in high-temperature storage characteristics and high voltage cycle characteristics; and a nonaqueous electrolyte for the cell.The present invention relates to a lithium ion secondary cell, comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte containing nonaqueous solvents and an electrolyte salt, the nonaqueous solvents comprising a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 (1) wherein Rf1 and Rf2 are the same as or different from each other, each being a C1-10 alkyl group or a C1-10 fluoroalkyl group; and at least one of Rf1 and Rf2 is a fluoroalkyl group, and the following compounds (I) and (II): (I) a fluorine-containing unsaturated compound; and (II) a hydroxy group-containing compound represented by the formula (2): Rf1OH (2) wherein Rf1 is the same as above, and the nonaqueous solvents comprising the compounds (I) and (II) in a total amount of 5000 ppm or less for the fluorine-containing ether.