公开(公告)号：US20020188072A1

公开(公告)日：2002-12-12

申请号：US10105272

申请日：2002-03-26

Applicant: NIPPON PAINT CO., LTD.

Inventor： Akihiro Kanakura ,  Takashi Irie ,  Hiroto Yoneda ,  Hisaki Tanabe

IPC: C08L067/02

CPC classification number: C08F299/00 ,  C08F8/10 ,  C08F8/14 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/30 ,  Y10T428/31938 ,  C08F2220/283 ,  C08F220/06

Abstract: The present invention is to provide a curable coating composition having much less of a volatile organic component, and being excellent in coating film performance such as durability and scratch resistance, and a coating film forming method using the above curable coating composition capable of suppressing generation of sagging and so on. The present invention is a curable coating composition which comprises (a) a component having an active methylene group and/or an active methine group, (b) a component having a methacrylate group and/or an acrylate group, (c) a Michael reaction catalyst and (d) a photo-polymerization initiator. The present invention also provides a coating film forming method which comprises a step (1) of applying a curable coating on a substrate to be coated and a step (2) including a stage of irradiating with ultraviolet ray and a stage of heating, said curable coating comprising the above curable coating composition.

Abstract translation: 本发明提供一种具有少量挥发性有机成分的固化性涂料组合物，并且涂膜性能如耐久性和耐划伤性优异的涂膜成型方法以及使用上述可抑制 下垂等。 本发明是一种可固化涂料组合物，其包含（a）具有活性亚甲基和/或活性次甲基的组分，（b）具有甲基丙烯酸酯基和/或丙烯酸酯基的组分，（c）迈克尔反应 催化剂和（d）光聚合引发剂。 本发明还提供了一种涂膜形成方法，其包括将待固化涂层涂覆在待涂布的基底上的步骤（1）和包括用紫外线照射和加热阶段的步骤（2）的步骤（2），所述可固化 包含上述可固化涂料组合物的涂料。

公开(公告)号：US20040219381A1

公开(公告)日：2004-11-04

申请号：US10855599

申请日：2004-05-28

Applicant: NIPPON PAINT CO., LTD.

Inventor： Akihiro Kanakura ,  Takashi Irie ,  Hiroto Yoneda ,  Hisaki Tanabe

IPC: B32B027/30 ,  B05D003/02 ,  B32B027/00

CPC classification number: C08F299/00 ,  C08F8/10 ,  C08F8/14 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/30 ,  Y10T428/31938 ,  C08F2220/283 ,  C08F220/06

Abstract: The present invention is to provide a curable coating composition having much less of a volatile organic component, and being excellent in coating film performance such as durability and scratch resistance, and a coating film forming method using the above curable coating composition capable of suppressing generation of sagging and so on. The present invention is a curable coating composition which comprises (a) a component having an active methylene group and/or an active methine group, (b) a component having a methacrylate group and/or an acrylate group, (c) a Michael reaction catalyst and (d) a photo-polymerization initiator. The present invention also provides a coating film forming method which comprises a step (1) of applying a curable coating on a substrate to be coated and a step (2) including a stage of irradiating with ultraviolet ray and a stage of heating, said curable coating comprising the above curable coating composition.

公开(公告)号：US20030039757A1

公开(公告)日：2003-02-27

申请号：US10106449

申请日：2002-03-27

Applicant: NIPPON PAINT CO., LTD.

Inventor： Hiroto Yoneda ,  Takashi Irie ,  Akihiro Kanakura ,  Yoshifumi Ichinose ,  Yuji Okura ,  Hideo Morimoto

IPC: B05D003/02

CPC classification number: C09D201/02 ,  C09D163/00 ,  C08L2666/02

Abstract: The present invention provides a thermosetting coating composition having a storage stability sufficient to be formed into a one-pack coating despite a small content of organic solvent contained therein and having a sufficient curability, and a method of forming a coating film by which the content of the organic solvent present in a coating at the time of application can be reduced. A thermosetting coating composition comprising a component (a) having a number average molecular weight of 300 to 3000 and two or more active methylene group and/or active methine groups per molecule, a component (b) having a number average molecular weight of 200 to 3000 and two or more null,null-unsaturated carboxylic ester groups per molecule, a component (c) having an onium salt, a component (d) having an epoxy group and/or 5-membered ring carbonate group and a component (e) being an organic acid, a phenol or a Lewis acid, wherein a solid content of said coating composition at a viscosity of 100 mPanulls is 50% by weight or more at 20null C.

Abstract translation: 本发明提供了一种热固性涂料组合物，其具有足以形成为单组分涂料的储存稳定性，尽管其中含有少量有机溶剂并且具有足够的固化性，并且形成涂膜的方法， 可以减少涂布时存在于涂料中的有机溶剂。 一种包含数均分子量为300〜3000的成分（a）和每分子2个以上的活性亚甲基和/或活性次甲基的组分（a）的热固性涂料组合物，数均分子量为200〜 3000和每个分子两个或更多个α，β-不饱和羧酸酯基团，具有鎓盐的组分（c），具有环氧基的组分（d）和/或5-元环碳酸酯基团和组分（e） 作为有机酸，苯酚或路易斯酸，其中在20℃下粘度为100mPa.s的所述涂料组合物的固体含量为50重量％以上。