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1.
公开(公告)号:US11830975B2
公开(公告)日:2023-11-28
申请号:US17128170
申请日:2020-12-20
Inventor: Hui Pan , Jianping Han , Yong Zhu , Heng Liu , Ou Dong , Shengbo Lu , Chenmin Liu
IPC: H01M10/056 , H01M10/0525 , H01M12/08 , C08G18/24 , C08G18/81 , C08G83/00 , C08G18/18 , C08G18/48
CPC classification number: H01M10/056 , C08G18/246 , C08G18/485 , C08G18/8116 , C08G83/002 , H01M10/0525 , H01M12/08 , H01M2300/0028 , H01M2300/0068 , H01M2300/0082 , H01M2300/0088
Abstract: An amorphous composite solid electrolyte is provided that includes one or more three-dimensional branched macromolecules with a core portion and at least three arm portions connected to the core portion. Each arm portion includes a random copolymer or a block polymer comprising a first monomer and a second monomer with a molar ratio of the first monomer to the second monomer in the range from greater than 0 to less than or equal to 1. An ion conductive electrolytic solution including at least one lithium salt solution in an amount of approximately 1 mol/l to 10 mol/l is entrained within the branched macromolecule, with a weight ratio of the branched macromolecule to the ion conducive electrolytic solution equal to or lower than 1:9, such that the branched macromolecule has a swelling degree of at least 5:1 (liquid:polymer in weight) of the ion conductive electrolytic solution.
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2.
公开(公告)号:US11824156B2
公开(公告)日:2023-11-21
申请号:US17460303
申请日:2021-08-29
Inventor: Ou Dong , Sing Ho Lo , Zhengfu Qiu , Wing Lung Hon , Jianping Han , Yong Zhu , Shengbo Lu , Chenmin Liu
IPC: H01M10/056 , H01M10/0525 , H01M4/525 , H01M4/02 , H01M4/134 , H01M4/133 , H01M4/505
CPC classification number: H01M10/056 , H01M10/0525 , H01M4/133 , H01M4/134 , H01M4/505 , H01M4/525 , H01M2004/027 , H01M2004/028 , H01M2300/0082 , H01M2300/0085
Abstract: The present invention provides a rechargeable lithium-ion battery with an in situ thermally-curable electrolyte. The thermally-curable electrolyte is cured from the thermally-curable electrolyte precursor solution including a first crosslinking agent, a second crosslinking agent, an initiator, an electrolyte solvent, an electrolyte salt, one or more electrolyte additives, and one or more monomers or a monomer polymerization product. The viscosity of the thermally-curable electrolyte precursor solution is below 200 cps such that the thermally-curable electrolyte precursor solution is infiltrated within the separator and the pores inside the cathode and anode layers then cured to form porous separator and porous electrodes fully permeated with a solid electrolyte.
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