Abstract:
The present invention relates to a redox flow battery and, more specifically, to a redox flow battery comprising an anolyte, a catholyte, and an ion exchange membrane, wherein the anolyte and the catholyte respectively comprise an electrolyte containing a Cl− ion and an active material containing a vanadium ion, and the electrolyte comprises at least one side reaction inhibitor selected from the group consisting of a metal phosphate, a metal hydrochloride and a metal sulfate.
Abstract:
The present invention relates to a redox flow battery, and more particularly, to a redox flow battery which is charged and discharged by supplying a positive electrolyte and a negative electrolyte to a battery cell using an active material containing vanadium and a cation exchange membrane, in which the positive electrolyte and the negative electrolyte contain vanadium ions as active ions, the difference in volume between the positive electrolyte and the negative electrolyte is maintained at 10% or less, and the total concentration of anions in the negative electrolyte is higher than the total concentration of anions in the positive electrolyte, whereby the transfer of water in the battery is controlled and a change in the volume of the electrolytes is minimized.
Abstract:
According to one embodiment of the present invention, the method for controlling the pump speed of a redox flow battery for transferring an electrolyte stored in an electrolyte tank to a cell stack comprises the steps of: measuring the input power and/or the output power of the redox flow battery; measuring the charging power and/or the discharging power of the redox flow battery; calculating the power loss of the redox flow battery by using the difference between the input power and the charging power, or the difference between the output power and the discharging power; and adjusting the pump speed according to the power loss.
Abstract:
Disclosed are a redox flow battery system and a control method for the same. In the redox flow battery system, an oxidation number is controlled by injecting at least one of an oxidant and a reducer into at least one of a cathode side and an anode side using a measured oxidation number of the electrolyte. Therefore, even though an oxidation number balance is inevitably broken, since an initial concentration of vanadium ion, that is, an average oxidation number is maintained without a large change in the concentration, efficiency and stability of a battery may be promoted, and the oxidation number balance may be monitored in real time and the oxidation number balance may be recovered without a separate process of separating electrolytes to entirely mixing the electrolytes, or the like, that is, without stopping a function of the battery, thereby facilitating maintenance and control of performance of the battery.
Abstract:
Disclosed is a carbon structure electrode for redox flow batteries, which includes a plurality of spherical macropores formed on a surface of a polymer-derived carbon structure and inside the polymer-derived carbon structure so as to allow electrolyte migration. The carbon structure electrode for redox flow batteries has excellent electrical conductivity and enables cost reduction through a simplified preparation process.