Metallo-organic polymers for gas separation and purification
    1.
    发明授权
    Metallo-organic polymers for gas separation and purification 失效
    用于气体分离和纯化的金属有机聚合物

    公开(公告)号:US06491740B1

    公开(公告)日:2002-12-10

    申请号:US09613735

    申请日:2000-07-11

    IPC分类号: B01D5302

    摘要: The present invention provides for methods and compositions for gas separation and purification utilizing a metallo-organic polymer adsorbent in processes for separating carbon dioxide, water, nitrogen oxides and hydrocarbons from gas streams. The metallo-organic polymer adsorbent composition has the formula: [R(L)n]mMn, wherein R represents an organic spacer selected from the group consisting of an organic cyclic or acyclic compound; L represents a ligation group substituted on the organic spacer selected from the group consisting of carboxylate group, —C(═O)O−; dithiocarboxylate group, —C(═S)S−; and &bgr;-diketonate group, —C(═O)C(R′)═C(—O−)—, wherein R′═H, or an aliphatic or aromatic group; M represents a transition metal or a rare earth metal selected from the group consisting of I to VIIB and VIII metals; m is the oxidation state of transition metal; and n is the number of the ligation group substituted on the organic spacer.

    摘要翻译: 本发明提供在气流中分离二氧化碳,水,氮氧化物和烃的方法中利用金属有机聚合物吸附剂进行气体分离和净化的方法和组合物。 金属有机聚合物吸附剂组合物具有下式:其中R表示选自有机环状或非环状化合物的有机间隔物; L表示在有机间隔基上取代的连接基,所述有机间隔基选自羧酸酯基,-C(= O)O-; 二硫代羧酸酯基,-C(= S)S-; 和β-二酮基团,-C(= O)C(R')= C(-O - ) - ,其中R'= H,或脂族或芳族基团; M表示选自I至VIIB和VIII族金属的过渡金属或稀土金属; m是过渡金属的氧化态; n是在有机间隔物上取代的连接基团的数目。